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APPLICATION PROJECT NAME Packaging Concepts LOCATION Lots 47, 47B, 47C, and 47D COMPUTER ID 00-5500001 PERMIT #. I FILE NO MSPM 01-001 I TYPE OF APPLICATION Major Site Plan Modification AGENT/CONTACT PERSON OWNER/APPLICANT Winston Lee, ASLA, AICP/winston Lee & PJM and Associates, L.C Associates, Inc. PHONE 561-364-0014 PHONE 561-689-4670 FAX. 561-364-7135 FAX. 561-689-5559 ADDRESS 4925 Park Ridge Blvd. ADDRESS 1532 Old Okeechobee Boynton Beach, FL 33426 Road #106 West Palm Beach, FL 33409 PM;7. I l. ,. "''''-+0'''' L'A. @ 0..0 I. c..oM Date of submittal/Projected meetine: dates. SUBMITTAL / RESUBMITTAL 01/09/01 1ST REVIEW COMMENTS DUE 01/26/01 PUBLIC NOTICE N/A TRC MEETING 02/20/01 PROJECTED RESUBMITTAL DATE N/A ACTUAL RESUBMITTAL DATE N/A 2ND REVIEW COMMENTS DUE N/A LAND DEVELOPMENT SIGNS POSTED N/A (SITE PLANS) PLANNING & DEVELOPMENT BOARD 03/27/01 MEETING CITY COMMISSION MEETING 04/03/01 COMMENTS \\CH\MAIN\SHRDA TA\Planning\SHARED\WP\PROJECTS\Quantum Park Lot 47 (Packaging Concepts)\MSPM 01 -001 \PROJECT TRACKING INFO.doc ..,ITY OF BOYNTON BEACH, FLl PLANNING & ZONING DIVISION SITE PLAN REVIEW APPLICATION FOR NEW SITE PLANS & MAJOR MODIFICATIONS TO EXISTING SITE Application Acceptance Late Fee Paid Receipt Number' ThIS application must be filled out completely accurately and submitted as an original to the Planning an~ Zoning Division TWELVE COMPLETE, sequentially numbered ASSEMBLED AND STAPLED sets of plans including a recent survey and appropriate fee shall be submitted with the application for the initial process of the Site Plan Review procedure AN INCOMPLETE SUBMITTAL WILL NOT BE PROCESSED Please print regibly (in Ink) or type ail information GENERAL INFORMATION 1 Project Name packinq Concepts Expansion 2 Applicant's name (person or business entity in whose name this application is made) PJM & Associates, L.C. Address 4925 Park Ridge Blvd., Boynton Beach, FL 33426 (Zip Code) Phone 561-364-0014 Fax: 561-364-7135 3 Agent's Name (person if any representing applicant) Wins ton Lee, ASLA, AICP Winston Lee & Associates, Inc Address 1532 Old Okeechobee Road #106 wP~t P;dm Rp~("'h, FT. 1140Q (Zip Code) Phone 561-689-4670 Fax: 561-689-5559 4 Property Owner's (or Trustee's) Name PJM & Associates, L. C. Address 4925 Park Ridge Blvd. Boynton Beach, FL 33426 Phone 561-364-0014 Fax: 561-364-7135 (Zip Code) 5 Correspondence to be mailed to agent only; if no agent, then to applicant unless a substitute is specified below'* *This is the one address to which all agendas, letters and other materials will be mailed 6 What is applicant's interest in the premises affected? (owner, buyer, lessee, builder developer, contract purchaser, etc.) Owner 1 J / ./ / ./ I 7 8 Street address or location of site 4925 Park Ridge Rlvn , "Rnynt-rm Beach, Florida 33426 08-43-45-20-000-0000 and 08-43-45-17-10-000-0475 Property Control #. Lot 0475 has not yet been ass i gnpn ;:! p~n hy pR(' Legal description of site SP-P- t=lttt=l~hpn Rvhi bi t "A" 9 Intended use(s) of site Tnnll~t-ri~l IWt=lrphnll!,::p/Distribution , 10 Developer or Builder' See attached Exhibit "B" for development team consultants/members. 11 Arch itect: 12 Landscape Architect: 13 Site Planner' 14 Engineer' 15 Surveyor' 16 Traffic Engineer' 17 Has a site plan been previously approved by the City Commission for this property? Yes. Site plan NWSP 95-007 approven hy rity rnmmi~5ion 9/19/95. 18 Estimated construction costs of proposed improvements shown on this site plan Approximately $1.680,000.00 II SITE DATA The following information must be filled out below and must appear, where applicable on all copies of the site plan 1 2. 3 4 c. d e f g Land Use Cateqorv shown in the Comprehensive Plan Tnnll!'::tri;:! 1 Zoninq District P. T n Pl t=lnnE'O Innllstri t=ll Development. ni !'::tri C"t- Area of Site 3.65+ acres 158. q7E; 28 . Land Use -- Acreaqe Breakdown sq ft. a Residential including 0 acres 0 % of site surrounding lot area of grounds Recreation Areas * 0 acres 0 % of site (excluding water area) Water Area .48 acres 13. 1 % of site Commercial 0 acres 0 % of site Industrial 3.17 acres 86 9 % of site b Public/lnstitutional o acres % of site o Public, Private and Canal rights-of-way o acres o % of site Planning and Zoning Division - Rev 10/15/1998 J'\SHRDA T A IPLANNING\SHAREO\WP\FORMSIAPPS\NWSP\SITEPLAN, DOC h Other (specify) o acres o % of site Other (specify) o % of site o acres Total area of site 3.65 acres 100 % of site .. Including open space sUitable for outdoor recreation and having a minimum dimension of 50 ft. by 50 ft. 5 Surface Cover a Ground floor building 1.24 acres 33.8 % of site area ("building footprint") b 48 acres 1 3 . 1 % of site Water area c Other impervious areas including paved area of public & private streets paved area of parking lots & driveways (excluding landscaped areas) and sidewalks patios decks, and athletic courts _ gO acres 1.4 R % of site d Total impervious area ~ acres 58.6 % of site e Landscaped area . 1 0 acres 2 7 % ofsite inside of parking lots (20 sq ft. per interior parking space required - see Sec 7 5-35(g) of Landscape Code) f Other landscaped areas,~ acres % of site 25 6 g Other pervious areas, including golf course natural areas, yards and swales but excluding water areas 0 acres 0 % of site h Total pervious areas ~ acres 41 4 % of site Total area of site 3.65acres 100 % of site 6 Floor Area d e f 9 a. Residential 0 sq ft. Commercial/Office 0 sq ft. I ndustriallWarehouse 51 . ~n8 sq ft. Recreational 0 sq ft. Public/Institutional 0 sq ft. Other (specify) 0 sq. ft. Other (specify) 0 sq. ft. b c. Planning and Zoning Division - Rev 10/15/1998 J:\SHRDA T A\PLANNING\S HARED\WP\FORMS'APPS\NWSP\SITEPLAN. DOC h Total floor are2 -~ -. SA.838 sq ft. 7 Number of ResIdential Dwellinq Units a Single-family detached 0 sq ft. b Duplex 0 sq ft. c Multi-Family (3 + attached dwelfing units) (1) Efficiency 0 dwelling units (2) 1 Bedroom 0 dwelling units (3) 2 Bedroom 0 dwelling units (4) 3+ Bedroom 0 dwelling units d Total multi-family 0 dwelling units e Total number of dwelling unIts 0 8 Gross Density N / A dwelling units per acre 9 Maximum heiqht of structures on site 27' feet : 450 ----/ stories 10 Required off-street oarkinq a Calculation of required b number of off-street parking spaces 1 1/2 spaces per employee (maximum of 60 employees per shift), plus 15 vlsi'Cor spaces = 60 spaces Off-street par~ing spaces provided on site plan 84 oarkinq spaces Representative of the project must be present at all Technical Review Committee, Planning and Development and City Commission meetings held to review this project Planning and Zoning Division - Rev 10/15/1998 J:\SHRDA T A\PLANNING\SHARED\WP\FORMS\APPS\NWSP\SITEPLAN.DOC /212-'2... I 10 C.0 1-55_-583-5559 WINSTON LEE PAGE 04 RIDER TO SITE PLAN APPLICATION The undersigned as applicant for Final Site Plan Approval does hereby acknowledge represent and agree thai all pl:ans. specifications, drawings, engineering, and other data submitted with this application for review by tt-,e City of Boyntor: Belich shall be reviewed by the variOUS boards, commissions, staff personnel and other partie~ designated, appointed or employed by the City of B:Jynton Beach, and any such party reviewing the Same sha! rely upon the accuracy thereof and any change in cny item submitted snail be deemed material a;-jd substantial The undersigned hereby agrees that all plar.! specifications drawings, engineenng ar.d other data whlct may be approved by the City oCSoynton Beach, or its boards, commissions, staff or designees shall bE constructed in strict compliance with the form in which they are approved, and any cha1ge to the same shall bE deemed material and snail place the applicant In violation of this appl,~:on and all aF=provals and'permits whid may be granted. The applicant agrees to allow the City of Boynton Beach all rights anc remedies as prov;ded for by thE applicable codes and ordinances of the City of Boynton Beach to bring any violation into compliance, and thE applicant shall indemnity, reimburse and save the City of Boynton Seach harmless from any cost, expense, claim liability or any action which may arise due to their erforcement 01 the same. a::;C~AGREEDTOthi.~f 5:: v~~~6er .~O Witness ~ App cant r ) PH ILl ~ rilE S H B~ tAA Ar(.uJCi ~ 'J t-A erA. e E.fl.- F Dell. ..f>.J M ~ A ~Sl)tl ~ re.5.> L C PlannIng and Zoring Division. Rev 10115/199B J:\SHROAT AIPLANNl NGISKARED\WP\FORMS\APPS\JNtISP\S ITEPLAN.OOC EXHIBIT " A" PJM at Quantum Park as recorded in Plat Book 76, Page 50, Public Records of Palm Beach County, Florida. Together with The south 71 53 feet of Lot 47B, less the west 8512 feet, together with lots 47C and 470, less the west 8512 feet of lots 47C and 470, of Quantum Park at Boynton Beach, P I 0 Plat No 10, according to the map or plat thereof as recorded in Plat Book 60, Page 34, Public Records of Palm Beach County, Florida. EXHIBIT 'B' QUANTUM PARK LOT 47, 47B, 47C &470 DEVELOPMENT TEAM/CONSULTANTS Property Owner/Developer: PJM & Associates, L.C 4925 Park Ridge Blvd Boynton Beach, FL 33426 Mr Philip Meschberg Phone 561-364-0014 Fax 561-364-7135 Architect! Agent: Jeff Gapstur Architectural Design Associates 11000 Prosperity Farms Rd #102 Palm Beach Gardens, FL 33410 Phone 561-626-7381 Fax 561-626-8466 Landscape Architect/Agent: Winston Lee & Associates, Inc. 1532 Old Okeechobee Road, #106 West Palm Beach, FL 33409 Phone 561-689-4670 Fax 561-689-5559 Surveyor: David Lidberg Lidberg Land Surveying, Inc. 675 West Indiantown Road #200 Jupiter, FL 33458 Phone 561-746-8454 Fax 561-575-3735 Engineer - Civil. Cherrie Sova Civil Scientific, Inc. 4047 Okeechobee Blvd #221 Phone 561-689-9878 Fax 561-689-6068 Engineer - Traffic Pinder Troutman Consulting, Inc. 2324 S Congress Ave , Suite 1 H West Palm Beach, FL 33406 Phone 561-434-1644 Fax 561-434-1663 Environmental Consultant: David Nickerson Environmental Services, Inc. 1001 North U S Highway 1 Suite 304 Jupiter, FL 33477 Phone 561-743-5141 Fax 561-743-5441 * / PACKAGING M.PAK. MARKETING SOLUTIONS CON C E PTS ASSOC., LLC CO"llCEPTIOI'o . PATE~T PROTECTIO"II . PROTOTYPES . MANL"FACTlJRING . E'liGINEERI!\G . COSTING . FINISHED PRODl CT January 5,2001 To Attentlon. City of Boynton Beach Michael W Rumpf AFFIDAVIT To the best of my knowledge, the maxnnum number of employees at the greatest shrft at buildout for the project will be sIXty (60) enrus M. Bleakley Vice PresIdent, Fin STATE OF FLORIDA COUNTY OF PALM BEACH Sworn to and subscribed before me tIns 5th day of January, 2001, by Denrus M. Bleakley, personally known to me, as Vice President of Finance for Packaging Concepts Assoc., LLC .~T'~ JENNI Y ACHELSON ,W.6 MY COMMISSION;; ex: 875582 ~ Of f\~ EXPIRES: Sep 30.]003 t.aoo.:t-NOTARV Fla. Howry SMVIGI' BoncIII'ID Co. ~ "LEAD TD SUCCEED" 4925 Park Ridge Blvd. . Boynton Beach, FL 33426 · Po. Box 4690, Boynton Beach, FL 33426 (561) 364-0014 Or Toll Free: (800) 881 MPAK . Fax: (561) 364-1480 Visit Us On The Web @ www.packagingconcepts.com 131-11-1996 05 36PM . ~l=lND.REW B BLASi P A 1~3404~ P ~ TO APR-07-1995 U Jl!M 95-1.07399 ORB 8692 p, 336 I ......._ ... _11._... Con gS,OOO.OO Ooc {,OtS.GO SPECIAL WARRANTY DEED ~ ( . :I'HIS SP:E:CD\L wARRAN"l'Y DEED, executed as of the ..3rA.).. day of , 1995, by Q~ ASSOCrATES a Florida ~eneral :. part rsh.i.p the "Grantor"), whose mailing address is 115 West ~ Washington Street, Ind1anapolis, Indiana 46204 to PJM & ASSOCIATES, i L C. I a Flo;z;-ida L:lmited Liability Company (the II <:;ranteeU ) I whose .~ mailing address is 2770 South Ocean Boulevard, Suite 602 Southc Nt,.. PalV' hacb, f'lo.~Q" ~~4ao ~ lI: J:'" ; ,r~ all ~~i~~ ~~..;~ :~. ~.. t'. , :~: t~ 1; \.'..~ r; t ~~J;~~ 'J\.': WI': ,:II: ,~.-:; ..,. <! t: ~ ~ r.: '-~ WITNESSETH That Granto~, fo. and in consid$raeion of the sum of Ten Dollars ($10 OO) and other Soccl and valuable consideration to Grantor in hand paid by Grantee, the receipt and sufficiency of wh:i.ch i. hereby liloknow1edged, has granted, ba~ai.nec;1, 4UlQ &01.<3. to Grantee and Grantee f" heir" and assigns forevE::r, the follow.i.ng' described rea1 property situate, lying, and being in ~alm Beach County, Florida (the IIProperty"); to wit 51!:B LEGAL DBSCRIPTION ATTACHED HERETO AS ExtUDTT liAR WHICH IS HE:R.:sBY MADE A PART HEREOF TO HAW AND TO HOLD the s.m~ in fee !Simple forever. This conveyance is made SUBJECT TO the following 1 Ad valorem real property taxes tor the year 1995 and Gubeequent years 2 Restrictions and matters appearing on the recorded plat of the Property. 3. There shall be no access to and f~o~ any portion of the Prope.rty which shares a common boundary wi th Park Rid.ge Boulevard excep~ as described on Exhib.i t "A -111 ~h;h;r. 4 . Those matters of record as specitically set forth in liB" att~ehed hereto and made a part hereof And Grantor covenants with Grantee that, except as above noted, at the time of the delive~y o~ this deed said property was free from all encumb:ranoes made by Grantor, and that Grantor hereby' Specia11y warrants the title to said property and will defend it &gainat the lawful ol.airMI of all pe'rl!ons claimi.ng hy, through, or under Grantor, but not otherwise ALL APPLICABLE FLORIDA DOCUMENTARY STAMPS HAVE trSEN ATTACHED TO - THIS DEED p'p4~k0206 clo3docs cd Wd10 ~ 000c 61 'oao "ONX\:J..:l ,,31>ttBla: W 5 I NN30 WOCI..:l "'.