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0-05417
MTERIAl SAFETY DATA SHEET
Page 1 of 6
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDEtrTIFICAnON
MSDS PREPARED BY: Environmental
W.R.Grace & Co.-Conn.
62 Whittemore Ave.
Cambridge. MA 02140
TeleDhone
In USA: (617) B76-14oo
Health DeDt.-Grace Construction Products
H. R. Grace & Co. of Canada Ltd.
294 Clements Rd. West
Ajax, Ontario. LIS 3C6
Number for Information and Emeroencv ReSDonse
. In Canada: (905) 683-8561
MSDS Nu.ber: 0-05417
0??oo1
Canee 1 s MSDS # 0-05357
Date: 03/08/1 996 -
Trade N,,_s and SvnonftlS:
(SEE SECTION 16 FOR ADDITIONAL
PRODUCT IDENTIFICATION)
DAJtACEMe 19
Chemical Names and Familv:
Naphthalene Sulfonate Formaldehyde
Copolymer. in Aqueous Solution
Product Use:
Formula:
Concrete Admixture
HIXTURE-NA
MIXTURE-NA
CAS# (Chemical Abstract Service):
SECTION 2 - HAZARDOOS INGREDIENT ANI) MJOR COMPONENT INFORMATION
(See Section 11 for Co.alete Ch~tcal Na.es)
EXPQSgl[ UJIITS (See Seni... 8 for ean.ti.. Limts)
Exposure U.i ts
ACGtH
TLV: 10"9/.,3 -TWA
Max. :
[NGREDIENT'
CALCIUM SULrATE
CAS# 07778-18-9
By Wt.
..00
OSHA
DEL: 15109'.,3 _ TWA
as Total Dust
5l1t~/'" 3 TWA
~s ResDlrable Dust
o.5Dpm.action le".1
OTHER
Non. Establ;sh.d
'ORHALOEHYOE
CAS# 00050-00-0
0.05
0.750_TWA
~.Oo_STEL
0.3 0,,", c.n ;n9
Limit
NIOSII-law.st
feasible 1.v.,1
t1src
CAS>
40.00 UonrEst.blished
Non. Establ;sh.d
Non. Establ;sh.d
MIXTURE
....,-........ '
SECTION 3 - HAZARDS IDEhdFICATION
Blero@ncY OV@rvi@w:
Harnlna Statements:
CAUTION! MAY CAUSE IRRITATION.
Contains Calcium or Sodium/Potassium naphthalene sulfonate-'
formaldehyde copolymer CAS# 37293-74-6 or 9084-06-4/67828-14-2,
Calcium or Sodium/Potassium sulfate CAS# 7778-18-9 or 7757-82-6/
7778-80-5 and Hater CAS# 7732-18-5.
Direct eye contact may cause irritation.
Repeated skin contact or inhalation may cause sensitization.
Swallowing liqUid may cause irritation to'gastrointestlnal tract.
May be irritating to nose and throat if inhaled. '
2531f
NPCA-HHIS Hazard Index:
I) Health:
0F'1 ammab ili ty:
"Reactivity: 0
o Personal Protection: B
(See Section 8)
Potential Health Effects
Routes of EXDosure:
Inhalation:
Adverse health effects are not expected from typical use. However,
if product is inhaled as vapor or mist. may cause Irritation re-
sulting In coughing, soreness in respiratory tract, chest tightness
and difficulty breathing. Hypersensitive individuals may experience
allergic respiratory reaction which can result in wheezing and chest
tightness.
Skin and Eve:
Eyf contact with' llauid or mlst may cause eye irritation resulting
in burning,' redness and tearing. Skin contact may cause irritation
resulting. in redness and swelling. Hypersensitive individuals may
develop an allergic reaction resulting in dermatitis. rash or hives.
Toxicity via skin absorption ;s 'low (Dermal LD50 rabbit for s'imilar
products is greater than 16 g/kg,i. '
Inaestion:
Solution may cause irritation to the gastrointestinal tract if
swallowed. If ingested may cause nausea, diarrhea or vomiting.
Systemic toxicity is low. (Oral LDSO rat for similar product
is 4.3 g/kg.)
Carcinoaenicitv Accordlna to NTP. IARe and OSHA:
Product is capable of releasing formaldehyde under certain conditions.