&0' J..&o' JU .L I 1...JL.. IIflUI llfU..J.J..A.I I 01-11-1996 ffi ~M I=ROM ~ B. BLASI P A TO 1~3340405999 P 03 ORB a6~.2 P9 337 IN WITNESS WHEREOF, Grantor has executed this deed as of the day an,d year fir.t above written Signed.. sealed, and delivered iLR:sel?(=f S -n;:v..-J e ---rIe/11iZ..- 1"Ty);>e or pr:1nt name) QUANTOM ASSOCIATES, a Florida general partnership t'J,~w/ tf,' ~ , ~~U/ /!. $~4- (Type or pr~nt name) By QUANTUM SIMON t :tHe i an Indiana corporation, genera~ artne By Melvin Simon President STATE OF INDIANA ) ) SS: } COtlNTY OF MARION J~ I The~'nq instrument was acknowledged before me th~s ~ day of , 1995, by Me1vi.n Si.mon, as PreBide~t of Quantum Sim , Inc., an Indiana corporation, as general part;~er: of Quantum Assoc1.ates, a Florida general partnersMp, on DeAAHhaf-..,. "he P'tttnership, who i. personally known "0 m~ (\~"" ., 1- ,..::.,~~.,~ ;:7 ~~, ..I.l)r;!(~' . : Sttlt..lbf -::r; 1!.Ji~ -".~.~-_. \ ,/,'~ (Print ?r type name~; '?[.I"'/~:;~~-: My ComnlJ.ssion Expi.re .~,:, County of Residence: . . [Official Notarial Seall Tbis Inst.n__t. fqaa P~I'OCI B':/ I S~e_ Il. rk~, El.. 115 ~.t. Ma8hin,~on 5~...C I"1.".~b. Illdiana tU04 UjtO/l "-l'Cl4ItJ.on th1a In3tnment -lCl .,. &"$tvrned tq <rAnt... P~rty ~a1_r!t Parcel 1~.!m~v.k~17~~~~ODb" bV71 kt:~~ 1J~t/~.gsrr~' ALL APP.LICABLE: FLORIDA DQC'OMENTARY STAMPS HAVE BEEN ATTACHED 'X'O ,. THIS DEED l:d Wd10 T0 000G 61 'o03a "ON xt1.:1 ,J,3I>ttBl8: W 5 I NN3a ~.:1 U~t ~~tU~ ~I uu 01-11-1996 05 3?PM .....,,~, FROM l=lNDREW S SLASI P A TO 1203334040:>9$ P04 ORB B~92 pg 338 Le~al Description ~ A tnlet ofland lying wlthln a ponion of Lots 47A 'and 478. QUANTUM PARK. Ai aOYNTON BEACH. P 1.0. PLAT NO. 10, acc:orc:ling to the Plat lhe~eof. as Tet:Ortkd in Phat Book 60. Pap 34 of the Public Records of Palm Beach County, Florida. Said lands being more particularly described as follows: cornmencing 8t the Southeast comer o(uid Lot 478. thence N 0."09'0;" E., along the East line o(.-;.d Lot 47B. 11.SS feet to the Point of Beginniftg; Thence N 8S",SO'S4" W. (parallel with and 7t.S3 feet North of (as measured at right angles) the South line of said Lot 47B1 a distanee of 20799 feet to a point 114 J3 feet EaSt or (as meausred at nght 8n~les) the West line of said Lot 418; thence N OJ"M'OS. Eo along a Hne pat3Uel with and 114 13 feet (as measund at right an~les) Ea~t o.fthe West line ofssid Lot 47B and Lot 47A. 11 distance of301 99 feet to a point on a eurve at which point the radtal line bears S 05"28"07" E. said curve to the Northeast coincident with the North line of Lot 47A, having a radius of 2944 I g f~ a central ancle of 03'32"54", a chord bearing ofN 86'18'20" E, a ~hord distance ofl82.30 feet and an arc length of 182.:t3 f~ thence S 4S"'23t04" E along the boundary line of said Lot 47A. a distance of 36.29 feet; thence S 01"09'05" W, along the East line of said Lot 47 A. a dist4nee of 292.43 feet to the Point of Beginning. - ... EXHIBIT " A If t7d WdG0"rn 000G 61 'oaG "ON ~3 .-\3I>tl:B1B W 5 I I-../N3G WOcH I Winston Lee ASSOcIateS., Inc. ill u w m@ ,-" J~9 .f "f:li~ 'kt':'q PLANNING AND ZONING DEPT L,lld"'lJ'c \1 .! lit' .WI L.mLl I'laJlrWl~ I ~ I I ( ( January 9, 2001 Mr Michael Rumpf Planning & ZOning Division City of Boynton Beach 100 E Boynton Beach Blvd Boynton Beach, FL 33425-0310 RE Packaging Concepts Expansion - Lots47 478, 47C & 470 Revised Site Plan Our File No 98010 14 Dear Mr Rumpf" Attached please find twelve (12) copies of our site plan application package for the above referenced project. The site plan IS being revised to add land area to facilitate an expansion to the eXIsting facIlity A vanance application IS being submitted concurrently and we are requesting that both follow the same meeting schedule Please let me know at your earliest convenience, if you reqUIre any additIonal information (j:IY JOnl Brinkman, AICP Project Planner cc: Philip Meshberg Dennis Bleakley 1 ~ = () d (),~L(:i1l1h':L R, ad. ,",Ult lOr \\(''-1 Palm Fkad1. Fl "4(J'I ro I ! 'h 1 {'...... ~ -. Ira. '(ll-h\-) .....:::;~(} nl~ul \\ n~l()n'\ 1a l anI l'lll PIHDER TROOTMfili \"OttSOLTlttG. Itte. Transportation Planners and Engmeers 2324 South Congress Avenue, Suite 1 H West Palm Beach, FL 33406 (561) 434-1644 Fax 434-1663 Email pindertroutman@msn.com January 5, 2001 Mr Michael Rumpf Planning and Zoning Director City of Boynton Beach 100 E Boynton Beach Boulevard POBox 31 0 Boynton Beach, FL 33425-0310 Re: Quantum Park Lots 47A, 478, 47C, 47D - #PTCOO-l72 PJM & Associates - Packaging Concepts Dear Mr Rumpf It is proposed to expand the development on Lot 47 of Quantum Park in the City of Boynton Beach The site is located on the south side of Park Ridge Boulevard east of the Boynton Beach High School It is proposed to expand the existing 25,838 SF building by 28,000 for a total of 53,838 SF for PJM & Associates. Access to the site is via one (1) driveway connection to Park Ridge Boulevard and two (2) connections to Beta Dnve The proposed expansion is estimated to generate 195 daily trips, 26 AM peak hour trips and 27 PM peak hour trips as shown on Attachment 1 Driveway volumes for the total of 53,838 SF building are provided on Attachment 2 The Quantum Park DRI is an approved project, and is considered a Previous Approval under Article 15, Traffic Performance Standards, of the Palm Beach County Unified Land Development Code (ULDC) The proposed land use and intensity are within the limits of the original approval of the Quantum Park DRI, as shown on Attachment 3, therefore, the proposed project is not subject to the Traffic Performance Standards. If you have any questions regarding the contents of this letter, do not hesitate to contact this office 7 --;;;; 1 l ~CA-/f//J~~ Anq-'rea M Troutman~ E /1/5/0J Zr sident / ttachments cc Masoud Atefi Philip Meschberg Letter Rumpf 00-172 1 5-01 Pi Attachment 1 Quantum Park lot 47 - PJM & Associates Expansion Trip Generation #PTCOO-172 1/5/01 tripgen Page 1 of 1 Daily Land Use Intensity Trip Generation Rate (1) Total Trips Industrial 28,000 SF 697 /1,000 SF 195 TOTAL 28,000 SF 195 AM Peak Hour Total Trips Land Use Intensity Trip Generation Rate (2) In Out Total Industrial 28,000 SF 0.92 /1,000 SF (88/12) 23 3 26 TOTAL 28,000 SF 23 3 26 PM Peak Hour Total Trips Land Use Intensity Trip Generation Rate (2) In Out Total Industnal 28,000 SF 0.98 /1,000 SF (12/88) 3 24 27 TOTAL 28,000 SF 3 24 27 (1) Source' Section 10.8, Fair Share Road Impact Fees, of the Palm Beach County Unified Land Development Code. (2) Source: Institute of Transportation Engineers (ITE), Trip Generation. 6th Edition. o ~ /~ N.T.S. \ i \ i \ 11 (2) ~! , ~I '~ PARK RIDGE BLVD /~ ~ ' , \ 2 (16)t ) \ / " / '~ ~ .-.1 "- ~ ,00: .0 <( f- LU co 94 SITE 131 150 , I ! / / / " / "- / ~ 2 (19)t LEGEND 2 - AM PEAK HOUR PROJECT TRAFFIC (19) - PM PEAK HOUR PROJECT TRAFFIC 150 - DAILY PROJECT TRAFFIC NOTE. INCLUDES ESTIMATED VOLUMES fOR EXISTING BUILDING. QUANTUM PARK INDUSTRIAL - LOT 47 An ACHMENT 2 PROJECT DRIVEWAY VOLUMES o ~ 1/4/01 ~ ('.I T""........ """00_ ~;H~ uT"";:;~ f- ~ ~ "- ~c.. '" 6 o C ~ c .~ g .;;; c 8- l< ... .. CII OJ '8 .. .#! oll ~ ii:' to... rl .,.. .. ~ :J "'C C ~ oS M .. crfo CII E ~ E :l 0 ~-- u c C III III CII _ :l > ~C1E. !!1 0.... ~ .~ ~::g ~ ; .;; o ~~~~~~~~~~N~ ~a~~N~~ ~~~~~~~~~~~~~~O~~N~ NN ~$ .2 ~~~~:n:n:n:n:n:n~~:n ~ ~j~~~_&~-~-~,&~_&~-~,~, ~(1---- --- Q. .;: ~ u..u........Ll..L..i....LI.......u.. 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Landscape ArchItecture Land Planning F.S.L. #LC Cl16 FAX MEMORANDUM DATE Januarv10, 2001 TO Michael Rumpf FROM Joni Brinkman, AICP RE Packaging Concepts Quantum Park Lots 47, B, C, & D Our File No. 98-010 15 No. of Pages (including cover) 4 A site plan and variance application submittal was made yesterday to the City for the above referenced proJect. Subsequently, it came to our attention that there was an error on the number of driveway connections indIcated for Beta Drive The discrepancy has been corrected in the attached traffic statement. This revision did not affect the number of trips generated by the proposed project You will receive the original signed and sealed copy for your files via mail Please call if you have any questions or require further information cc Philip Meshberg Dennis Bleakley 1512 Old Okeechobee Road. Suite 106 West Palm Beach. FL 33~09-5270 561-689-~670 . Fax 561-689-5559 PI"DER TROOTMfih ~O"SOLTI"G. I"c. Transportation Planners and Engmeers 2324 South Congress Avenue, Suite 1 H West Palm Beach, FL 33406 (561) 434-1644 Fax 434-1663 Email pindertroutman@msn.com January 5, 2001 Revised January 9, 2001 Mr Michael Rumpf Planning and Zoning Director City of Boynton Beach 100 E Boynton Beach Boulevard POBox 31 0 Boynton Beach, FL 33425-0310 Re: Quantum Park Lots 47A, 478, 47C, 47D - #PTCOO-172 PJM & Associates - Packaging Concepts Dear Mr Rumpf It is proposed to expand the development on Lot 47 of Quantum Park in the City of Boynton Beach The site is located on the south side of Park Ridge Boulevard east of the Boynton Beach High School It is proposed to expand the existing 25,838 SF building by 28,000 for a total of 53,838 SF for PJM & Associates. Access to the site is via one (1) driveway connection to Park Ridge Boulevard and three (3) connections to Beta Drive The proposed expansion is estimated to generate 195 daily trips, 26 AM peak hour trips and 27 PM peak hour trips as shown on Attachment 1 Driveway volumes for the total of 53,838 SF building are provided on Attachment 2 The Quantum Park DRI is an approved project, and is considered a Previous Approval under Article 15, Traffic Performance Standards, of the Palm Beach County Unified Land Development Code (ULDC) The proposed land use and intensity are within the limits of the original approval of the Quantum Park DRI, as shown on Attachment 3, therefore, the proposed project is not subject to the Traffic Performance Standards. If you have any questions regarding the contents of this letter, do not hesitate to contact this office. Sine",' l' -/~ A~/J!/~i /t~~ea M Trcutma/ P E. Ih/o/ l resident / Attachments cc Masoud Atefi Philip Meschberg Letter Rumpf 00-172 1-9-01 a. Attachment 1 Quantum Park Lot 47 - PJM & Associates Expansion Trip Generation #PTCOO-172 1/9/01 tripgen Page 1 of 1 Dailv Land Use Intensity Trip Generation Rate (1) Total Trips I nd ustrial 28,000 SF 6 97 /1,000 SF 195 TOTAL 28,000 SF 195 AM Peak Hour Total Trips Land Use Intensity Trip Generation Rate (2) In Out Total Industrial 28,000 SF 0.92/1,000 SF (88/12) 23 3 26 TOTAL 28,000 SF 23 3 26 PM Peak Hour Total Trips Land Use Intensity Trip Generation Rate (2) In Out Total Industrial 28,000 SF 0.98 /1,000 SF (12/88) 3 24 27 TOTAL 28,000 SF 3 24 27 (1) Source Section 10.8, Fair Share Road Impact Fees, of the Palm Beach County Unified Land Development Code. (2) Source' Institute of Transportation Engineers (lTE), Trip Generation, 6th Edition. o ~ ~, / \ i \ 11 WI ~ I PARK RIDGE BLVD 94 SITE 94 37 150 LEGEN D 2 - AM PEAK HOUR PROJECT TRAFFIC (19) - PM PEAK HOUR PROJECT TRAFFIC 150 - DAILY PROJECT TRAFFIC NOTE. INCLUDES ESTIMATED VOlUMES FOR EXISTING BUILDING. i i ~ /\ ~ / ~ \ \ \\ \ ~ / ~I '\ ~ ' ex:> T""" .J C<: o -< I- LU a:l N.T.S ~ ~ \ I I I / / 2 (12)t I \ \ \ '\ 0(4) t i i i \ \ \ 2 (19)t QUANTUM PARK INDUSTRIAL. LOT 47 ATTACHMENT 2 PROJECT DRIVEWAY VOLUMES o ~ R 1/9/01 ~ X A C K A GIN .G M_PAKO MARKETING SOLUTIONS CO~CEPTS ASSOC., LLC CONCEPTION . PATENT PROTECTION . PROTOTYPES . MA,"IUFACfURlNG . ENGINEERING 0 COSTING . FINISHED PRODUCT February 15,2001 Mr Jose Alfaro City of Boynton Beach Plannmg & Zonmg Department 100 E. Boynton Beach Blvd Boynton Beach, FL 33425 RE. EnVIronmental Penmt Dear Mr Alfaro, Packagmg Concepts Assoc, LLC. is undergoing an expansion of It's regular or core busmess. The antICIpatIOn of mcreased busmess m the near future, and the real need for storage space IS the reason for our expansIon at tIns tune. Oddly, our mcreased busmess IS not related to the productIon of CheIIDCal products, but to the sale of empty plastic contamers that are used world-wide. We are sublDlttmg the Matenal Safety Data Sheets (MSDS) that pretty much follows those gIven to Mr Mark Boblc, UtilitIes Department., CIty of Boynton Beach some 3 years or so ago Smce our chelDlcal productIon IS down SIZed and jUst a few new chemicals have been mtroduced smce our last EnVIronment ReVIew, we hereby request that a modification to our current EnVIronmental Penmt be approved for the new expansIon SIte. We look forward to a favorable ruling m tIns matter Smcerely, Edwm 1. Stoltz, P Vice PresIdent Cc' Current MSDS ~ "LEAD TO SUCCEED' 4925 Park Ridge Blvd. 0 Boynton Beach, FL 33426 0 P.O Box 4690, Boynton Beach, FL 33426 (561) 364-0014 Or ToIl Free: (800) 881 MPAK 0 Fax: (561) 364-1480 Visit Us On The Web @ www.packagingcoDcepts.com 02/18/2001 12 35 1-5&1-589-5559 B2/1&/208l 11~J1 5613756259 WINSTON LEE WYN1U1 ~ t"" .. .:. PAEE 02/03 r~ -.. '\ TECHNICAL REVIEW COMMITTEE MEETING AGENllA - 1'0; i Bob ~ De~ty Fi,. dmhal I X.vlc1 Ha1~t FotMWrl ~vironmentaJi1t ,i John ~ pollce r epartDlent ~ H.Davi4 Kelley h., lJ~Utt~3S D~ ; T"Jm01hY J...erat, BuUding pMsion . &_ HaU, ~~) p.:1bJlc W~ !! Jot'fery Uv~ Pub1ie Worb-Traffic I B*'M,ra MetQhIm, Pub pivitfon Lusia Gekv, PlBtmiq and Zonm, DivDion HJ)a.v~d K,cn.y J~_, Engini ~DI Department J1IWM, !diobooI W Il_f. CllAJrutJ11 t- DATE: T\l'eSday. Febmary20, 20C 1 TIME: 1:00 AoM. PLACE: Cont'cm1ce Rocm1 C, 2nd i9oor. west W"tnaJ, City Hill ,;.~.: ~ 1. New BuiDtII A. M....r,....~l i p1t.QfBCT: . StOi lCha~ Horn~ert AJl()Cistion I !A~ OWNER.: Get 114 van-Gel.der Stor .ehaven Homoowntr.l .M&ociation LOCATION' 169.J S~ prive . ;- :.~lON. ReqJfit for muter ptllll modiflcatiODJ to include the .cJo.ure of Stot .ebavcn Drive, the installation of gatee at projeet erdraI:ICe and masoot)' will 9qo A..~. i B. i ~M.t ~ PIo 1 j n<.QIBCT ] 1 j ~J~ Concepts 82/18/2801 12 35 1-561-689-5559 82/16/28131 11: 37 56131SI:)2!.:iS P.2 : ll'C ~,4oend;I 02/20/01 \ '. AGBN'f' S ,j ; OWNEJt ~ WINSTON LEE &I'tl'flU'l 1ltJ'!U1 1"' & t:.. PAGE 133/133 ,..~c. u. Wn; aton IM~ ASlJ\ AlCPlWin,ton Lee & Aas.xUcCll, Inc. Pll\H & Assoc.... L.C. f. LOCATION : oBSClUPTXON i I J..o~ 47,472147Cl and 41)) \ :R.eqJe6t for fJflW site plq ilpprow.1 fur .. 53,838 .$qusr& foot additi<>l1 to an 6Xi~:ing industrlaVw.-ebouse building Iooated on 3.65+ 8CJ"e,. 2. ~ CoJmnonu by me.inbcn ! l 3. iA~.t i i i CC; 1. W'i1dn<<, PlISb ~ . 101m Guiclty, hiterlm Director ofB~ng ~~~T~~~l:l'.WII\I'~ VI'C p",,~ t<n'47 (f^CItWJJM1COHC1iP'JS)~ j)t.<<l1\1~C .ll/3EN!)AfQJ\Q1.~.,O(lC 1 'j i i 1 ; Hl/J~ 1 '3% 40""9654~.4 407'3554714 PKG CONC ASSO I~C PC:.GE ~3 __<1..... _~..- 0.. ~ Bull'. Eye ];..11-6' C1eaner MATERIAL SAFETY DATA SHEET ~ Packa~in9 rnncep~~ Aq~nr inc - 5700 Lake Worth Rd_r Suite 20~R Lake Worth, FL. 33463 ~- ("",W_l (407) 965-1130 &T...... .c~ ""one _ MCI~ .-es:;~ ~n 0 0 CAS /llwlI'Oet N/A 0QIe ....-.. 6/1S/q~ ~~Stoltz. ph.D. NOlI: ..._ ~ not ~_ "aY/f"""."" I. or,., ll__..~. -___I9VloIOIO~.... SECTION 1 - MATERIAL IDENTIFICATION AND INFORMATION Q)MI'ONINlI Cb..... Men. Gnlf c::GInmaft NaMe e 1"4 GI' 0.1' GI' OINA fIa ACGIH 'IlV O'IHIII UMq IICOMMENOfD SDA 0 * Non-~OUIlngr~l4Htts rorAL SECTION 2 - PHYSICAL / CHEMICAL CHARACTERISTICS Sll-*~ (l1,O. I) ......... IIort '-_.be e . I) WGIW ~ :::0 (1) 173GF VOpOr ~ (n'm"Q ~T~ N fA - o.r..v tAh \) ( 1) 1 59 ....., ... Wlalw None N/A .0.-.:. Qf'C:IOoar SECTION 3 - FIRE AND EXPLOSION HAZARD DATA RcIlf\ -.. QI'tQ ~\MG (2) ~ ~ s-.:a ... ~~ _~ ~ll:lhJl~L.-" 1.8. 2050F Toe r...-.. N A .....""V_ Water Spray Confine to immediate area-Use self contained breathing gear. / I '-"-"'l FN ~ ~~ Melt "lastic rl1hp ODttanQf *=Parts Per Million N/A=Not Applicable -lCJ-:6SJ......~ ~ 1 =it- J.l-:'3hS....- ..... PkG ::]hC --f'. ,;....~~u ~c ;: -,:;c: -,~ PCA 'lOO/Bull's Eye -1;r9654~~4 ,. ~ " q3~ -1f1-=1bS-1- .. PhG CO~IC c.sso Ihl~ - -'~::.. -:j ~ ....... <T...... _,.. __ On l.a>ei) Bull's Eye L,en-s' Cleaner MATERIAL SAFETY DATA SHEET ~ PackaQing rnncept~ A~~nr ~ 5700 Lake Worth inc MlI:lI ""- ....E.C~ 1/.100 CAS~ N/h Cate-~ a/lC:;/QS ~~Stoltz, ph.D. Lake vlorth, FL. ~N~ (,.", ,.........,.,...,) Rd__ Suite 20'1B 33463 965-1130 (407) E:Jl....V- oCt pt,.,.....~ NCTt: .... __ ~ no' ~-. ~"... "*". t\Ot 1. 01.... .I~. ~ ",.....,.. _ De..-- to I'lGIIlCIN ........ J I Non'IfOZDrdoUllngt~I."ts TOTAl. ~ ,.~ ~ lion E..oao ."..... . /lat. e . I) wow - None N/A ~ ....... s..cw:a "- ~~ Water Confine area-Use self contained ,breathing gear \k-..::I ~ a'l;l ~n_ Melt plastic tuh~ 412179654""14 Hl131 1 q% , ..,-, . J. -Hl"'%5'P14 PKG CONC ASSO INC Pt:.GE fJ5 lQItWY <'1'_ ~... UMO On I"ggej) Natural Peppermint Breath Freshener MATERIAL SAFETY DATA SHEET ~ Packa~inq ~nncp.pr~ A~~n~ ~n~ - 5700 Lake worth Rd.. Suite 20SB Lake Warth, FL 33463 IlI\of'e ~ ~~._.."-.l ( 4 0 7 ) 9 6 5 -113 0 E"~"",,, ~~ ....~. 1:)('" ll. f 1 01 CAS~' N/A. ~~ 4/7F./Qr:, ~.,' F. T ~t'nltz, Ph n HOlt: ~ __.- not ---. . tJItIf _."., I .01" .ftNI\_.~. _ _ _De......... ~_. SECTION 1 - MATERIAL IDENTIFICATION AND INFORMATION QOWION8IIS _ CIwnloGI Name ~ C4IMMIn NcItMt ~J_e '''or 0.1"4 or Ac:GlM n.v 01l81M11 iICOMNINDlD SDA 38B 2000 Non-HclmrdoUllngtedl..,1'S TOTAl. 1730F :t: .005 @70oF V_ "'- ('""~ C3"0f~ N / A VQllOf oer.v ~. 1) ( 1) 1.59 :::(2) Complete ha:l1 ..... .~ ( .1) ~ ....,... ~. a'40c>>' Fragrant/Clear F~~_ , ~ ] F.............~.. rl.8.. r~ __1.McI ( 1) 700 F ( TOe) . I~ N / A ......._'1_ N / A I I ~ ' ~ Water Spray-CO? 5NcuFft C f' t . d' If i ~~ on ~ne 0 ~mme 1ate area-Use se -conta ned b~eath1nq gear. I 'I ~-- --.. HaaQ Melt plastic tube CphOOQI *~Parts per million N/A-Not Applicable 4079554714 131 1'3% 11"'~ 407%54714 PKG CONC ASSO INC PAGE EP ....- (T....,. ....... .. \-.:I Of\ laleQ Natural Spearmint Breath Freshener MATERIAL SAFETY DATA SHEET r.au_ Packa9in~ rnnc~pt~ Aggnr Tnr ...,.,,- 5700 Lake Worth Rd.. Suite 205B Lake worth, FL, 33463 """'"" ~ (Jet ""_I ( 4 0 7) 9 6 5 - 1130 ~ ~~ MSCI_ 1:1~ll. '1 n? c:,..$ ~. N/A oar.~ 4/2F./Qr; PretlCnCl" ~_T_~toltz, ph n NOtl: __opaaeIa....,~ ,,~_.,..,. CIlJl . ..1'0 ___ .~. h soooe _ tloe....... to""""'_. SECTION 1 - MATERIAL IDENTIFICATION AND INFORMATION c:o....cte. ~ NclnW and Canlmon....... ,.. OIHA Ac:t;U4 UM1a (~c: 1'1. . aNd..: _ 0.1'1. .IS'''.J IIt\ 1\.V 1ltCC' If IINOtD SDA 38B/200o C 1 ) 41 0 1_noo . Non.HcuardoUlI~edl.,,1ll Pro,..,....;o+-;::Irv I ., \ . TOTAl . . . 01NII ~ (1) 1730 F ~~ (2) O. 986 :t . 005 @7 0 0 F VOOOI_ ~ (""""9 orldr.~ N / A Point None \lggor~ ~ ...A_.Qde ~. I) ( 1) 1.59 ( .1) N I A ~(2) Complete ~ No "-""=. ~~ Fragrant/Clear I'lCIf\ I'cwIf ~ ~I ~: ......... -' n.......... ~ .. ILA. J loA ~~ (1) 700FCTOC) "'~ N/A ~......,v_ N/A . ~ - ~1IQIf). ~~ water Spray-C02 Confine to immediate area-Use self-contained breathinq gear. I J , ~RIw_ ___n~ Melt plastic tube ~tlonol *=Parts Per Million N!A-Not Applicable ~tJ""9b54~l4 18/31 ;qb 1 ,..-- .HJ'7%54714 PKG CONC ~sso lNC PC.GE 08 PeA ,10Z!Spearaint SECTION 4 - REACTIViTY HAZARD DATA {I_ I ;..;" High Temper;lture If...", 0(1 -- --~ l~"-"l - "CU. J.~ ~~~ ""YM8IL\noM ( I 1llllIrQer:v CC I .... ... 0... N/A N/A I~ N/A : SECTION 5 - HEALTH HAZARD DATA ~ IOU1II QP Ul1II'I' NIM!M -.zA. I ......" 1 .. 't>.....-..... ........ li~ eXl NIN._4&._ ~I:lIIlU.J --- NIP I/Il8C M... .- ...4" ll~ (Xl NIIr_ cr.no None None ""CII'4~ "'...... __ COl'ClIIDflI ~""'_..4c.__ EMEI~I~CY FIRST AID 'IOCEDU RES N/A N/). SM. t.lMGIeClt ....rane. for ~ "Mtmenf. O..,.,allon arG SUggorf' Hec.-aIY ~~ Flush with cool, clear water ..-=-- Wipe or wash off with water ......... N/A ....... Drink freshwater -,. cr' ."-- ~ ,.,... ---...... ~ ~..- Not Required Not Required ( · N~l:quir.d ( I onwC--'Y) .... ---- Do on.~ o.-.-~ .-. Not Required ~-- Normal practices ......r_.-...- .--...... Wipe up a wash with water-Dry to prevent sliCCQrv Ar~~ ....~........ Per normal local refuse disposal ...-._....1_ ft~..--.. Store at normal ambient room temerature. QI,.. ------ ~.--- Keep out of the reach of children Rating: Health (0), Flammability (1), Reactivity <0>, Special (0) Jegree 4_Extreme/3=High/25Moderate/l-Slight/O-Insignificant 4079654'""14 Hlnl 1'3'36 11""'" 407'3654714 PKG CONC ASSO HiC PClGE a'3 ......... <1_ NI:tIIW ,.. __ 0f'I ~ Natural Wintergreen Breath Freshener MATERIAL SAFETY DATA SHEET ~ P~ckaqinq rnn~ppt~ A~~n~ Tnr "-- 5700 Lake worth Rd.. Suite 20SB Lake worth, FL., 33463 -- (,..~~_.) (407) 965-1130 ~ -- ....- of"!o "01 CAS~' N/A ClaH~ 4/2F./g~ ~.. EaT stoltz. Ph.D 1'CJf1: ~__~ _.~... '~-lftOI-..L~."" iI'I_."-"."" >ea:e _ be~" ~ "'d. SECTION t - MATERiAllDENTIFfCATION AND INFORMATION SDA 38B 2000 ACQIM 01HII ~ llY ~ Non.Hamrdoua Ingredlen" P TOTAl SECTION 2 - PHYSICAL / CHEMICAL CHARACTERISTICS SOecfIc ~ <1\0-' " ( 2) O. 986 :!: .005 Ii! 7 00 F w-. PoIrII None (__ III .... ( . I) N / A Wf::IeI ~ No ::::v (1) 1730F Vo9<< ~ (...... "9 <rd I__aN. N / A _o-.v ~. I' ( 1) 1.59 ::-:;:(2) Complete ~. ~~ Fragrant/Clear SECTION J - FIRE AND EXPLOSION HAZARD DATA ~ _cr..a _UIeO ~ MeaIa So.ClIOIIft ~~ I ~.......,. ] J~..."""" ~., ( l) 70 of (TOC) r__ N fA. _ .......\/...... N I A Water Spray-CO? Confine to immediate area-Use self-contained Llal~ breathing gear. I I ur-.o,.,. _ "'-~ Melt plastic tube Oolionol *=Parts Per Million N/A=Not Applicable Mason Chemical Company 'The Quaternary SpecIalist" 721 West Algonqum Road Arlington Heights, IL 60005 847-290-1621 U.S & Canada 1-800-362-1855 Emergency Telephone 1-800-424-9300 Chemtrec Health 3 Fire 1 Reactivi~ 0 Section 1 Identity Trade Name: Chemical Family- Formula: MAQUAT LC12S-50% Quaternary Ammonium Compounds [R1-N(CHl)2CH2CJ!,rCI- Chemical Name: Benzalkonium Chloride c.A.S. No.. 8001-54-5 DOT C/QSsification' DOT Proper Shipping Name: Corrosive Liquid NOS (Contains Quaternary Ammonium Compound) 8, UN1760, PG n, ERG 60 Section 2. Hazardous Ingredients Benzalkonium Chloride Water Wei~ht 50.0% 50.0% TW AffL V NO Section 3 Physical and Chemical Characteristics (Fire & Explosion Data) Boiling Point: NO Percent Volatile (by weight) 50% Solubility In Water: Soluble Appearance and Odor' Colorless to light straw in color Benzaldehyde Odor Specific Gravity: (H20 = 1) 0.98 Flash Point: 2000F PMCC pH 6-8 Evaporation Rate Butyl Acetate=1 NO Vapor Pressure approximately 24mmHg Auto Ignition Temp.: NO Lower Explosion (~). NO Upper Explosion (~): NO Extinguishing Media: Dry Chemical, Water Fog, CO2, Foam Special Fire Fighting Procedures: Cool fIre exposed containers with spray, Must wear MSHAlNIOSH approved self contained breathing artus. Unusual Fire Explosion Ha1.llrds: Explosive mixtures can form with air Combustion products are toxic. Solvents vapors can travel to an ignition source and flash back. Section 4 Physical Hazards ~. Stability. Stable Conditions to avoid: NA Incompatibility: Strong oxidizers or reducing agents Conditions to avoid: Mixing with strong oxidizers or reducing agents Hazardous Polymerization. Will not occur Mason Chemical Company Trade Name: MAQUA T LC12S-SO"Io Pa&e 1 0 Hazardous Decomposition Products: Toxic hydrogen chlonde fumes, oxides of carbon and nitrogen. Section 5: Health Hazards Routes of Entry: Skin Contact, Inhalation, Eye Contact. InhaUztion: Irritation of mucous membrane can be caused by solvent vapors or mists of products. Eye Contact: Corrosive. Severe eye damage can result from direct contact. Skin Contact: Severe Irritation. Corrosive. Ingestion. May be fatal. Burning pain in the mou~ throat, abdomen, severe swelling of the larynx, skeletal muscle paralysis affectm~ the ability to breathe, circulatory shock, convulsionS. First Aid' Skin and eye: In case of contact, immediately flush the eyes and skin with plenty of water for at least IS minutes. For eyes, call c physician. Remove and wash contaminated clothing before reuse. Ingestion: If swallowed dnnk promptly, a large quantity of egg whites, gelatin solution or, if these are not available, drink large quantitie of water A void alcohol. Call a phYSIcian immediately Note to Physician: Probable mucosal damage may contraindicate the use 0] gastric lavage. Chemicals Listed as Carcinogen by: OSHA -NO LA.R.C. Monographs -NO National Toxicology Program -NO Section 6: Toxicity Acute Oral LD.so 735 mg/kg for males and females combined Acute Dermal greater than 3350 mglkg Primary Skin - Severe Irritant. Corrosive. Primary Eye - Corrosive Section 7 Special Protection Information Ventilation type: mechanical (Explosion proof) Respiratory Protection. None required if good ventilation is maintained. For mist or vapor wear NIOSH Approved respirator. Protective Gloves: Rubber or Neoprene Eye Protection. Splashproof safety gogglc!s Other Equipment: Impervious apron, eyewash facility, emergency shower, faceshield. i I Section 8: Special Precautions aDd Spil1lLeak Procedure Handling and Storage: Keep from freezing. Store in original container Spill and Leak Procedure: Remove ignition sources. Wear respirator Small spills may be mopped up, flushed away with water 0 absorbed on some absorbent material and incinerated. Large spills should be contained; the material th.en moved into containers anI disposed of by approved methods for hazardous wastes. Waste Disposal: Incinerate. Make sure that all federal, state and local regulations are observed. l11e seller makes no warranty expressed or implied concerning the accuracy or any results to be obtained from the use of any infonnation and no warranty expressed (] implied concerning the use of the products. The buyer assumes all risks of the use and/or handling. Mason Chemical Company Trade Name: MAQUAT LC12S-SO"Io Pa&e 2 . unlQema . MATERIAL SAFETY DATA SHEET Page Revised Replaces Printed 1 of 7 12/28/99 4/02/98 3/31/00 PHOSPHOLIPID CDM UNIQEMA MSDS 10 806611 1 CHEMICAL PRODUCT .AND COMPANY IDENTIFICATION Material Name PHOSPHOLIPID COM ICI Americas Inc POBox 15391 Wilmington, Delaware 19850 ICI Operator (24 hr ) ~ (~02).,.