Exposures to formaldehyde during typical applications are expected to
be insignificant. Exposure to formaldehyde vapor is a potential
concern if product is heated or spray applied and under confined
space conditions or during response to large spills. Formaldehyde Is
classified as follows:
NTP:
,r
Suspect animal carci"~~n
Cat~qory 2B carcino~_n
. Pc' Iti a 1 Cancer Haz
L_..
0-05417
MATERIAL SAFETY DATA SHEET
Page 3 of _
-.
SECTION 4 - FIRST AID HEASURF..
EYE: In case of contact. immediately flush eyes with plenty
of water for at least 15 minutes. Call a physician If
Irritation persists.
SKIN: Hash sk.ln with soap and water. If Irritation develops
and persists. call a physician. Hash contaminated
clothes before reuse.
INHALATION: If Irritation due to inhalation develops, get fresh air.
If symptoms persist. call a physician.
INGESTION: If swallowed, induce vomiting immediately as directed by
medical personnel. Never give anything by mouth to an
unconscious person. Get medical attention Immediately:
SECTION 5 - FIRE FIGHTING MEASURES
Flash Point: Not Applicable
Method Used: Aqueous System
N.F.P.A. Ratlna: H-l F-l R-O
Flammable Limits:
1fl N.A. Ufl N.A
Extinauishlna Media
Product Is an aqueous solution and does not burn but will decompose.
In case of fire use water. dry chemical, Carbon dioxide or "alcohol"
foam.
Scecial Fire Flahtlna Procedures
Not Applicable
Unusual Fire and Exclosion Hazards
Burning may release Carbon dioxide, Carbon monoxide and Sulfur
oxides. Heating may release Formaldehyde,
SECTION 6 - ACCIDENTAL RELEASE MEASURES
U.S. RELEASES
Prevent product from. entering drink.lng water supplies or streams.
Observing precautions noted in the MSDS, collect liquid or solidify
liqUid with an inert, noncombustib,le material and' remove for disposal.
Spill reporting requirements and reportable quantities vary ~y region.
In case of any spill or release. consult Section 6 and 15 of the
MSDS and all applicable state and local regulations.
CANADIAN RELEASES
Prevent product from ~nterlng dr i nk.i ng water supp 1 I es or 'str1!ams.
Observing precautions noted in the MSDS. collect liquid or solidify
with an inert. noncombustible material and remove for disposal.
Dispose of all waste in accordance with applicable local, provincial
and national regulations.
0_05417
I1I\TERIAl SAFt.11 U^I^ ~HEET
~age .. OT 8
SECTION 7 - HANDliNG AND STORAGE INFORMATIOfI
Precaut10narv Measures: ~
... Do not get 1n eyes, on sk1n, or on cloth1ng.
Hash thoroughly after handling.
Hash contam1nated clothes before reuse.
Keep conta1ner closed when'not 1n use.
For profess10nal use only. Keep out of children's reach.
SECTION 8 - EXPOSURE <DN'TROl5/PERSONAl PROTECTION/CANADIAN EXPOSURE lIMITS
Vent1lat10n: .
Local Exhaust: Recommended when appropr1ate to control exposures.
Mechani ca I: 'Reconmended when appropr1 ate to control exposures.
Spec1al: Not Appl1cable
Other: Not Applicable
Resoiratorv Protect1on:
Respiratory protect10n is not generally reau1red. However, if
respiratory irritation develops due to inhalation of vapor or mists,
a NIOSH approved organic vapor respirator (Type TC-23C-XXX) w1th a
prefilter is recommended. A NIOSH approved respirator for
Formaldehyde vapor is reauired whenever exposures exceed the limits
speCified in Section 2 of this MSOS. For add1t1onal 1nformation
refer to US OSHA regulation 29 CFR 19l0.l048-Formaldehyde (g)(2)
Respirator Sect10n or other applicable regulations.
2532f
Skin Protect10n: .
Impervious rubber gloves should be worn to guard against prolonged or
repeated contact.
Eve Protection:
Safety glasses appropriate for routine handling. Use of goggles or
a full face respirator should be considered if product is heated or
spray applied.
Other Protective Clothina or Eauioment:
Wear appropriate clothing to prevent skin contact.
Hork/Hvaien1c Practices:
Use good hygiene practices and observe above precautions.
0-05417
MATERIAL SAFETY DATA SHEET
Page 5 of s
SECTIOft 8 - EXPOSURE CONTROLS/PERSONAL PROn\..uON/CANADIAN EXPOSURE lIHITS (Cant. d)
Provincial Exposure Limits
ACGIH
ALBFRTA
B.C.
ONTARIO
OUEBEC
Inc:rr(lld;(IInt!;
NSFC
FORI'lALDEHYDE:
lp_TWA
2p_STEL
2p,.....s hr.
l_TWAEV
2p_STEV
2p-,!'
2p_
2p"," COEL
-CALCIUM SULFATE:
10 I119/00g - TWA
2533f
SECTION 9 - PKYSICAl AND CHEMICAL PROPERTIES
Boilino Point: Approx. Equal
to Water
Vaoor Pr~ssure (mm Ho.) Approx. Eoual
to Water
Soecific GravitV(HZO.l) Approx,
EQua 1 to 1. 1
4 Volatiles -601 Water
Vaoor Oensitv(AIR = 1) Aoprox. Eoual
To Water
Evaooration Rate Approx, Equal
(Butyl Acetate = 1) To Water
Solubility in Hater: Complete-
IU!
7 - 10
Bulk Densitv (lIeu. ft): Not Apolicable
Aooearance and Odor: Clear dark ~rown liqUid with slight
mothball (naphthalene) odor.
Odor Threshold:
O.OBppm (as Naphthalene)
D-OS417
- ~TERIAl SAFETY DATA SHEET
Page 6 of _
SF:CTION 10 - STABIUTY AND REACTIVITY
Stable under normal conditions (ves or no): YES
Conditions or Materials to avoid (which mav react or cause instabilitv):
None Known
Hazardous DecomDosition or Bvnroducts:
None Known
Hazardous Polvmerization:
Will not occur
Conditions to Avoid:
None Known
SECTION 11 - TOXICDLOGlCAL INFORHATIOH
INGREDIENT
<Chemical Name.
CAS#. & Common Name)
Calcium or Sodiu./Potassiu.
Naphthalene Sulfonate - Fo~l-
dehyde Copol,.er CAS# 37293-74-6 or
9084-06-4/67828-14-2
TOXICITY DATA LDso. LCSO etc.
(See Section 2 for Exnosure Limits)
LDSO (oral rat) -4.3 g/kg
Ca1ciu. or Sodium/Potassium
Sulfate CAS# 7778-18-9 or
7757-82-6/7778-80-5
LDSO (oral rat)
-6 g/l(g
:434f
0-05417
MTERlAL SAfETY DATA SHEET
Page 7 of 6
SECTION 12 - EmtOGICAL INFORMATION
None Available At This Time
SECTION 13 - DISPOSAL alIISIDFRATIONS
U.S. DISPOSAL
This product Is not a Federal HazardouS Haste according to US EPA
Regulation 40 CFR 261. Dispose of waste product in accordance'
with local and state regulations;
CANADIAN DISPOSAL
Dispose of waste in accordance with all applicable government
regulations.
SECTION 14 - TRANSPORT INFORMATION
Unit.d St.t.~ DOT
P~OPER SHIPPING: Nol Applicable
~
HAZA~O CLASS:
IDENTIFICATION #:
LABELl,) REOUIRED:
TransDOrtat.ion Hazard Classifla.t.i...
Canadian R.oulation5
TOG CLASS: Nol Applicable
Nol Applicable
Nol Applicable
Nol Applicable
Surface Freiaht Classification:
Concrete or Masonry Plasticizer and
Hater Reducing Compound
D-054 1 7
"TERIAL SAFETY DATA SHEET
Page 8 of 8
SECTIOIl 15 - REGULATORY INfORMATIOIl
SARA Tttle III Reoortina Infonllltion
ner I & II Hazard Cateaories:
(Not Meant To Be All Inclusive
Selected Reaulations R@Dresented)
IMMEDIATE (ACUTE) HEALTH
Contains Extremelv Hazardous-SARA III.S.~t1on 302 Inaredi@nt: YES
Comments: Contains less than 0.05t Formaldehyde: Not Reportable
Contains Toxic Chemical Release-SARA III Section 313 Inaredient: YES
Comments: Contains less than 0.05t Formaldehyde: Not Reportable
other Govern..nt Reoorttna Reautrewents:
CERCL.A HAZARIXlJS SUBSTANCES:
Formaldehyde Is listed as a Reportable Substance with a Reportable
Quantity (RO) of 100 lbs. Based on the maximum pOSSible Formaldehyde
content, a 20.000 gallon spill of product would equal the RO.