~~ '~'.i<.:" . ~--,; '-~'" . Medical Emergency (24' br..J: ~J:.'. 'F ... t 181 Chemical Emergency (24"'h'r:;) :;~...._ '"". '~~ . ..~vrJ:ation Spills, Leaks, Fires'; or A:~g,~;~~):.. " 'l-'t' ,...~.:.~;~?~::?O . . ~. .r"11-i.~~ 4ii~ 2 cnO?osrrION/INFORMATION ONc~ttNGRlmIBNTS .gredients" . "-~~~~~ OSHA Sodium coco PG-dimoni#W,~hloride phosphate (~l~$~lO-79-2) .::::' ::';':.;''$:~ .~-- .;":;:'" PEL Not listed Values are not prodUqt s~q~fications '~~;\:r~~~ :.:i.~;::-~"'C"A~~~,,-. . 3~-J~1'jON . ..~ It.... General ' 7';-f:- r:,:~~1~~ :.-.'" ..- Limited toxicity d~ta are availabr~'~4~Itbl~~~~~ifi~ product; this health hazard assessment 1S based on the results ~~;sqg~n1ng tests _Ip-_:r:-..~~'~, Emergency Overview Appearance Clear yellow liquid CAUSES EYE IRRITATION MAY CAUSE SKIN IRRITATION INHALATION OR INGESTION MAY CAUSE MUCOUS MEMBRANE IRRITATION MAY BE HARMFUL IF SWALLOWED I Routes of exposure Eye contact; Skin contact; Inhalation I Symptoms of Overexposure (Acute & Chronic) Eye contact This material will cause eye irritation following contact Skin contact This material will probably irritate human skin This product will probably not be absorbed through human skin I ,J,lR~qqp,wP Plaza, 3411 Silverside Road, Wilmington, DE 19810 lerepnooe~-~22-B215, (302) 8873000 Fax (302) 887-3525 l-'~cw ", Af'fI1*~ - . U~Lrk..l02 , 1198 ~ Unaqema is an International business 01 Imperial Chemical Industries PLC. Uniqema operates thtough ICI affiliated companies in ~ the relevant countnes. SUCh as ICI Americas Inc.. Unichema, a division oIlndopco Inc., and Mona Industries in the USA. . unl~ema MATERIAL SAF~TY'DATA SHEET Page Revised Replaces Printed 2 of 7 12/28/99 4/02/98 3/31/00 PHOSPHOLIPID COM UNIQEMA MSDS ID 806611 , .. 3 HAZARDS IDENTIFICATION (Cent.) High concentrations of mists or aerosols may irritate respiratory passages No toxic effects are known to be associated with inhalation of this material Ingestion In humans, irri t~.t1.cm;;. 9fJ~~ ."". de:relop fo~lowi~: ;~~:... ~' Th~s mater~al m~'~;~t:." _,;;;:,,';S.:...::r.. -:foo:~ ~~', ~, ~<i.."''''~'_.''''~':,: '"1 - :.. ~. Chronic Effects No. atir~le .,:g:ff~6E*~rr: th~s'~J?~Oallct esophagus and stomach can chronic exposure to .- i ~ - -'~-,.~.~ .-I..i . ~ .;..; .~- (:.:..:~ 4 FIRST AID MBAS~~~:r:!p:; "-, ~<'--' - Eyesf ." Immediately flus\~~~fr~lenty of water ~~~east 15 minutes If redness, itching~"q~ ~ 'l?\lrning sensation>~~,.._ ~ops, have eyes examined treated by medical pe.'rsQ-DP.el : > Skin ......< .,. Wash material .off qft'h;.fif' _:;.,.:;;. '.' itching, or a burning p~. Ingestion-~~!' - . 00 NOT INDUCE VOMITING G'"fit~';:, '::" refer to medical personnel' ol!:;'c poison control center Never give person Inhalation Remove victim to fresh air If a cough or other respiratory symptoms develop, consult medical personnel and .~x of soap and water If redness, .J ''get medical attention ,. . ".. ~~tes of water to drink and '.-~~im either a physician or a .~~lW'~~h to an unconscious " 'r:~:1f?-:t ~'_. 5 FIRE FIGHTING MEASURES I I Flashpoint and method >200 deg P, 93 33 deg C (PMCC) Autoignition temperature No data Flammable limits No data ~xtinguishing media ~. Water fog, alcohol foam, carbon dioxide, dry chemical, haiogenated agents s.l.'.9~CopcprjI:f~~i~~~~~ DeMlJlpment !:ferepnone (aaor~~-8tl5: ~2) 88j~ - - - Fax (302) 887 3525 1.'" ReIIMtw_lIJItCW " ANIc( - . UNO-lTH-1Q2 11J'91 ~ Unoqema is an lIlIernational business 01 Imperial Chemic8llndustries PLC. Uniqema operates tIvough ICI affiliated compaNes. . in ~ the relevant countnes, such as ICI Americas Inc.. Unichema. a division of Indopco Inc., and Mona Industries in the USA. . unl~ema MATERIAL SAF~TY DATA SHEET Page Revised Replaces Printed 3 of 7 12/28/99 4/02/98 3/31/00 PHOSPHOLIPID COM UNIQEMA MSDS ID 806611 5 FIRE FIGHTING MEASURES (Cant.) Self-contained breathing apparatus with full facepiece and protective clothing Unusual fire and explosion hazards None known Explosion data Sensitivity to Tl\echanica~ i~11W..~P:t;.~j.:.j~t: :~p+icable -< . 'p - ~(i~~if3.'_ ~1t.:'~- . ~. r:.' Sensitivity to eta.tic dlachf\%,g~'if~hij1Wi'4.ri::~le . -;:"" , :' .,'~. '.:!, .~ft :~~ . )' :. ~ . _ :. .....>.v _ ) -6 ACCIDENTAL RELEASE<~~ ~ _:'~::;~i~ fer to Section 8 for proper personal protect.~~~~~ipment ~- Steps to be taken in c.lfS$ .-material is releaseq -~~:~lled Soak up material 'with absorbent and shoveJt~~~~' a chemical waste container .~, '1".: . " ~ Wash residue fromsp'i.ll. ;~'~,~a with water cQli'taining detergent and a sewer serviced by a pe~~~ted w~stewater treatment facility ~-" ~ -~:>~. 7 ~~~:~~~~~.~, flush to Storage requirements 50-90 deg F in original alO~ container Precautions to take during handling and storage Prevent skin and eye coqtact Avoid breathing this material Do not swallow Normal chemical handling and storage .-.rl.... I I 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure limits No ACGIH TLV or OSHA PEL assigned good hygiene practice Minimize exposure in accordance with !gineering controls Use ventilation adequate to maintain safe levels E.lJg~dfoa<tQfd fl~..3411 Silverside Road, Wilmington, DE 19810 ~JrepPlo1\e 'tsOO'r822"-'l3':H5. (302) 8873000 Fax (302) 8873525 l.-' Respa.ISIIIeCant "it ANIle!.". n 1 U....o-lTH-l02 l1ft38 ~ Umqema is an international business 01 Imperial Chemical Indu&tries PlC, Uniqema openItes through ICI affiliated companies in ~ the relevant countl1e$, SUCh as leI Amencas Inc., Unichema. a division cllndopc:o Inc., and Mona Industries in the USA, . unlQema MATERIAL SAFETY'DATA SHEET Page Revised Replaces Printed 4 of 7 12/28/99 4/02/98 3/31/00 PHOSPHOLIPID CDM UNIQEMA MSDS ID 806611 ". 8 EXPOSURE CONTROLS/PERSONAL PROTECTION (Cont.) Chemical tight goggles Protective clothing Impervious gloves "9.~~lDU':SICAL AND ....':i~00..-'" ,:.' pearance & odor C~~Ytkllow liquid ,-,..lor threshold No da;g~:~\~..~ Boiling point 203 deg:~Fic"'95 deg C Melting point No da~i::~fi( '~ Vapor pressure (mm Hg "~i'l:i~@"',~g C) No data Vapor density (air = i~1bt~~~~a pH - 6, (10% aqueous).~ ,: ~'" - ~_ Specific gravity 1 020~7 'j~"' .;';, % Volatile by volume NO da..t-~ --~; 'ri,:. Cloud point No data Viscosity No data Partition Coefficient No data Coefficient of water/oil distribution Freezing point No data "~~~~:'IJ . -'~'~1~:~~ltj ~ ;~~~...~~ ~.~ ,.;1 -3W8<?f,~ ,.....~~~~_.. -~:;,fg;.~'t1' t.<'i-~ .. ..- ... , ~~':i;hti r~1~i No Jafa: . :~', ~~. 10 STABILITY AND REACTIVITY Stability Stable under normal conditions i I Incompatibility Oxidizing agents Conditions to avoid None known Hazardous decomposition products ComLul:)Liu.l.l ~ CCll::OOn dioxide, U~~Iaza,~ .. ,Wfl~0E19810 Telephdf\e'''l'8ttl)"''~-8215,1: /!"'aX-~rS81-3525 ca%boa moaoxiac. UitFegcn=ca, lil- ~"CIIi" "il ANlet: - . UNO-LTH.'02 11191 ~ Uniqema is an international business of Imperial Chemical Industries PLC. Uniqema operates Ihrough ICI affiliated companies in ~ the relevant counllies. such as ICI Americas Inc.. Unichema, a division of Indcpco Inc., and Mona Industries in the USA. . unlQema MATERIAL SAFETY DATA SHEET Page Revised Replaces Printed 5 of 7 12/28/99 4/02/98 3/31/00 PHOSPHOLIPID CDM UNTQEMA MSDS ID 806611 10 STABILITY AND REACTIVITY (Cont.) Hazardous polymerization will not occur ~ ~ ~.;;f;{.:~_ ."... ' The toxicity data~,J...iflJ;~q '~J: O'.'L . ~.. ~ on the results of screening tests on this sp~c~~~p~e~\~ ;'.. . -- . - ~ 1 ...'!.,-::'~ :. ~. ..; ~ _>oii~ :~~~~.. Eye contact A 5%' suSP..E4i,}f~pn O'f "fftf'eF'~" \. ~$ested This material was mildly i~~_i~a~in~ in. rabbit e~.i: .... ., ~ic:m ~tudies However., due to the p..:.e'P~~nt d1lut1on that wcf~ ~ ~_.' 1t 1S expected that this material:"' wi-I"! probably cause mo(i"e'i:;~'t.1',.;~ye irritation ~j- ~Ain contact A s%' susPension of this material Wa~-t.~sted However, due to the percent dilution that was test~a.~his material is expected to cause \UQQ.erate skin irritatiGn.;::" Acute oral toxicity The oral LDSO is between 0 5 and 5 g/kg This material is classified"';9.,f?- ':s!i~~~~y toxic" by ingestion -,.7. T~ ;~. Carcinogenicity This material i~.qi~~. a~ a carcinogen by OSHA, IARC, and NTp:" _'~~: .~ Reproductive toxicity/teratogenicity No ava~laQ~e ~~formation Mutagenicity No available information .. Other effects of overexposure r No other adverse clinical effects have been associated with exposures to this material Toxicologically synergistic products None known I I 12 ECOLOGICAL INFORMATION No data is available on this product Uniqema, Concord Plaza, 3411 Silverside Road. Wilmington. DE 19810 Telephone (800) 822-8215, (302) 887-3000 Fax (302) 8873525 l-' RIspoIIlibleClnl" "it APrI*t: ~ I UNO--lTH+l02 "/98 ~ Uniqema IS an inlemational business 01 Imperial Chemical Industries PlC. Uniqema opetales through ICI affiliated companies in ~ the relevant countnes. such as ICI Amencas Inc., Unichema, a dMsion oIlndopco Inc., and Mona Industries in the USA. . unlQema . MATERIAL SAFETY DATA SHEET Page Revised Replaces Printed 6 of 7 12/28/99 4/02/98 3/31/00 PHOSPHOLIPID COM UNIQEMA MSDS ID. 806611 13 DISPOSAL CONSIDERATIONS Disposal method Discarded product is not a hazardous waste under RCRA, 40 CFR 261 Container disposal Empty container retains product residue Observe all hazard precautions Do not distribute, make available, furnish or reuse empty container exc~pt for storag~.. and '~~~~~9~~~nal p:oduct Remove all prod1;1ct res1due ~rom conta~n~r a~~~~~~~~erw1se destroy empty conta1ner before d1sposal-'~ <.'. <"~..!"r:'~':'!~P1>c; : ..........~ ." ~ ::- 1.4 TRANSPORT Department of TranspoJ:'ta.tion Not regulated ~~.....;; ~,~tJ, .co-, .,.. ~UG (Transporation of Dang~rous Goods) Not re~t~~d '"'" ~:.,..... <l;"; . ~ &"L",,;': ';:! ~ ""-;.;;.,....,~ .' 15..~TORY INFO .", ~^t.9Jl" . ~.. DSL (Tox~c Sub~tances Contr4\ ,~,1;.) . .R"e~~~~~~rts, 40 CFR 710 All 1ngred1ents are op.t-~~; ":pS~' '~t~l~t ;Substance Inventory (Canadian Domestic Subst'anc-elil Listt'~ ;1 '-\ All ingredients NOT confirmed qnt~~: '~~ad+~..DsL 'V . (.. .... ~: l~:l.O ~:O~;~azard Summary .~. TSCA OSHA Hazard Communication Standard, 29 CFR Physical Hazards None Health Hazards Irritant (eye) WHMIS Classification Class 0, Division 2 -- Toxic CERCLA and SARA Regulations (40 CFR 355, 370, and 372) This material contains the following chemicals subject requirements of SARA 313 **** NO SARA 313 CHEMICALS FOR THIS CHEMICAL **** I I to the reporting SARA 311/312 Hazard categories Immediate YES Delayed NO ttire' NO Uniqe~Qp~~, 341\fii\verside Road, Wilmington, DE 19810 TelephoM' ~~~t15 (30~Wa7 3000 Fax (302) 887-3525 l-' Resp4h"_CIII" 1-'APlMcf - . l.JNO.LTl1-102 1','98 ~ Uniqema IS an international business 01 Imperial Chemical Industries PlC. Uniqema operates through ICI affiliated companies in ~ the relevant countnes. such as ICI Americas Inc., Unichema, a division of Indopco Inc., and Mona Industries in the USA. . unlQema MATERIAL SAF~TY DATA SHEET Page Revised Replaces Printed 7 of 7 12/28/99 4/02/98 3/31/00 PHOSPHOLIPID CDM UNIQEMA MSDS 10 806611 15 REGULATORY INFORMATION (Cant.) Reactivity NO State Regulations None ~- product based on the r is most aware of the proper personal protective ion contained in the ~..i-'i~:{C w..... _~ .\~~~:~~- . ~i~ We assigned NFPA ratl'~~~ '-:i~~: hazards of its ingre -: '~}~J!f1J .~.\. '.'-:..,,_. ." application of the p . ~ 'et;:i lie' 'mtl'st~ " equipment (PPE) is p~J~ed consistent product MSDS * r :.'", IS Information Health 1 Flammability 1 Reactivity 0 ~~..~~ i]- ;~; -1~"~~ NFPA Information Health 1 Flammability 1 ;:-L ,,~-:.r~-?l~~:":~'; Reacti vi ty 0 ~. '.~:'~ ~:-: ::1fv:~~1~' -1 ,.; - ~ ..;..~ ~ ,.t~-:f~"'- ~ . .<.;,.,~,I"-:,l,~',,;.( *This information is inte~ded so~:e;~:~~~~'t~ uS.e ,>of. individuals trained in the particular hazard ratJ.ng system ,',' " , . This Material Safety Data Sheet was prepared by Qn~~~~ Regulatory ~.. . ~ ' --: ' ~ Services Department , Date 7/12/99 I The information herein is given in good faith I but no warranty, expressed or implied, is made (R) is a Registered Trademark of ICI Americas (TM) is a Trademark of ICI Americas Uniqema, Concord Plaza, 3411 Silverside Road, Wilmington, DE 19810 Telephone (800) 822-8215, (302) 887 3000 Fax (302) 887 3525 L.-..... l"IIICaII" "it ANIc( - . UNQ-ll'li-102 "/918 e Uniqema .s an international business 01 Imperial Chemicallnduslries PLC. Uniqema operates through ICI alfdiated companies in the relevant counlnes. SUCh as ICI Amencas Inc., Unichema, a division oIlndopco Inc., and Mona Industries in the USA. .. Telephone 973 628 4000 1361 Alps Road Wayne, NJ 07470 Emergency Medi~1 Information Transportation Emergency' 1 800 228 5635 En 016 612 221 3999 En 016 CHEMTREC 1 800 424 9300 ~ ISP TECHNOLOGIES INC ~.~~.. :i~~~ MSDS NO 1467 12 REV 12 DATE 10-HAY-1999 _ '<&:t: ~....