CHEMICAL INVENTORY CERTIFICATIOfl:
All ingredients contained in this product are included on the US EPA
Toxic Substance Control Act (TSCA) Inventory or exempt from listtng
on the TSCA Inventory.
All ingredients. contained in this product comply wtth the requirements
of the Canadian Environmental Protection Act (CEPA) and are listed on
the Domestic Substance List (DSL).
2S37f
Non-Hazardous Inoredient Disclosure:
Water. Calcium or Potassium/Sodium naphthalene sulfonate-formaldehyde
polymer. Potassium/Sodium sulfate
SECTION 16 - OTHER INFORMATIOfl
The information contained in this Material Safety Data Sheet Is applicable to
the following products:
Darace~ 19
"THE DATA INCLUDED HEREIN ARE PRESENTED ACCORDING TO H. R. GRACE & CO.-CONN's PRACTT~E
CURRENT AT THE TIME OF PREPARATION HEREOF, ARE MADE AVAILABLE. SOLELY FOR THE
CONSIDERATION, INVESTIGATION AND VERIFICATION OF THE ORIGINAL RECIPIENTS HEREOF AND
NOT CONSTITUTE A REPRESENTATION OR HARRANTY FOR HHICH GRACE ASSUMES LEGAL
RESPONSIBILITY. IT IS THE RESPONSIBILITY OF A RECIPIENT OF THIS DATA TO REMAIN
rURRENTlY INFORMED ON CHEMICAL HAZARD INFORMATION, TO DESIGN AND UPDATE ITS ON~ PROGRA
.ND TO CQHPlY HITH ALL NATJ""~L, FF'IERAL, STATE AND LOCAL LA"S AND REGULATIONS
APPLICABLE TO SAFETY. OCCUf.1i IONAl ilEAL TH, RIGHT- TO-ICNOI' 'r ENVIRONMENT~I PROhl. nON.
MP-90045
MATERIAL SAFETY DATA SHEET
Page 1 of 10
SECTION 1 - CHEMICAL PRODUCT AND aJlPANY IDENTIFICATION
MSDS PREPARED BY: Environmental
W.R.Grace & CO.-Conn.
62 Whittemore Ave.
Cambridge. MA 02140
Teleohone
In USA: (617) B76-1400
Health Deot.-Grace Construction Products
W. R. Grace & Co. of Canada Ltd.
294 Clements Rd. West
Ajax, Ontario. LIS 3C6
Number for Information and Emeraencv Resoonse
In Canada: (416) 6B3-B56l
"SDS NUlIber: HP-90045 0??oo1
Cancels MSDS # MP-90011
Date: 07/17/1995
Trade Na~s and SynonYms:
(SEE SECTION 16 FOR ADDITIONAL
PRODUCT IDENTIFICATION)
!fA TER REPELLENT AIlMIxnJRES
Chemical Names and Famllv:
Product Use:
Masonry Dispersion
Masonry Water Repellent and Strength
Enhancer
Mixture-NA
MIXTURE-NA
Formula:
CAS# (Chemical Abstract Service):
SECTION 2 - HAZARDOOS INGREDIENT AND MAJOR <D4PONENT INFORMATION
(See Section 11 for Coaolete Che.tcal N~s)
EXPOSURE UIlITS (See Sect;on 8 for YD.!;" L;mts)
Exposure Lim; ts
ACGIH
None Established
Max. ~
8v Wt.
2.00
OSHA
None Established
OTHER
None Established
INGREOIENT:
BENZENESULfONIC ACIO...
CAS# 25155-30-0
OIETHANOLAMINE 1.00 3ppm - TWA 3ppm - TWA NIOSH-REL
CAS# 00111-42-2 115 mg/~ I (13 mg/,} ) 3ppm
FORMALOEHYOE 0.25 O.5ppm(act;on level) 0.3 ppm Ceiling NIOSH-lowest
CAS# 00050-00-0 0.75ppm-TWA Limit feasible level
2.0ppoo-STEL
TRIETHANOLAMINE 10.00 None Established 5.0 ppm - TWA None Established
CAS# 00102-71-6
MP-90045
MATERIAL SAFETY DATA SHEET
Page 2 of 10
SECTION 3 - HAZARDS IDENTIFICATION
Emeraencv OVerview:
Harnlna Statements:
HARNING! CAUSES IRRITATION. MAY BE HARMFUL IF SWALLOHED.
Contains one or more of the following Ingredients: Triethanolamine
CAS# 102-71-6, Dlethanolamlne CAS# 111-42-2, Benzenesulfonlc Acid
DOdecyl Sodium Salt CAS# 25155-30-0, Formaldehyde CAS# 50-00-0 and
Hater CAS# 7732-18-5. May contain Nonhazardous Ingredients
Registered as Trade Secret In New Jersey; TSRN #80100041-5010P,
5015P, 5018P and 5041P.
Irritating to eyes, skin or respiratory system.
Repeated skin contact or inhalation may cause sensitization.
May be harmful if swallowed.
Possible cancer hazard based on the Formaldehyde content.
Overexposure by ingestion may cause liver and kidney damage.
NPCA-HMIS Hazard Index:
o Health: 2
o Flammability: 1
o Reactivity: 0
o Personal Protection: B
(See Section 8)
*
Potential Health Effects
Routes of EXDosure:
Inhalation:
This product contains a small amount of Formaldehyde. Formaldehyde
is considered to have good early warning properties due to Its
pungent odor. Because the amount in the product is small and vapors
are easily detected by smell at levels of 0.8ppm or higher, exposure
can be minimized, Formaldehyde vapors may irritate nose, throat,
mouth and mucous membranes causing coughing, breathing difficulty and
in severe exposures, pulmonary edema. A small portion of people may
experience an allergic respiratory reaction (wheezing and chest
tightness) upon repeated exposure. Laboratory tests indicate that
overexposure to formaldehyde may produce reproductive or mutagenic
effects.
MP-90045
MATERIAL SAFETY DATA SHEET
Page 3 of 10
SECTION 3 - HAZARDS IDENTIFICATION (Can't)
Skin and Eve:
Vapors may Irritate eyes causing tearing and redness. EYE contact
with solution can cause Irritation and slight reversible corneal
injury.
Prolonged contact with SKIN may cause Irritation resulting In
dermatitis. Skin sensitization may occur In a small portion of
exposed persons. Repeated contact can result In an allergic reaction
such as rash or hives,
Inaestlon:
Swallowing may irritate mouth, throat, and stomach causing pain,
nausea, vomiting and diarrhea. Liver and kidney damage from chronic
overexposure has been demonstrated In laboratory animals.
Carcinoaenicltv Accordina to NTP. IARC and OSHA:
The following information is
of this product only: NTP:
IARC:
OSHA:
applicable to the Formaldehyde content
Suspect Animal Carcinogen
Group 2A Probable Carcinogen
Potential Cancer Hazard
Other Effects of Overexoosure:
This product contains amines which may react with nltrosatlng agents
to form nltrosamlnes. Some nltrosamines have been shown to be
carcinogenic In laboratory animals.
2180f
Skin and Eve:
Vapors may irritate eyes causing tearing and redness. EYE contact
with solution can cause irritation and slight reversible corneal
injury.
Prolonged contact with SKIN may cause irritation resulting In
dermatitis. Skin sensitization may occur In a small portion of
exposed persons. Repeated contact can result In an allergic reaction
such as rash or hives.
Inaestlon:
Swallowing may Irritate mouth, throat. and stomach causing pain.
nausea, vomiting and diarrhea. Liver and kidney damage from chronic
overexposure has been demonstrated in laboratory animals,
Carcinoaenlcltv Accordlna to NTP. IARC and OSHA:
The following Information Is
of this product o~ly: NTP:
IARC:
applicable to the Formaldehyde content
Suspect Animal Carcinogen
Group 2A Probable Carcinogen
MP-90045
MATERIAL SAFETY DATA SHEET
OSHA: Potential Cancer Hazard
Page 4 of 10
Other Effects of Overexoosure:
This product contains amines which may react with nitrosating agents
to form nitrosamlnes. Some nitrosamlnes have been shown to be
carcinogenic in laboratory animals.
2l80f
SECTION 4 - FIRST AID MEASURES
EYE: In case of contact. immediately flush eyes with plenty
of water for at least 15 minutes holding eyelids apart.
See a physician.
SKIN: Immediately flush skin with plenty of water. If
irritation develops. consult a physician. Remove
contaminated clothing and wash before reuse.
INHALATION: If Inhaled remove to fresh air. If not breathing, give
artificial respiration. If breathing is difficult give
oxygen, Get medical attention immediately.