~ ~""~~*-"'''-.'~'''~' II : .~ :;-;".~ .... .~.' __'r, '~.~ ,': .:;: r ..:..=J~' _i.....~.~.. .' .t,,: .'~ ,; ~-'. '. .t~'~;~::..',~ ~~. ~ : r - ,~:~_''"1'~_ 4' ~ .. " -.' ) . ':' .'.~ ... ~ .;~~~~~.:.~~.~~~~.: ~- :~ f. ... "..:" 1 2 72030 5 P~ge 1 PLASDONE K-29/32 SECTION 01 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION DOMESTIC TRADE NAME. PLASDONE K-29/32 EXPORT TRADE NAME. PLASDONE K-29/32 CAS REGISTRY NO.. 9003-39-8 CAS REGISTRY NAME. 2-PYRROLIDINONE, 1-ETHENYL-, HOMOPOLYMER SYNONYM. POLYVINYLPYRROLIDONE MOLECULAR FORMULA. (C6~O)x SECTION 02 - COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS NONE SECTION 03 - HAZARDS IDENTIFICATION * * * * * * * * * * * * E MER 6 E N C Y 0 V E R V I E W * * * * * * * * * * * * * * * WHITE TO CREAMY-WHITE POWDER. * * MAY FORM EXPLOSIVE DUST-AIR MIXTURES. * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * -ACUTE TOXICITY- ORAL TOXICITY RAT LDSO > 100,000 MGjKG DERMAL TOXICITY' NOT ABSORBED TOPICALLY i INHALATION TOXICITY I HUMAN, GUINEA PIG AND RABBIT, EXPOSURE TO AEROSOLS AND DUSTS OF SMALL PARTICLE SIZE PRODUCED NO EVIDENCE OF HARMFUL EFFECI'S. SKIN IRRITATION. HUMAN; REPEATED INSULT PATCH TEST, NOT A PRIMARY IRRITANT EYE IRRITATION RABBIT, NO IRRITATION OBSERVED Please see reverse side for additional information .. Telephone 973 628 4000 1361 Alps Road Wayne, NJ 07470 Emergency 1 800 228 5635 Ext. 016 Medical Information. 612221 3999 Ext. 016 Transportation Emergency' CHEMTREC 1 800 424 9300 :iil~~ :~~.",,:~: ~ ~t-~~~~t~~~,' " ~,:':': ~ *', ,~,;".~%"'i<:~iri,'~}k ,'-tJf4SDs1HO~4@1~r2' ISP TECHNOLOGIES INC .~'-:.~;, ::;~,:"'~,::;'":,;,,:':-,:,,:t,:",,.,~_ "':' . "/"., II' ~', ,',";,__ ~ ':~."~: ",<~~!.:<si~:" SECTION 03 - HAZARDS IDENTIFICATION (CONT) SENSITIZER: NO HUMAN, REPEATED INSULT PATCH TEST, NOT A SENSITIZER. DOT CORROSIVE. NO DATA FOUND PRIMARY ROUTE(S) OF ENTRY' CONTACf -SIGNS AND SYMPTOMS OF EXPOSURE- SYMPTOMS OF INGESTION NO EFFECfS OF EXPOSURE EXPECI'ED SYMPTOMS OF INHALATION. NO EFFECTS OF EXPOSURE EXPECI'ED SYMPTOMS OF SKIN CONTACT NO EFFECTS OF EXPOSURE EXPECI'ED DUE TO CONTACf MAY POSSmL Y CAUSE IRRITATION OR DERMATITIS IN SOME INDIVIDUALS UPON PROLONGED CONTACf SYMPTOMS OF EYE CONTACT NO EFFECTS OF EXPOSURE EXPECI'ED WITH THE EXCEPTION OF POSSmLE IRRITATION. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE. NO DATA FOUND -OTHER TOXICITY. OTHER ACUTE TOXICITY NO DATA FOUND SUB CHRONIC ORAL TOXICITY RODENT AND DOG STUDIES, NO ADVERSE EFFECf LEVEL EXCEEDS 10% OF TOTAL DIET, NO EVIDENCE OF CARCINOGENIC ACTIVITY SUB CHRONIC INHALATION TOXICITY NO DATA FOUND SUB CHRONIC MISCELLANEOUS TOXICITY NO DATA FOUND I I AQUATIC TOXICITY NO DATA FOUND TUMORIGENICITY CHRONIC RODENT AND DOG FEEDING STUDIES SHOW TIlAT THE NO ADVERSE EFFECf LEVEL EXCEEDS 10% OF THE DIET WITH NO EVIDENCE OF CARCINOGENIC ACTIVITY Please see reverse side for additional information . Telephone 973 628 4000 1361 Alps Road Wayne, NJ 07470 Emergency 1 800 228 5635 Ext. 016 Medl~llnformatlon: 612221 3999 Ext. 016 Transportation Emergency' CHEMTREC 1 800 424 9300 ~ ISP TECHNOLOGIES INC "~~..~<~<~'.':. ",~/ SECTION 03 - HAZARDS IDENTIFICATION {CO NT ) MUTAGENICITY PVP WAS TESTED IN THE AMES ASSAY, DOMINANT LETHAL TEST ON MICE, L5178Y MOUSE (TK + /-) LYMPHOMA ASSAY, BONE MARROW CHR.OMOSOMAL ABERRATION ASSAY, AND THE BALB/C 31'3 TRANSFORMATION. IN EACH ceASE PVP WAS FOUND NOT TO BE MUTAGENIC. REPRODUCTIVE TOXICITY TERA TOWGY STUDIES WITH PVP CONCENTRATIONS UP TO 10% OF THE DIET SHOW NO EMBRYOTOXICITY, FETOTOXICITY OR TERATOGENICITY MISCELLANEOUS TOXICITY NO DATA FOUND SECTION 04 - FIRST AID MEASURES FIRST AID FOR INGESTION DRINK PLENTY OF WATER. CALL A PHYSICIAN. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. FIRST AID FOR INHALATION: NONE REQUIRED FIRST AID FOR SKIN CONTACT FOR ALL FOREIGN MATERIALS, WASH AFTER EXPOSURE. FIRST AID FOR EYE CONTACT FOR ALL FOREIGN MATERIALS, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER. SECTION 05 - FIREFIGHTING MEASURES FLASH POINT NO FlASH POINT AUTOIGNITlON TEMP' NO DATA FQUND FLAMMABLE UMITS: NO DATA FOUND FIRE FIGHTING MEDIA. USE MEDIA PROPER TO PRIMARY CAUSE OF FIRE. SPECIAL FIRE FIGHTING PROCEDURES: j NONE KNOWN I FIRE/EXPLOSION HAZARDS: MAY FORM EXPWSlVE DUST -AIR MIXTURES. TIllS MATERIAL HAS A DUST EXPWSION HAZARD GREATER THAN PfITSBURGH COAL DUST NFPA HAZARD CODES - HEAL TH/FLAMMABIUTY /REACTIVITY 1 3 0 Please see reverse side for additional information .. Telephone 973 628 4000 1361 Alps Road Wayne, NJ 07470 Emergency 1 800 228 5635 Ext. 016 MedlC4llnformatlon. 612221 3999 Ext. 016 Transportation Emergency' CHEMTREC 1 800 424 9300 c ISP TECHNOLOGIES INC );rs..: ~' :' .i'::.~.;f;:~.:~.:_~~~'- if';.~r;",.rl; .~._ 'l<~........)......~ ~t: - ," '- SOS:'1ft)}1 :'iIl ~R ... ;"i...,.~1-<.~ ~....t~ ",~, "- _' 1.. .:. -: h' 4 '. .. ~."', ~~: > :;.< ~~,~ $.n....~ ..~~~... :'\";- -"'~~~'~:- ;'.. -: :7. .:.('t " -_...,. . <., - ., - - . ~ .,'.. .. ..... ..it..,;;,'Y:, <. '1,->":-\.' '. ~ .... ,. .-, 1 '.I~". .... ;-.~ .. ',il); f .- "L ~... It J"_', :)' ~~ 'r, "j."I'.. - ... ~ r. "'...... :~... ~.. ... \. . SECTION 05 - FIREFIGHTING MEASURES (CONT) HMIS HAZARD CODES - HEAL TH/FLAMMABIUTY /REACTlVITY o 3 o SECTION 06 - ACCIDENTAL RELEASE MEASURES SPill/LEAK CLEAN-UP PROCEDURES: SCOOP UP A VOID DUSTING. DISPOSE OF WITH SOLID WASTE ACCORDING TO FEDERAL, STATE AND LOCAL REGUlATIONS. FLUSH SPILL AREA WITH WATER. EPA HAZARDOUS SUBSTANCE REPORTABLE QUANTITY NOT liSTED SECTION 07 - HANDLING AND STORAGE PRECAUTIONARY MEASURES: A VOID BREATHING DUST AVOID EXCESSIVE DUSTING CONDmONS. DISPOSAL METHOD' DISPOSE OF WITH SOLID WASTE ACCORDING TO FEDERAL, STATE AND LOCAL REGUlATIONS. RCRA CLASS. NOT REGULATED SECTION 08 - EXPOSURE CONTROLS/PERSONAL PROTECTION VENTILATION GENERAL PRECAUTIONARY MEASURES SUGGEST USE WITH ADEQUATE VENTlIATION.. RESPIRATORY PROTECTION DUST MASK WHERE DUSTING eAriNOT BE AVOIDED EYE PROTECTION. SAFETY GlASSES. SKIN PROTECTION. NONE REQUIRED ; I PERSONAL HYGIENE. OBSERVE ORDINARY MEASURES OF PERSONAL HYGIENE. PROTECTIVE MEASURES DURING REPAIR/MAINTENANCE OF EQUIPMENT WASH EQUIPMENT THOROUGHLY WITH STEAM OR WARM WATER UNTIL CLEAN.. CHECK FOR FlAMMABLES WITH AN 'EXPWSION METER' AND ALSO CHECK THE OXYGEN LEVEL Please see reverse side for additional information .. Telephone 973 628 4000 1361 Alps Road Wayne, NJ 07470 Emergency 1 800 228 5635 Ext. 016 Medicellnformation' 612221 3999 Ext. 016 Transportation Emergency' CHEMTREC 1 800 424 9300 ~ ISP TECHNOLOGIES INC . .~SDS ~o~i~~ft{f~fv: {"":;t';.'~:: ....,.:~::p,:~~~::..<..;~,...:, _..':~' :., ..,.:;'~ ',: .;i.,~+:" o_~:.;.';':~~",_~;.:t; Y.':::t..~~~ ".~; ;'?~ I ~~~"i ...~....J>. "~,.-'I t.....-.t-'l., i'.(- ~"'\,/,:.lJ-~. \'" . .....),... \"L'''~~' SECTION 08 - EXPOSURE CONTROLS/PERSONAL PROTECTION (CONT) WITH AN OXYGEN METER. IN ALL CASES, FOLWW GOOD INDUSTRIAL SAFETY PRACTICES BEFORE ENTERING EQUIPMENT EXPOSURE UMITS. FOR INERT OR NUISANCE DUST (PARTICUlATES NOT OTHERWISE REGUlATED/ClASSIFIED)' OSHA PEL.TWA 15 MGjM3 - TOTAL DUST, 5 MGjM3 - RESPIRABLE FRACTION ACGrn TLV TWA 10 MGjM3 - INHALABLE, 3 MGjM3 - RESPIRABLE SECTION 09 - PHYSICAL AND CHEMICAL PROPERTIES BOIUNG POINT NO DATA FOUND VAPOR PRESSURE. NOT VOlATILE VAPOR DENSITY (AIR = 1) NOT VOlATILE WATER SOLUBIUTY SOLUBLE MELTING/FREEZING POINT NO DATA FOUND APPEARANCE. WlllTE TO CREAMY WHITE POWDER SPECIFICGRAV (WATER=1) NODATAFOUND PERCENTAGE VOLATILES: 5.00 % WATER (MAXIMUM) EVAPORATION RATE. NOT VOLATILE pH OF SOLUTION. 3.00 - 7.00 (5% SOLUTION) ODOR: NO DATA FOUND SECTION 10 - STABILITY AND REACTIVITY STABIUTY STABLE UNDER NORMAL STORAGE CONDmONS. HAZARDOUS POLYMERIZATION. WILL NOT OCCUR UNDER NORMAL STORAGE CONDmONS. CONDITIONS TO AVOID' HEAT, FIRE, SPARKS AND OTHER SOURCES OF IGNITION. AVOID EXCESSIVE DUSTING CONDmONS. INCOMPATIBLE MATERIALS: STRONG OXIDIZING OR REDUCING AGENTS. HAZARDOUS DECOMPOSITION PRODUCTS. TOXIC FUMES OF NOx EMI'ITED WHEN HEATED TO DECOMPOSmON. I I SECTION 11 - TRANSPORT INFORMATION -DOMESTIC DATA- Please see reverse side for additional information ~ ISP TECHNOLOGIES INC .. Telephone 973 628 4000 1361 Alps Road Wayne, NJ 07470 Emergency Medical Information Transportation Emergency' MSDS NO -1467 12 RtV 12 1 800 228 5635 Ext. 016 612221 3999 Ext. 016 CHEMTREC 1 800 424 9300 Page 6 ~, ~~~~..~, SECTION 11 - TRANSPORT INFORMATION .(CONT) DOT SHIPPING NAME NOT REGULATED DOT HAZARD CLASS NOT REGULATED HAZARDOUS INGREDIENT(S) NONE UN NUMBER NONE -EXPORT DATA- EXPORT SHIPPING NAME. NOT REGUlATED EXPORT HAZARD CLASS NOT REGUlATED HAZARDOUS INGREDIENT(S) NONE UN NUMBER: NONE / Please see reverse side for additional information . . unltlema MATERIAL SAFETY DATA SHEET Page Revised Replaces Printed 1 of 7 12/28/99 4/02/98 3/31/00 PHOSPHOLIPID CDM UNIQEMA MSDS 10: 806611 1 CHEMICAL PRODUCT ANI) COMPANY IDENTIFICATION Material Name PHOSPHOLIPID COM ICI Americas Inc POBox 15391 Wilmington, Delaware 19850 ICI Operator (24 hr ;;:"-" Medical Emergency (2 Chemical Emergency ( Spills, Leaks, Fir Values are not 2 .gredients Sodium coco OSHA PEL 0-79-2) Not listed General Limited toxicity data are ava1 hazard assessment is based on the ific product; this health ning tests Emergency OVerview Appearance Clear yellow liquid CAUSES EYE IRRITATION MAY CAUSE SKIN IRRITATION INHALATION OR INGESTION MAY CAUSE MUCOUS MEMBRANE IRRITATION MAY BE HARMFUL IF SWALLOWED I Routes of exposure Eye contact; Skin contact; Inhalation / Symptoms of OVerexposure (Acute & Chronic) Eye contact This material will cause eye irritation following contact .n contact This material will probably irritate human skin This product will probably not be absorbed through human skin IJ.lR~~ Plaza, 3411 Silverside Road, Wilmington. DE 19810 lerepnooe~alf22-8215, (302) 887-3000 Fax (302) 887-3525 L.-' HelP IIIlISIbIeClrl' ""Ar.." ~ - ~ Uniq8ma is lII1 Wll8fl\8lional business 01 Imperial Chemic:allnduslries PlC. Uniqema operates lhrough ICl affiliated companies in ~ the releYanl count'-. such as ICI Americas Inc., Unichema. . division oIlndopco Inc., and Mona Industries in the USA. .. . unlQema Page Revised Replaces Printed 2 of 7 12/28/99 4/02/98 3/31/00 MATERIAL SAFETY DATA SHEET PHOSPHOLIPID COM UNIQBMA MSDS ID 806611 3 HAZARDS IDENTIFICATION (Cont ) High concentrations of mists or aerosols may irritate respiratory passages No toxic effects are known to be associated with inhalation of this material Ingestion In humans, irri develop followi This material m Skin esophagus and stomach can Chronic Effects No thi chronic exposure to ~~_;~ FIRST AID Eyes f2;;;t:.~ \ Immediately flu '":' ';~lenty of water redness, itChi~g~~. .\.rning sensation~L,::. ,_ treated by med~c~ .~ . el"'!" ~~.~r .v~}j' Wash material off ~~:~: itching, or a burning'; . Ingestion . DO NOT INDUCE VOMITING " refer to medical personnel or rR' poison control center Never give anyt person Inhalation Remove victim to develop, consult ast 15 minutes If ops, have eyes examined and of soap and water If redness, ~l!'lSet medical attention .,. -3;# es of water to drink and .m either a phyaician or a h to an unconscious fresh air If a cough or other respiratory sYmptoms medical personnel 5 FIRE FIGHTING MEASURES / '/ Flashpoint and method >200 deg F, 93 33 deg C (PMCC) Autoignition temperature No data Flammable limits No data inguishing media ~. Water fog, alcohol foam, carbon dioxide, dry chemical, halogenated agents S),l,q~Copqxp3~i~~~~ oe~!pment tt~ (8OOflt1~-~5:'fJ02J~f~- - -Fax (302) 887-3525 l.-' ~.IbIeClll" ,t ANlctl - ~ ~ Unoqema is.... inlemalional business 01 Imperial Chemical Industlies PlC. Uniqema operates through lei alfilialed companies in the relevant countnes, such as ICI Americas Inc., Unidlema. a division oIlndopco Inc., and Mona Industries in the USA. .. . unlQ.ema Page Revised Replaces Printed 3 of 7 12/28/99 4/02/98 3/31/00 MATERIAL SAFETY DATA SHEET PHOSPHOLIPID COM ONIQEMA MSDS 10 806611 5 FIRE FIGBTIN<1 MEASURES (Cont . ) Self-contained breathing apparatus with full facepiece and protective clothing Unusual fire and explosion hazards None known Explosion data Sensitivity to Sensitivity to ~r to Section 8 ipment 'lled 1 a chemical waste aining detergent and flush to treatment facility Storage requirements 50-90 Precautions to take during handling and Prevent skin and eye contact Avoid breathing this material Do not swallow Normal chemical handling and storage J I 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure limits No ACGIH TLV or OSHA PEL assigned good hygiene practice Minimize exposure in accordance with i~ineering controls Use ventilation adequate to maintain safe levels E.Vg~dfDB~.p~~3411 SilversideRoad. Wilmington. DE 19810 ~~epK'o1'Ie.taOOr82z-'8'~fS. (302) 887-3000 Fax (302) 887-3525 L.'$. RespansillleClll" ,t APrIiIaC 11 I ~ Uniqema is an international business of Imperial Chemica/Industries PLc. Uniqema operates lIvough leI affiliated companies in ttw. NllI""",nl r.nuntNM: ~"""'~!I:. 