INGESTION: If swallowed. induce vomiting as directed by medical
personnel. Never give anything by mouth to an uncon-
scious person. Get medical attention immediately.
SECTION 5 - FIRE FIGHTING MEASURES
Flash Point: Not Determined
Method Used: (Aqueous System)
N.F.P.A. Ratlna: H-l F-l R-O
Flammable Limits:
1El N.A. Ufl N.A.
Extinauishina Media
Product Is an aqueous solution and is unlikely to burn until all
the water has been evaporated. In case of fire use water. dry
chemical or C02'
Soecial Fire Flahtlna Procedures
Cool exposed containers wIth spray. Self-contained breathing.
apparatuses should be worn in confined areas.
Unusual Fire and Exolosion Hazards
None Known
MP-90045
MATERIAL SAFETY DATA SHEET
Page 5 of 10
SECTION 6 - ACCIDENTAL RELEASE MEASURES
U.S. RELEASES
Prevent product from entering drinking water supplies or streams.
Observing precautions above. collect liquid or absorb with an inert
noncombustible material and remove for disposal.
Spill reporting requirements and reportable quantities vary by
region. In case of any spill or release. consult sections 6 and 15
of the MSDS and all applicable state and local regulations.
CANADIAN RELEASES
Prevent product from entering drinking water supplies or streams.
Observe precautions above. collect liquid or solidify liquid with an
Inert, noncombustible material and remove for disposal, Dispose of
all waste In accordance with applicable government regulations.
SECTION 7 - HANDLING AND STORAGE INFORMATION
Precautlonarv Measures:
..,Avoid contact with eyes. skin and clothing.
...Hash thoroughly after handling.
...Avoid breathing vapors or spray mists.
.. .Use with adequate ventilation.
...For professional use only. Keep out of children's reach.
...Keep container closed when not in use.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION/CANADIAN EXPOSURE LIMITS
Ventilation:
Local Exhaust:
Mechan I ca I :
Special:
Other:
Recommended when
Recommended when
Not Applicable
Not Applicable
appropriate to control exposures.
appropriate to control exposures.
Resoiratorv Protection:
A NIOSH approved respirator for Formaldehyde vapor Is required when-
ever exposures exceed the limits specified In Section 2 of this MSDS,
For additional Information refer to US OSHA regulation 29 CFR
1910.1048 Formaldehyde (g)(2). Respiratory Section or other
applicable regulations.
For individuals who choose to wear a respirator below regulated
limits. a NIOSH approved respirator with cartridges for organic
vapor or Formaldehyde with a prefilter for mists Is recommended.
MP-90045
MTERIAL SAFETY DATA SHEET
Page 6 of 10
SECTION 8 - EXPOSURE <DfITROLS/PERSOHAL PROTECTION/CANADIAN EXPOSURE LIMITS (Con' t)
Skin Protection:
Impervious rubber gloves should be worn to prevent prolonged or
repeated contact.
Eve Protection:
Wear goggles (or full-face respirator) to protect against vapors and
splashIng.
Other Protective Clothina or Eauioment:
Wear appropriate clothing to prevent skin contact.
Work/Hvaienic Practices:
Use good hygiene practices and observe above precautions.
Special Note: This product contains a small Quantity of ethoxylated
compound, Trace Quantities of ethylene oxide may be present as a
result. Ethylene Oxide vapor may build up in the head space of
storage containers or tanks. The possibilIty of exposure to Ethylene
Oxide vapor above the OSHA action level(0.5ppm) must be addressed
during non-routine tasks such as cleaning of storage tanks. Consult
the OSHA Ethylene Oxide Standard 29 CFR 1910.1041 for appropriate
procedures.
P.",,;ndal Exposu", L;,rits
B.C.
2ppm..8 hr
Inor@<dif!'nts
FORMALoEHYOE:
ACGIH
lppll _ TWA
2ppa>-STEL
ALBERTA
ONTARIO
1 p,...TWAEV
2p.......STEV
2pptn CoEL
OIETHANOLAMINE:
3pptn
3pptn BhrOEL
6pp'" COEL
3p.......TWAEV
TRIETHANOLAMINE:
O.5ppm(proposedl
AIRBORNE MIST:
10 Ilg/M 3
1235f
OUEBEC
2pJ1111-8 hr
2pfllll'4&X
MP-90045
MATERIAL SAFETY DATA SHEET
Page 7 of 10
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Botlina Point: Not Determined
Soecific Gravltv(H20.1) Appox. 1.2
1 Volatiles Appox. 60
(As Hater)
Vaoor Pressure (mm Ha.) Appox. 55
Solubilitv in Hater: Complete
Bulk Densitv (#/cu. ft): Not Applicable
Evaooration Rate Not Determined
(Butyl Acetate. 1)
gH Appox. 9.0
Vaoor Densitv(AIR - 1) Not Determined
Aooearance and Odor: Milky white dispersion.
Odor Threshold:
O.B ppm (As Formaldehyde)
SECTION 10 - STABILITY AND REACTIVITY
Stable under normal conditions (ves or no): YES
Conditions or Materials to avoid (which mav react or cause lnstabilitv):
Avoid contact with strong oxidizing agents and acids.
Hazardous Decomoosition or Bvoroducts:
If dried and burned CO. C02. Nitrous Oxides and Sulfur Dioxide,
Hazardous Polvmerizatlon:
Hill not occur.
Conditions to Avoid:
None Known
MP-9004S
MATERIAL SAFETY DATA SHEET
Page 8 of 10
SECTION 11 - TOXICOLOGICAL INFORMATION
INGREDIENT TOXICITY'DATA: LDSO & LCSO
(Chemical Name,
CASH. & Common Name) (See Section 2 for EXDosure Limits)
CONTAINS ONE OR MORE OF THE FOLLOHING INGREDIENTS:
FOrllilldehyde
CASH 00050-00-0
LDSO (oral, rat) 800 mg/kg
LDSO (skin, rabbit) 270 mg/kg
LCSO (inhalation, rat) 590 ppm
LDSO (oral, rat) 710 mg/kg
LDSO (Oral, Rat) 8 g/kg
LDSO (Oral, Rat) 1,260 mg/kg
Dtethanola11tne
CAS# 111-42-2
Trtethanola11tne
CASH 102-71-6
Benzenesulfontc Actd. Dodecyl-,
Sodtu. Salt CASH 25155-30-0
ll46f
SECTION 12 - ECOLOGICAL INFORMATION
None Available at This Time
SECTION 13 - DISPOSAL CONSIDERATIONS
U.S. DISPOSAL
According to the US EPA (40 CFR 261.3) waste of this product is not
defined as hazardous. However, individual ingredients may be subject
to local disposal restrictions. Dispose of waste in accordance with
all applicable local. state and federal regulations.
CANADIAN DISPOSAL
...Dispose of waste in accordance with all applicable government
regulations.
MP-90045
MATERIAL SAFETY DATA SHEET
Page 9 of 10
SECTION 14 - TRANSPORT INFORMATION
United States DOT
PROPER SHIPPING: Not Applicable
~
HAZARD CLASS:
IDENTIFICATION #:
LABELls) REDUIRED:
Tran5DDrtat;an 1b7.:1n1 ClU5;ficat.illll
Canadian R.aulat;Dn~
TOG CLASS: Not Applicable
Nonhazardous
Nat App H cab Ie
Not AppHcable.
Surface Freiaht Classification: Concrete or Masonry Plasticizer
(Not Meant To Be All Inclusive
SECTION 15 - REGULATORY INFORMATION Selected Reaulations ReDresented)
SARA TITLE III REPORTING INFORMATION
Tier I & II HAZARD CATEGORIES: DELAYED (CHRONIC) HEALTH
IMMEDIATE (ACUTE) HEALTH
Contains Extremelv Hazardous-SARA III Section 302 Inaredient: NO
Comments: Contains less than lt Formaldehyde: NOT REPORTABLE
Contains Toxic Chemical Release-SARA III Section 313
Comments: Contains less than 0.25t Formaldehyde:
Contains less than lt Diethanolamine:
Inaredient: YES
REPORTABLE
NOT REPORTABLE
other Govern~nt Reoortlna Reaulrements:
CHEMICAL INVENTORY CERTIFICATION:
All ingredients contained in this product are included on the US EPA
Toxic Substance Control Act (TSCA) Inventory or exempt from listing
on the TSCA Inventory.
All ingredients contained in this product comply with the ReqUirements
of the Canadian Environmental Protection ACT (CEPA) and are listed on the
uomestic Substance List <OSL>.
CERCLA HAZARDOUS SUBSTANCES: Formaldehyde is listed as a reportable
substance with a Reportable Quantity (RQ) of 100 lbs. Based on the
maximum possible Formaldehyde content. a 900 gallon spill of product
would equal the RQ, Report such spills to the National Response
Center (800-424-8802, the SERC and the LEPC.