1(;, ArnI'nNlIct Inr Ilnir.hAnuli A rtivicinn nf IntInnr';n loc.. and IMnn.R Irvtuc:.tf'im;. in the USA. .. . unlQema MATERIAL SAFETY DATA SHEET Page Revised Replaces Printed 4 of 7 12/28/99 4/02/98 3/31/00 PHOSPHOLIPID CDM ONIQBMA MSDS 10' 806611 8 EXPOSURE CONTROLS/pERSONAL PROTECTION (Cont.) Chemical tight goggles Protective clothing Impervious gloves Respiratory protection Not normally ne . ,"~ ~arance & odor liquid vJor threshold No Boiling point 203 d C Melting point No da Vapor pressure (mm H ,. g C) No data Vapor density (air = ~ ,:~,.. _ ta pH - 6 ( 10% aqueous Vi"~-~~' .;~'!.:?:~t~.;.. >. . .' . 02n!'~~!F ~~~~,u~~ Spec~f~c grav~ty 1 v. ~f;-S. ~;t'h'N~~.~::.~.~',~ % Volatile by volume -.~.~. ._~tf:-::~'" ..;. ,- .r-..,,:......~ Cloud ~oint No data t/:~~1~>.~ Viscos~ty No data ' .,t'~\h~> Partition Coefficient No data ~.' Coefficient of water/oil distribution Freezing point No data Other protective equ Eyewash station 10 STABILITY AND REACTIVITY Stability Stable under normal conditions I I Incompatibility Oxidizing agents Conditions to avoid None known Hazardous decomposition products Cornbul:>Llul1 ~ CQ.l.Lon dioxide, Uniqe~~~ .. .W~DE19810 Tel~"''aWtlti'l-8215.1: - f!'aX~SlJt-3525 carbon monoxide. llitrogcn=s, L.~ RlspHsltllCaII" "it ANkr - . ttQ Uniqema is an inIema1iona1l:Mit-. 01 ~ Chemicellnduslriea PlC. Uniqema opera1eS ttvough lei affilialed c:ompanies in "- ....a.u.,... ~""tnac CIIIf""h ~ Irl A~<< hv- II~ "rtivicinn nllrvtnrw-n I~ llIIM Unru:li Irw1ItctrilllC in thA IIAA. .. . unltlema MATERIAL SAFETY DATA SHEET Page Revised Replaces Printed 5 of 7 12/28/99 4/02/98 3/31/00 PHOSPHOLIPID COM ONIQEMA MSDS ID' 806611 '!. 10 STABILITY AND RBACTIVITY (Cont.) Hazardous polymerization Will not occur The toxicity da tests on this s results of screening Eye contact A 5% au mildly to the materia ested. This material was ion studies However, due it is expected that this e irritation ~Ain contact A 5% s the pe to cau sted However, due to is material is expected Acute oral toxicity g/kg This material is ingestion Carcinogenicity OSHA, IARe, Reproductive Mutagenicity No available information , Other effects of overexposure No other adverse clinical effects have been associated with exposures to this material Toxicologically synergistic products None known I I 12 ECOLOOICAL INFORMATION No data is available on this product ~. Uniqema, Concord Plaza. 3411 Silverside Road. Wilmington. DE 19810 Telephone (800) 822-8215 (302) 8873000 Fax (302) 887-3525 L.'$. RllpGlWllltClll" ,lANk" - . ~ Uniqelna is ." inlemationaI business 01 Imperial Chemical ~ PLC. Uniqema operat.. through ICI alfillated . in ..... ..oa-~~ ..--ontnAC ~..,...".. Irl 61T\Oo~oe II'W'" II~ . rtiuictinn ^'.~ 1f'V' "rvI L4nnA Irwtll~ in fhcI. ~ 4 . unlQema MATERIAL SAFETY DATA SHEET Page Revised Replaces Printed 6 of 7 12/28/99 4/02/98 3/31/00 PHOSPHOLIPID COM UNIQEMA MSDS ID 806611 13 DISPOSAL CONSIDERATIONS Disposal method Discarded product is not a hazardous waste under RCRA, 40 CFR 261 Container disposal Empty container retains product residue Observe all hazard precautions Do not distribute, make available, furnish or reuse empty container except for stor ~-c.\ . ,- {- ---- ,. . ~nal product Remove all product residue from co ',. erwise destroy empty container before disposal ~".. ..~~ ~~.... ~t.t;~~:tb~i:.~~~'::~i~sIfrl-,t . . ~{~. ..~ ,,:~/~;". TRANSPORT ;....~'. ~ .,_:;.~J'}~ ! __1~. ~". . D ~rtment of Transp~~y~~n Not regulated ..""'l'.~ . -.. .~...: '"\ ... ~0G (Transporation o~ us Goods) Not OSHA Hazard Communication Standard, 29 Physical Hazards None Health Hazards Irritant (eye) TORY TSCA .;.:!.' ... latioHs, 40 CFR 710 - ':,'~Substance Inventory DSL (Canadian Domestic Subs All ingredients NOT con azard Summary WHMIS Classification Class 0, Division 2 -- Toxic CERCLA and SARA Regulations (40 CFR 355, 370, and 372) This material contains the following chemicals subject to the reporting requirements of SARA 313 **** NO SARA 313 CHEMICALS FOR THIS CHEMICAL **** ; / S~RA 311/312 Hazard categories ~ Immediate YES Delayed NO 1'1re' NO Un~ 341tJii\verside Road. Wilmington. DE 19810 TelepMM 1SWJ'~~15. (~~7-3000 Fax (302) 887-3525 . l'" RespoastitClll" " INlIer - . ~ ~ IS an inl_lionaJ ~ 01 Imperial Chemicallnduslries PlC. Uniqema operates lIvough ICI affolialed companies in .. .&. ...... ______ ,__ 1_.......___ .4;.";_;__ ._...____ ,__ __.... ,.___ 1_............__ ;_....... lCO .. . unlQema MATERIAL SAFETY DATA SHEET Page Revised Replaces Printed 7 of 7 12/28/99 4/02/98 3/31/00 PHOSPHOLIPID CDM UNIQBMA MSDS 10: 806611 "!. 15 REGULATORY INFoRMATION (Cont.) Reactivity NO State Regulations None 3 Information Health 1 Flammability 1 Reactivity 0 '.'!consistent - ' ',;,..5~; !i!}J~J~y ~~-lf.~'t(.,,:''''':' j\.r}frl~~_~~ : ;~.z;><<,"l~;...~.,!;' ~i)J-;':i><' ~" ;;y-~~~ ~ ~;.) ~~l%Ii~l product based on the r is most aware of the proper personal protective ion contained in the We assigned NFPA rat hazards of its ingre application of the p equipment (PPE) is p product MSDS * NFPA Information Health 1 Flammability 1 Reactivity 0 -"-i . . ~k ;. *This information is intende2r . ... the particular hazard rat1ng system trained in ..."..., \..-a( This Material Safety Data Sheet was prepared~~~: Services Department .' ....t5.; Date 7/12/99 Regulatory r I The information herein is given in good faith I but no warranty, expressed or implied, is made (R) is a Registered Trademark of ICI Americas (TM) is a Trademark of ICI Americas Uniqema, Concord Plaza, 3411 Silverside Road, Wilmington. DE 19810 Telephone (800) 822-8215, (302) 887-3000 Fax (302) 887-3525 L.'$. ReIpoadlleClll" "it ANlcr - . ~ Uniqema is lIIl internalionlll ~ allmperial Chemic:al1ndustrtes PLC. Uniqema operaI_lIwough ICI affiliated companies in - thp ""',v,,,,, l'O""'""~ .."'" "" let Americas ,"" lJniehet'n;o) a dMsion 01 tndooco loc. and Mona Industries in !he USA i~~' :\ ~, ' ",'/:' .....:_ .,/'~ .f Material Safety Data Sheet 12601 Twinbrook Parkway Rockville, MD 20852 USA Responsible Partyl Roger Williams Telephone calls: (301) 881-0666 8:00am - S'OOpm EST Mon. - iri. ATfENTJON! USP Reference Standards are sold for chemical test and assay purposes only and NOT for human consumption. The information contained herein is applicable solely to the chemical substance when used as a USP Reference Standard and does not necessarily relate to any other use of the substance described, (i.e. at different concentrations, in drug dosage forms, or in bulk quantities). USP Reference Standards are intended for use by persons having technical skill and at their own discretion and risk. This information has been developed by USP staff from sources considered reliable but has not been independently verified by the USP Therefore, the USP Convention cannot guarantee the accuracy of the information in these sources nor should the statements contained herein be considered an official expression. NO REPRESENTATION OR WARRANTY EXPRESS OR IMPLIED INCLUDING THE WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE is made with respect to the information contained herein. Catalog Number' 44350 MICONAZOLE NITRATE Revision Date: Package Size: 200 mg June 28, 1999 I SECTION 1 - IDENTIFICATION I Common Name: Miconazole Nitrate Formula. C18H14Cl4N20 HN03 Synonym nlf Chemical Name: 1 H-Imidazole, 1-[2-(2,4-dichlorophenyl)-2-[(2,4- dichlorophenyl)methoxy]ethyl]-, mononitrate CAS Number- 22832-87-7 RTECS Number' NI477 1000 Chemical Family' An Imidazole Therapeutic Category' Antifungal Principle Components Miconazole Nitrate Usual Adult Dose: Adverse Effects: Overdose Effects: Acute: Chronic: Inhalation' Eye: Skin Ingestion. SECTION 2 - INGREDIENT INFORMATION Percent Exposure Limits Pure Material nlf I SECTION 3 - HEALTH HAZARD INFORMATION; The usual adult dose ofmiconazole nitrate (topical, to the skin) is as a 2% cream or lotion twice a day Possible allergic reaction to material if inhaled, ingested or in contact with skin. Symptoms of overdose may include nausea, vomiting, diarrhea, convulsions, andrart rhythm disorders. Possible eye, skin, gastrointestinal and/or respiratory tract irritation. Possible hypersensitization and diarrhea. May cause irritation. Remove to fresh air May cause irritation. Avoid eye contact. Flush with copious quantities of water There is little absorption through skin or mucous membranes when miconazole n)trate is applied topically, however, it has caused contact dennatitis. Flush with copious quantities ofwatet May cause irritation and toxicity A void ingestion. Flush out mouth with water This material is incompletely absorbed from the gastrointestinal tract. i oIf = not found I Copyright <0 2000 The United States Pharmacopeial Convention, Ine. All Rights Reserved. Page 1 of 3 AICONAZOLE NITRATE Catalog Number' 44350 Package Size: 200 mg Revision Date: June 28, 1999 Hypersensitivity to material, acute porphyria, and impaired liver function. Medical Conditions gravated by Exposure: Cross Sensitivity. Pregnancy Comments: Pregnancy Category' nlf Pregnancy problems with miconazole in humans have not been documented and it is considered safe for use during pregnancy, although some sources recommend that its vaginal use should be avoided during the first trimester B I SECTION 4' - FIRST AID MEASURES I General: Remove from exposure. Remove contaminated clothing. Persons developing serious hypersensitivity (anaphylactic) reactions must receive immediate medical attention. Ifperson is not breathing give artifIcial respiration. Ifbreathing is difficult give oxygen. Obtain medical attention. Overdose Treatment: nlf SECTION 5 - TOXICOLOGICAL INFORMATION Oral Rat: LD50' 920 mglKg Oral Mouse: LD50' 578 mglKg Irritancy Data. nlf Target Organ(s): nlf .isted as a Carcinogen? NTP' No IARC' No OSHA. No Other' No Flash Point: nlf I SECTION 6 - FIREFIGHTING MEASURES i Auto-Ignition Temperature: 3500 C Upper Flammable Limit: nlf Lower Flammable Limit: nlf Extinguisher Media. Fire and Explosion Hazards: Firefighting Procedures: Conditions to Avoid Incompatibilities: Decomposition Products: Water spray, dry chemical, carbon dioxide or foam as appropriate for surrounding fIre and materials. This material is assumed to be combustible. As with all dry powders it is advisable to ground mechanical equipment in contact with dry material to dissipate the potential buildup of static electricity As with all fIres\ evacuate personnel to a safe area. FirefIghters should use self-conrined breathing equipment and protective clothing. I I I SECTION 7 - PHYSICAL HAZARDS I I ; A void exposure to light. Oxidizing agents and alkalis. When heated to decomposition material emits toxic fumes of NO x and Cl- Emits toxic fumes under fire conditions. Hazardous Polymerization? No Stable? Yes SECTION 8 - HANDLING I SPILL I DISPOSAL MEASURES Copyright <<:> 2000 The United States Pharmacopeial Convention, Inc. All Rights Reserved. i oJf = not found Page 2 of 3 llCONAZOLE NITRATE Catalog Number' 44350 Package Size: 200 mg Revision Date: June 28, 1999 Handli~g: As a general rule, when handling USP Reference Standards avoid all contact and inhalation of dust, mists, and/or vapors associated with the material. Wash thoroughly after handling. Storage: Store in tight, light-resistant container as defined in the USP-NF This matenal should be handled and stored per label instructions to ensure product integrity Spill Response: Wear approved respiratory protection, chemically compatible gloves and protective clothing. Wipe up spillage or collect spillage using a high efficiency vacuum cleaner A void breathing dust. Place spillage In appropriately labelled container for disposal. Wash spill site. Disposal. Dispose of waste in accordance witlt all applicable Federal, State and local laws. SECTION 9 - EXPOSURE CONTROLS I PERSONAL PROTECTION Ventilation Gloves. Eye Protection Protective Clothing: When working with small quantities in a well-ventilated area, respiratory protection may not be required. The use of an approved dust mask is recommended. No special ventilation requirements. Rubber Safety Glasses Protect exposed skin. Respiratory Protection SECTION 10 - PHYSICAL AND CHEMICAL PROPERTIES NOTE The data reported below is general information, and is not specifIc to the USP Reference Standard Lot provided! Appearance and Odor' White or almost white crystalline or powder; slight odor Melting Point: 170.50 C (also reported as 1840 C) Solubility in Water' Very slightly soluble Boiling Point: nff Specific Gravity' n/f Vapor Pressure: nff Vapor Density' nff Evaporation Rate: nff Reactivity in Water' nff % Volatile by Volume: nff I I Copyright <0 2000 The United States Pharmacopeial Convention, Inc. All Rights Reserved. I nlf = not found i , ~ Page 3 of 3 Ciba Specialty Chemicals Corporation Consumer Care POBox 2444 High Point, NC 27261-2444 24-Hour Health/Environmental Emergency Phone 1-800-873-1138 Material Safety Data Sheet IRGASAN DP 300 MSDS No: 235 Date Printed: 04/19/00 1 PRODLCT IDENTIFICATION Chemical Family' 2,4 4'Tnchloro-2'-HydroxydIphenyl Ether Intended Use: AntimICrobial Agent NFP A RATING Product Name(s): IRGASAN DP 300 55 LBS. IRGASAN DP300 2.2# Product Code: 1562428C6 156492501 2. COMPOSITION / INFORMATION ON INGREDIENTS CAS No. 3380-34-5 Common Name: Tnclosan ACGIHlPPM TW A STEL - - None None Dermal. (Rabbit) LD50 > 6,000 mglkg InhalatIOn. (Rat) LC50 > 140 mgim3 Ingestion. (Rat) LD50 > 5,000 mg/kg 3 HAZARDS IDENTIFICATION Route(s) of Entry: Inhalation and dermal. Ciba .... . e.:. ". .. :.. :. ..... ........:. . .... :..- :.:: Value beyond chemIStry Effective Date: 1; 12/00 Health 2 Flammability 1 Reactivity 0 Protective Equipment E HMIS RATING OSHAlPPM PEL None % by Wt. 100 Potential Health Effects: Very toxic to aquatIc organisms. Target Organ Effect: Ammal studIes revealed the lIver IS a target organ at hIgh doses, however lIver mjury IS not likely to occur in humans because of the very low human exposures and the dIfferences In lIver responses between some specIes and humans. The U.S Food and Drug AdrnimstratlOn has concluded lower doses are safe for human consumptIOn. See SectIon 11 Carcinogenicity (NTP): Not lIsted. Carcinogenicity (IARC) Not lIsted. Carcinogenicity (OSHA). Not listed. Pnnted. 4/19/00 Page 1 of 7 Effective Date' 1/12/00 IRGASAN DP 300 Ciba Specialty Chemicals Corporation Consumer Care 4 FIRST AID MEASURES Ingestion. If conscIOUS, give plenty of water to dnnk. Get medical attentIOn. If unconSCIOUS, do not give anythmg to dnnk. Get lll11uedlate medical attentIOn. Skin. Wash with mild soap and water If irntation occurs, get medical attentIOn. If clothmg IS contaminated, remove and wash before reuse Inhalation. Remove to fresh air Get medical attentIOn. Eyes. flush eyes with water for at least 15 minutes. Get medical attentIOn. 5. FIRE FIGHTI~G MEASURES Flash Point: Flash Point Method Used. Flammable Limits in Air (Lower - % by volume) Flammable Limits in Air (Upper - % by volume) Auto-Ignition Temperature: TDG Flammability Class (Canada) 2230 C (433 0 f) ASTM 056 (Tag Closed Cup) Not applicable 1\lot apphcable Not apphcable Not regulated General Hazards: None known. Fire Fighting Equipment: Use self contained breathing apparatus Fire Fighting Extinguishing Media. Carbon dioxide, dry chemical, foam, water Fire and Explosion Hazards: No unusual hazards. Hazardous Combustion Products: Burning may produce hydrogen chloride, chlorine and oxides of carbon. Explosive Data-Sensitivity to Mechanical Impact: Not evaluated. Explosive Data-Static Discharge: Not evaluated. Emergency Response Guidebook Information: None 6. ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Shovel into approved disposal contamer Vacuum contammated area. Avoid creatmg dusty conditions. Water Spill. Prevent matenal from entermg sewers, waterways, or low areas. Large releases to surface waters may result m fish kills and reqUire reportmg to the local environmental authontles. 7 HANDLING AND STORAGE PIlnted. 4/19/00 Page 2 of 7 Effective Date: 1/12/00 IRGASAN DP 300 Ciba Specialty Chemicals Corporation Consumer Care CAUTION! For manufacturing, processIng, or repackaging. SkIn and eye irntatIon. AVOId contact with eyes, skIn and clothIng. Keep container closed. For industrial use only 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Personal Protective Equipment: Wear appropriate eqUipment to prevent probabilIty of exposure and personal contact. Deluge safety shower and eye wash should be located near work area. Eye Protection: Wear side-shield safety glasses. Skin Protection. Wear impervious gloves as a standard handling procedure. Respiratory Protection. In cases where there IS a likelihood of Inhalation exposure to the powder (dust), wear a NIOSH approved dust respirator Engineering Controls: Local exhaust recommended, mechanical exhaust acceptable. Emergency Response Protection: No additIOnal speCIalIzed eqUIpment should be requIred. 9 PHYSICAL AND CHEMICAL PROPERTIES Physical Form: Color' Odor: Odor Threshold: Solubility in Water' Powder WhIte Odorless Not evaluated 001 gll at 200C (68 OF) Miscible in cold water (forms hazy solution in warm water) 7xl0(exp-4) Pa Not evaluated Not applicable 56 580 C (133 - 136 0 F) Not applicable > 2800 C (> 536 0 F) Not applIcable Not applicable Not applicable Not applIcable log Pow = 4 8 Vapor Pressure: Specific Gravity: Boiling Point: Melting Point: Freezing Point: Decomposition Temperature: Evaporation Rate: Bulk Density' Vapor Density' pH. Coefficient of water/oil: Volatile(s): DISSOCIation constent: pKa = 8 14 @ 200C 10. STABILITY AND REACTIVITY Stability' Stable Incompatibility' A VOId contact with chlorinating substances Hazardous Polymerization: Will not occur Pnnted. 4/19/00 Page 3 of 7 Effective Date: 1/12/00 IRGASAN DP 300 Ciba Specialty Chemicals Corporation Consumer Care 11 TOXICOLOGICAL INFORMATION Eye Irritation. (Rabbits) Irntant Skin Irritation. (Rabbits) Irritant Inhalation Toxicity' (Rats) LC50 > 140 mg/m3 Sensitization: In gumea pigS, not a dermal sensitIZer by maximization test or Buehler (non-adjuvant) test. RIPT (Humans) - Not a primary irritant, fatiguing agent or senSItizer Phototoxlcity (humans)' Not phototoxic by dermal route. Photoallergy (humans) Not a photosensitIZer by dermal route. Subchronic: The dermal NOEL m rats is 10 mg/kg/d for skm effects, systemic effects did not occur at doses up to 80 mg/kg/d. Oral dosing of rodents revealed NOELs of 100 (rat), 75 (hamster), and below 25 mg/kg/d (mouse) Oral dosing resulted in NOELS of 30 mg/kg/d m baboon and 25 mg/kg/d In dog. Chronic/Carcinogenicity' Chromc The pnmary target organ after oral dosing IS the liver in rats and nuce and the kIdney ill hamsters. The NOEL in rats IS 52 (males) and 67 (females) mg/kg/d, and in hamsters 75 mg/kg/d. Carcinogemcity. Rat and hamster chronic studies did not reveal any pre-neoplastic or neoplastic effects of oral dosing. A carcmogeniclty study in mice fed at 10 up to 200 mg/kg/d revealed a signifIcant incidence of tumors only in the liver of mi~e exposed to 30 mg/kg/d and higher The NOEL of 10 mg/kg/d IS over 600 times higher than relevant human exposure levels and, accordmg to the US Food and Drug Adrmnistration, provides sufficient margm of safety for human use. Teratology' Rats showed delayed fetal oSSIficatiOn at 150 mg/kg/day (gestation days 6 through 15), developmental effects did not occur; maternal and fetal NOEL = 50 mg/kg/day Mice showed maternal effects and delayed fetal ossIfIcatiOn at 150 mg/kg/day (gestatiOn days 6 through 15); maternal and fetal NOEL = 25 mg/kg/day Rabbits showed only maternal body weight and food mtake reductions at 150 mg/kg/day (gestation days 6 through 18); maternal ""JOEL = 50 mg/kg/day; fetal NOEL = 150 mg/kg/day Reproduction. Rat fertility and reproduction index values over two generations were not adversely affected at 150 mg/kg/day, the highest dose given in the dIet. For offspring (Fl pups), the NOEL is 50 mg/kg/day based on increased (p<O 05) body weight. Mutagenicity' Not mutagemc in bacterial (Ames) assay and mouse lymphoma test (TK locus) Not c1astogenic m CHO cells in vitro Unscheduled DNA synthesIs did not occur Negative ill mouse nucronucleus test m vivo. Acute Oral Effects: (Rats) DLSO > 5,000 mg/kg Acute Dermal Toxicity' Acute Dermal (RabbIts) LD50 > 6,000 mg/kg Additional Information: Dermal studies in animals and human volunteers did not reveal adverse systemic effects. AddItiOnal studies illdlcate the material does not accumulate in tissues and IS readily metabolized and removed from the body 12. ECOLOGICAL INFORMATION Biodegradability' Not readily biodegradable Pnnted. 4/19/00 Page 4 of 7 Effective Date' 1/12/00 IRGASAN DP 300 Ciba Specialty Chemicals Corporation Consumer Care Aerobic soil showed pnmary bIOdegradation with half-life 17-35 days. Secondary Wastewater Treatment (activated sludge)' 95% removal of influent concentrations. Ecotoxicity: Bluegill LC50 = 840 mcg 1 (96 HR), NOEC = 560 mcg/l (Fathead mmnow) LC50 = 260 mcg/I, "\JOEL = 100 mcg/l (96 HR), LClOO = 560 mcg/l (24 HR) (Rambow Trout) LC50 = 350 mcgl (96 HR) (Rambow Trout) (Early Life Stage) LOEC = 71.3 mcg/l, NOEC = 34 1 mcgil (Daphnia Magna) LC50 = 390 mcg:l (48 HR), NOEL = 100 mcg/l (Daphnia Magna) Chromc (21-day) LOEC = 200 mcg/l, NOEC = 40 mcgil Cenodaphnla dubla. EC50 = 130 mcg/! Earthworm (EIsema foetida foetida) LC50> 1 026 mcglkg Algae (Scenedesmus subsplcatus) NOEC = 0 46 mcg/l Cucumber' Seedling Growth Test: For all endpomts NOEC> 1,000 mcglkg Bobwhite Quail. Oral acute LD50 = 862 mg/kg Bobwhite Quail. 8-day feedmg, LC50 > 5000 ppm, NOEL = 1250 ppm Mallard Duck: LD50 > 2150 mg/kg Biological Oxygen Demand (BOD5) < 0 01 mg/g Chemical Oxygen Demand (COD) 1 116 gig Activated Sludge Respiration Inhibition Test: InhibItion (IC50) @ 20 mgil (3 HR) NitrIfIcation InhibItion. IC50 = 11 4 mg/l Additionallnformation: TOC/DOC AnalysIs, OECD 301C TOC = 50% Organohalogen content = 36 7% 13. DISPOSAL CONSIDERATIONS Waste Disposal Method. Incmerate m a furnace where permItted under appropriate federal, provmclal and local regulatIon. Container Disposal Information. Emptied contamer may contain product residue and should not be reused. RCRA Hazard Class. Refer to SectIOn 15 Regulatory Information for RCRA status. 14. TRANSPORT INFORMATION DOT Proper Shipping Name: lATA. Proper Shipping Name: IMDG Proper Shipping Name' Technical Shipping Name (If n.o.s.)' Hazard Class: ID Number' Packing Group: TDG Proper Shipping Name: Not Regulated Not Regulated Environmentally hazardous substance, solid, n.o.s. (Contams Triclosan, Manne pollutant) 9 UN 3077 PG III Not Regulated Pnnted. 4/19/00 Page 5 of 7 Effective Date: 1/12/00 IRGASAN DP 300 Ciba Specialty Chemicals Corporation Consumer Care Department of Transportation: Section 171 4 Manne Pollutants. (c) ExceptIOns. Except when transported aboard vessel, the requirements specific to manne pollutants do not apply to non-bulk packagmgs transported by motor vehicles, rail cars or aircraft. 15. REGULATORY INFORMATION US Federal Regulations Chemical Weapons Convention (CWC). ThiS product does not contain any chemicals lIsted under the Cherrucal Weapons Convention Schedule of Cherrucals. Clean Air Act -Hazardous Air Pollutants (HAP) ThIs product does not contam any hazardous air pollutants (HAP), as defined by the U.S Clean Air Act Section 12 (40 CFR 61) Clean Air Act - Ozone Depleting Substances (ODS): This product neither contams, nor was manufactured with, a Class I or Class II ozone depleting substance (ODS), as defmed by the U.S Clean Air Act Section 602 (40 CFR 82, Subpt. A, App A+B) Clean Water Act - Priority Pollutants (PP) This product does not contain any priority pollutants listed under the U.S. Clean Water Act Section 307 (2)(1) Priority Pollutant List (40 CFR 401 IS). Occupational Safety and Health Act (OSHA)' ThiS product IS considered to be a hazardous chemical under the OSHA Hazard Communication Standard (29 CFR 1910 1200) . Resource Conservation and Recovery Act (RCRA): ThiS product is not considered to be a P or U lIsted hazardous waste under RCRA (40 CFR 261). SARA Title III. Section 302 - Extremely Hazardous Substances (EHS): ThIs product does not contain any chemicals regulated under Section 302 (40 CFR 355) as extremely hazardous substances. SARA Title III. Section 304 - CERCLA: This product does not contain any chemicals regulated under Section 304 (40 CFR 302) as hazardous chemicals for emergency release notification ("CERCLA" List). SARA Title III. Section 311/312 - Hazard Communication Standard (HCS) This product is not regulated under Section 311- 312 (40 CFR 370). SARA Title III. Section 313 Toxic Chemical List (TCL): This product does not contain any chemicals for routine annual toxic chemical release reporting under SectIOn 313 (40 CFR 372). TSCA Section See) - Consent Order / SNUR. This product IS not subject to a Section 5(e) Consent Order or Sigmficant New Use Rule (SNUR) TSCA Section 8(b) - Inventory Status: All cherrucal(s) comprising this product are either exempt or lIsted on the TSCA inventory TSCA Section 12(b) - Export Notification. This product does not contaID any cherrucal(s) that are subject to a Section 12(b) export notificatIOn. International Regulations Canadian Inventory Status: This product contaIDs only chemicals that are currently lIsted on the Canadian Domestic Substance LiSt. Pnnted. 