PENNSYLVANIA lists Formaldehyde as a special and environmental hazard.
2178f
MP-90045
MATERIAL SAFETY DATA SHEET
Page 10 of 10
SECTION 15 - REGJLATORY INFORMATION (Cant'd)
MHMIS CLASS: D-2A
ThIs product has been c1asslfed in accordance
of the Controlled Products RegulatIon (CPR).
informatIon requIred by the CPR.
(Not Meant To Be All InclusIve
Selected Reaulatlons ReDresented)
wIth the Hazard CrIteria
ThIs MSDS contaIns all the
STATE SPECIFIC EMERGENCY RELEASE REQUIREMENTS:
Some chemicals contaIned in this product, such as Formaldehyde.
and Benzenesulfonic AcId Dodecy1 SodIum Salt, have state regulated
reportable quantitIes whIch are more strIngent than the federal
requ! re~,!,;::!t$:loted above. Due to the comp 1 ex and dynaml c nature of
these regulatIons, it Is not possible to provIde a complete summary.
You should contact the Environmental Protection if product
is released to the land or water.
CALIFORNIA PROPOSITION 65 Informat1on: HARNING: ThIs product contaIns
chemicals known to the state of CalIfornia to cause cancer, bIrth
defects or other reproductive harm.
2320f
SECTION 16 - OTHER INFORMATION
The informatIon contained in thls Material Safety Data Sheet Is applicable to
the following products:
Hater Repellent Admixtures
Multi Pave
Best Tuff
Control
Darapel
Dry Block Block Admixture
Dry Block Mortar AdmIxture
For Cast
Hydro Pe 1
"THE DATA INCLUDED HEREIN ARE PRESENTED ACCORDING TO w. R. GRACE & CO.-CONN's PRACTICES
CURRENT AT THE TIME Of PREPARATION HEREOf, ARE HADE AVAILABLE SOLELY fOR THE
CONSIDERATION, INVESTIGATION AND VERIfICATION Of THE ORIGINAL RECIPIENTS HEREOf AND DO
NOT CONSTITUTE A REPRESENTATION OR WARRANTY fOR WHICH GRACE ASSUMES LEGAL
RESPONSIBILITY. IT IS THE RESPONSIBILITY Of A RECIPIENT Of THIS DATA TO REMAIN
CURRENTLY INfORMED ON CHEMICAL HAZARD INfORMATION, TO DESIGN AND UPDATE ITS OWN PROGRAM
AND TO COMPLY WITH ALL NATIONAL, fEDERAL, STATE AND LOCAL LAWS AND REGULATIONS
APPLICABLE TO SAfETY, OCCUPATIONAL HEALTH. RIGHT-TO-KNOW AND ENVIRONMENTAL PROTECTION."
7700 High Ridge Road
Boynton Beach. Florida USA 33462
(561) 533-1450 (800) 782-7399
(561) 533-1500 FAX
www.kilpatrickco.com
"Specialists in Irrigation, Landscape, Turf Care, Industrial Products & Equipment in Florida, the Caribbean and Latin America"
oo~
@ ~ 0 \Yl rn
:,27/9)Cj
w'
PLANNING AND
ZONING DEPT
~ arch 30, 1999
Mr. Richard C. Ahrens
President and CEO
Ahrens Companies
3750 Investment Lane, Suite 2
West Palm Beach, Florida 33404-1765
Dear Richard:
This will serve as our permission for you to use a picture(s) of our building and
the basic building/lot statistics in your company's web page for purposes of promoting
your company in the construction industry. Further, you may use the following
testimonial to accompany the picture(s) and building/lot statistics.
"Ahrens Companies constructed our 40,000 square foot warehouse/office building
to house the growth and expansion of our 40 year old irrigation and turf equipment
business in south Florida. Aesthetically and functionally, the building is proving to be
what we hoped it would be, and it has drawn favorable commentary from the commercial
and industrial community. We chose Ahrens Companies over other interested companies
to construct our building because of our belief that they would provide the best product
within the time requirements; and, they can take pleasure in knowing they substantially
fulfilled those criteria."
1=1 BOYNTON PUMP &
.. IRRIGATION SUPPlY
II] KISCO Pifer
- KILPATRICK
liII TURF EQUIPMENT