4/19/00 Page 6 of 7 Effective Date: 1/12/00 IRGASAN DP 300 Ciba Specialty Chemicals Corporation Consumer Care Canadian WHl\nS. This product does not contaIn any chemicals hsted on the Canadian WHMIS Ingredient Disclosure LIst. Controlled product, Class D2B State Re2ulations California Proposition 65' This product does not contain any chemicals currently on the CalIfornia list of Known Carcinogens and ReproductIve Toxins. Massachusetts Right-to-Know' ThIS product does not contaIn any chemicals which are subject to Massachusetts Right-to-Know dIsclosure reqUIrement. New Jersey Right-to-Know' The folloWIng IS requIred composItIon informatIOn. ChemIcal Name Phenol,5-chloro-2-(2,4-dIchlorophenoxy)- CASRN 3380-34-5 Pennsylvania Right-to-Know' The folloWIng IS reqUIred compositIon information. Chenucal Name' Phenol, 5-chloro-2-(2,4-dichlorophenoxy)- CASRN 3380-34-5 Comment: Not on Pennsylvania Hazardous Substance List 16. OTHER INFORMATION MSDS No: Prepared By' Approved By' Title: Approved Date: Supersedes Date: 235 Reba Lemons Frances E. Knight Manager, Product RegistratIon 01/11/00 07/29/99 Revision Summary: Changes m SectIOn(s) 2 Disclaimer' For further mformatIOn, please contact: Phone' (336) 801-2373 Product StewardshIp Team. Fax. (336) 801-2056 The Information and recommendatIons contaIned herem are based upon data believed to be correct. However, no guarantee or warranty of any kind expressed or Implied IS made with respect to the information contamed herein. This material safety data sheet was prepared to comply WIth the OSHA Hazard CommunicatIOn Standard (29 CFR 1910 1200) and WIth the Workplace Hazardous Matenals InformatIOn System (WHMIS) This supersedes any previous mformation. Printed. 4i 19i00 Page 7 of 7 MATERIAL SAFETY DATA SHEET PRODUCT IDENTIFICATION f3 v C /1- tS~ EPA Registration No. 48139-6 Everglades@ Everyday Insect Repellent Everglades@ Everyday Insect Repellent Towelette SECTION I - GENERAL INFORMATION MANUFACTURER: Hilton Head Laboratories, Inc. POBox 1960 Bluffton,SC 29910 EPA Est. No 62828-SC-001 DATE PREPARED' 01/01/97 EMERGENCY TELEPHONE NO 843-987-3100 Anytime INFORMATION: Same PREPARED BY Nancy S Ball SECTION II - HAZARDOUS INGREDIENTS N,N-Diethyl-M-Toluamide( CAS # 134-62-3) Isopropyl Alcohol (CAS #67-63-0) 28.50% 40.00% ACGIH Threshold Limit Value: None SECTION III - PHYSICAUCHEMICAL CHARACTERISTICS Freezing Point: No Information Found Boiling Point: 1820 F Vapor Pressure: No Information Found Vapor Density. No Information Found Appearance: Clear Liquid Solubility(Oil)' Soluble Solubility (Water): SI Soluble Decomposition Temp No Information Found Auto-ignition Temp No Information Found Flashpoint: 740 F (23 C) PMCC Evaporation Rate: No Information Found Odor' Mild Aromatic Sp Gravity @200C' 0.920 Ibs/Gal: 7.68 Viscosity. No Information Found Percent Volatile: No Information Found pH: No Information Found Corrosion Rate: No Information Found SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash Point (Method Used): 740 F (PMCC) Flammable Limits (Lower and Upper): No Information Found Extinguishing Media: Foam, Carbon Dioxide, Dry Chemical, Water, Fog Special Procedures. Use self-contained breathing apparatus, cool fire-exposed areas and equipment. Unusual Fire/Explosion Hazards: None SECTION V - REACTIVITY DATA Stability. Stable Conditions to Avoid: None Incompatibility. Strong Oxidizing Agents azardous Decomposition or Byproducts: None Known Hazardous Polymerization: Will not occur PAGE 2: Insect Repellent, Everyday SECTION VI - HEALTH HAZARD DATA ROUTE OF SYMPTOMS FIRST AID ENTRY Eye May cause severe irritation with tearing Flush with plenty of water for at least and blurred vision 15 minutes. Contact a physician if irritation persists. Ingestion Can cause irritation of the stomach and Give affected person 2 glasses of water intestines, possibly resulting in nausea and get medical attention and vomiting. immediately Acute Oral Toxicity lD(50) - 6000 mg/kg Inhalation Should not cause problems at nc~mal Remove affected person to fresh air temperatures, but the inhalation of the Give oxygen, if necessary Apply vapors at elevated temperatures may artificial respiration if indicated and cause nasal and respiratory irritation. get medical attention immediately lD(50) - 10,000 MG/KG Skin Contact with this product before dilution Immediately flush affected areas with may cause irritation ( it may be severe in water Remove contaminated clothing some cases) and wash affected areas with soap Acute Dermal Toxicity-lDSO - 10,000 and water Contact a physician if mg/kg irritation persists. Toxicity Category III Chemicals listed as carcinogens or potential carcinogens: ; Nat" Toxicology Program' None (ARC Monographs: None OSHA. None SECTION VII - PRECAUTIONS FOR SAFE HANDLING & USE PESTICIDE STORAGE AND SPill PROCEDURES. Store upright at room temperature. Avoid exposure to extreme temperature In case of spill or leakage, soak up with an absorbent material such as sand, sawdust, earth, fuller's earth, etc. Dispose wit chemical waste. Do not contaminate water, food or feed by storage or disposal. PESTICIDE DISPOSAl. Pesticide or mixture that cannot be used according to instructions must be disposed of at or by c approved waste disposal facility SECTION VIII - CONTROL MEASURES RESPIRATORY PROTECTION Normal (Mechanical) Exhaust EYE PROTECTION OSHA - approved safety glasses or goggles PROTECTIVE CLOTHING. Rubber or impelVious gloves OTHER PRECAUTIONS. See SECTION VII HYGIENIC PRACTICES. Wash hands before eating and smoking. SECTION IX - TRANSPORTATION SHIPPING NAME. PESTICIDE,lIQUID, TOXIC, FlAMMABLE, NOS IDENTIFICATION NUMBER: UN2903 HAZARD CLASS. III REPORTABLE QUANTITY limited Quantities LABElS REQUIRED' None UNIT CONTAINER. 4 OZ Polyethylene Bottle DISPOSAL METHODS See SECTION VII APPLICABLE REGS. 49CFR AEROSOL PROPEllENTS. None HAl. WASTE: None MATERIAL SAFETY DATA SHEET ~Clariant GLARIANT CORPORATION 't000 Jvl)NROE ROAD 0IARlGITE, N C 28205 hemical Emergency _ CHEM'l'REC - Day or Night .L-dOO-424-9300 PACKAGING CONCEPTS ASSOC INC 4925 PARK RIOOE BLVD BOYNTON BEACH FL 334260000 ATTN Product Safety Manager DIAHOLD 242580 A-S03- VERSION 01 REVISED DATE 07/15/1999 Page 1 For MSDS Info (704) 331-7710 CLARIANT Corporation (704) 331-7000 ------ H MIS ------ HEALTH 2 * ~ILITY 3 REACIIVlTY 1 PERSONAL PROTECIION H ----------~------------------------------------~---------------------------------------------------- SECIION 01 - PROoucr IDENTIFICATION TRADE NAME DIAHOLD A-S03- PROoucr CODE 242580 VERSION NU1BER 01 ALPHA CODE NOT AVAILABLE CAS NU1BER NOT AVAILABLE SYNONYMS PRODUCT HAS NO SYN:>NYMS CHEMICAL FAMILY ETHANOL SOUJrION OF CARBOXYLIC ACID TYPE ANIONIC ACRYIATE RESIN FORMUIA NOT AVAILABLE PRIMARY PRODucr USE SPECIALTY CHEMICAL SECIION 02 - CCMPOSITION INFORMATION ON HAZARDOUS INGREDIENTS ?ONENT .rlANOL lDSO(ORAL) (RAT) - 7060 foI;/KG LeSO (INHAlATION) (MJUSE) (4HR) - 39000 foI;/M3 CAS NO 64-17-5 WT\ 60 PEL/TLV 1000 PPM OSHA ACGIH SECIION 03 - HAZARDS IDENTIFICATION (REFER TO SECI'ION 11 FOR ADDITIONAL INFURMATION) EXPEcrED ROUI'E OF ENTRY SKIN CONTACI X SKIN ABSORPTION EYE CONrACI X INHAlATION X IroESTION X EFFECIS OF EXPOSURE E'IliAOOL CONCENTRATIONS EXCEEDIN3 1000 PPM MAY CAUSE IRRI-dTION TO '!lIE EYES AND UPPER RESPIRATORY TRACT IF EXPOSURE AT HIGH ~TIOOS IS PROI.DN3ED, STUPOR AND DROWSINESS MAY OC'CUR A CENTRAL NERVOUS SYSTEM DEPRESSANT CAN CAUSE GLANOOI..AR EFFECTS IN HtJ.1ANS REPORTED TO BE AN ~ Tt.M:>R.IGENIC AGENT AND A SUSPECI TERATCGEN IN3ESTION MAY CAUSE NAUSEA va-1ITIN3, ABDGUNAL PAIN, HEAaACHE, DIZZINESS, SHOR'INESS OF BREATH, DRUNKEN BEHAVIOR, VI~ DISTlJRBANCES DROWSINESS, cc::t-1A, OR DEATH VISUAL EFFECI'S INCLUDE BUJimED MATERIAL SAFETY DATA SHEET ~Clariant CLARIANT CORPORATION ~OOO r-DNROE ROAD CHPoUOTTE, N C 28205 hemical Emergency .L CHEM'l'REC - Day or Night 1-800-424-9300 DIAHOW 242580 A-S03- VERSION 01 REVISED DATE 07/15/1999 Page 2 For MSDS Info (704) 331-7710 CLARIANT Corporation {704} 331-7000 ------------------------------------------------------~~-------------------------------------------- SEcrION 03 - HAZARDS IDENTIFICATION (CONT ) VISION, DIPLOPIA, RESTRIcrION OF VISUAL FIElDS, CCMPLETE BLINDNESS "TIiERE IS INADEQUATE EVIDENCE FOR THE CARCINOGENICITY OF OF E'I'HAOOL AND ALCOHOLIC BEVERAGES IN EXPERIMENTAL ANIMALS TIiERE IS SUFFICIENT EVIDEN<Z FOR THE CARCINOGENICITY OF ALCOHOLIC BEVERAGES IN HU-1ANS" (IARC K:>NCX:mAPHS, VOLtJv1E 44 ) A CARBOXYLIC ACID TYPE ANIONIC ACRYIATE RESIN TESTS HAVE BEEN PERFORMED ON A SIMILAR ~ AND THE RESULTS FOR SUCH TESTS ARE LISTED BELOW AcurE ORAL TOXICITY TESTING WAS PERFORMED OVER FOURTEEN DAY PERIOD ON SWISS ALBINO STRAIN MICE BASED ON THE OBSERVED DATA, THE LOSO IS GREATER THAN 10 G (AS POLYMER SOLIDS) / KG OF BODY WEIGHT SUBAaJrE ORAL TOXICITY (90 DAYS) STUDY REVEALED THAT THE MAXIMUM NON-OBSERVABLE EFFEcr LEVEL IS 0 2\, THE LOWEST OBSERVABLE EFFEcr LEVEL IS 1 0\, AND THE OVERT TOXIC EFFECf LEVEL IS 5 0\ SIMILAR MATERIAL HAS BEEN CLASSIFIED AS "SAFE FOR Ht.J.1AN SKIN CONTAcr" SIMILAR MATERIAL WAS ALSO FOUND TO BE NON-SENSITIZING TO GUINEA PIG SKIN AND . WAS FOUND TO EXHIBIT NO EVIDENCE OF PHOTCYrOXICTY TO GUINEA PIG SKIN SIMILAR MATERIAL WAS ALSO CLASSIFIED AS "NEGATIVE" IN EYE MUCOUS TESTS DIAHOID A- 503 WAS FOUND TO BE NON-MUI'AGENIC AaJrE DERMAL TOXICITY (LOSO) WAS FOUND TO BE GREATER THAN 2000 M3/KG OF BODY WEIGHT JWN EFFECTS ON O'IHER ILI.1mSSES NO KNOWN EFFECTS ON OTHER. ILI.1mSSES FOR THIS PRODUCT LISTED CARCINOGEN NONE X OSHA NI'P IARC OTHER. SECTION 04 - FIRST AID MEASURES FLUSH IJ+1EDIATELY UNDER RUNNING WATER FOR FIFl'EEN MINUTES IRRITATION OCCURS, SEEK MEDICAL ATI'EN'I'ION , IF REnmSS OR FIRST AID FOR EYES WASH 'mQROtDILY WITH SOAP AND WATER FOR 15 MINUl'ES OCCURS, SEEK MEDICAL ATI'ENTICN / I IF SKIN IRRITATICN FIRST AID FOR SKIN FIRST AID FOR INHAlATION GET VICfIM TO FRESH AIR GIVE ARTIFICIAL RESPIRATION OR OXYGEN IF BRFATHIW HAS STOPPED GET PRQo1PT MEDICAL ATI'ENTION DO oor GIVE ~ IF VICfIM IS UNCONSCIOUS MA~ERIAL SAFETY DATA SHEBT ~Clariant CLARIANT CORPORATION 4000 MONROE ROAD CHARLOTTE N C 28205 :hemical Emergency .~ CHEMTREC - Day or Night .1.-800-424-9300 DIAHOLD 242580 A-S03- VERSION 01 REVISED DATE 07/15/1999 Page 3 For MSDS Info (704) 331-7710 CLARIANT Corporation (704) 331-7000 SECTION 04 - FIRST AID MEASURES (CONT ) FIRST AID FOR INGESTION IF INGESTED, SEEK MEDICAL ASSISTANCE NOTE TO PHYSICIAN NONE KNOWN SECTION 05 - FIRE FIGlITING MEASURES FLASH POINr (' F) ~LE LIMITS LEL VEL 54 (12'C) 3 3t 19t AUI'OIGNITION TEMPERATURE (' F) UNI<N::MN HAZARDOUS <n1BUSTION PRODUCTS THERMAL DE<:::a-D?OSITION MAY PRODUCE OXIDES OF CARBON XTINGUISHING MEDIA WATER X ALCOHOL FOAM X CO2 X DRY CHEMICAL X WATER/FOG SPRAY X NO EXTINGUISHIN3 MEDIA: SPECIAL FIRE FIGHTING PROCEDURES FIRE EXPOSED CONTAINERS SHOUID BE COOLED WInI WATER SPRAY FIRE FIGHTERS SHOUID WEAR FULL PROTEcrIVE CLO'llIIOO AND A SELF-CONTAINED BREATHING APPARATUS TO AVOID BREAnlING OF TOXIC FUo1ES PREVENT RUNOFF TO SEWERS AND BODIES OF WATER FRCM FIREFIGHTING INVOLVIOO nlIS MATERIAL AS IT WILL BE A RCRA HAZARDCUS WASTE WHEN IT BE<:.'CMES A WASTE MATERIAL IF A LEAK OR SPILL HAS NO!' IGNITED, USE WATER SPRAY TO DISPERSE THE VAPORS AND TO PROTEcr THE PERSONNEL A~ING TO STOP THE LEAK WATER SPRAY MAY BE USED TO DILtJI'E SPIlLS TO ~LE MIXTURES UNUSUAL FIRE AND EXPLOSION HAZARDS NONE I<N:>WN I I SECTION 06 - ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE OF SPILL OR LEAK CONTAIN SPILL PREVENT SOURCES OF IGNITION WEAR APPROPRIATE RESPIRATORY , MATERIAL SAFETY DATA SHEET ~Clariant CLARIANl' CORPORATION '4000 r-oNROE ROAD CHARLOTTE N C 28205 hemical Emergency .~ ClEMTREC - Day or Night 1-800-424-9300 DIAHOLD 242580 A-503- VERSION 01 REVISED DATE 07/15/1999 Page 4 For MSDS Info (704) 331-7710 CLARIANT Corporation (704) 331-7000 SECI'ION 06 - ACCIDENTAL RELEASE MEASURES (CONT ) PROTECTION AND PROPER PROTECTIVE EQUIPMENT VENTILATE IF IN ENCIDSED AREA. RECOVER AS LIQUID USIro HAND OR EXPLOSION PROOF PUMP OR USE SUITABLE ABSORBANr TO COLLECT CLE:Att UP BY FLUSHIro WlnI WATER IF APPROPRIATE OR REM:>VAL OF CONTAMINATED SOILS SECI'ION 07 - HANDLING AND STORAGE HANDLING AND STORAGE INFORMP.TION STORE IN A DRY, WELL-VENTILATED AREA AWAY FRCM HEAT, SPARKS, AND FLP.ME DO NOT STORE WInI ACIDS OR STRONG OXIDIZING MATERIALS KEEP CONTAINERS UPRIGHT AND TIGlITLY CLOSED HANDLE IN A MANNER ro PREVENT HU1AN CONTACT SECI'ION 08 - EXPOSURE CONTROLS/PERSONAL PROTECTION RESPlRA'IDRY PROTECTION WHERE EXPOSURE IS LII<ELY TO EXCEED ACCEPTABLE CRITERIA, USE NIOSH/MSHA APPROVED RESPIRATORY EQUIPMENT RESPIRA'IDRS SHOUlD BE SELECTED BASED CN THE FORM AND CONCENTRATION OF CONTAMINANT IN AIR AND IN ACCORDANCE Wlm OSHA (29 CFR 1910 134) PROTECTIVE GLOVES RUBBER EYE PROTECTION CHEMICAL SPIASH GOGGLES ornER. PROTECTIVE EQUIPMENT NJNE ~ VENTILATION GOOD GENERAL VENTILATION SHOtnD BE PROVIDED ro KEEP VAPOR c.'CNCENrRArIONS BELOW THE REC.'Ct+1ENDED EXPOSURE LIMIT EXPOSURE LIMITS NJNE CN PROIXJC'T IDLH (n+tEDIATELY DANGEROUS TO LIFE OR HEALTH CONCENTRATICN) NOT DETERMINED J I SECTION 09 - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE AND ODOR AMBER. TO YELU:lW CLEAR VISCOUS LIQUID ODOR'mRESHOLD NOT AVAIlABLE 'i ( \ IN WATER) 7 9 - 8 9 MATERIAL SAFETY DATA SHEET ~Clariant CLARIANT CORPORATIoN 4000 r-DNROE ROAD ~PLOTTE, N C 28205 .hem.ical Emergency ..L CHEM'l'REC - Day or Night 1-800-424-9300 DIAHOLD 242580 A-503- VERSION 01 REVISED ~TE 07/15/1999 Page 5 For MSDS :Info CLAJUANT Corporation (704) 331-7710 (704) 331-7000 ------------------------------------------------------~--------------------------------------------- SECfION 09 - PHYSICAL AND CHEMICAL PROPERTIES (CONT ) SOLUBILITY IN WATER SOLUBLE SPECIFIC GRAVITY 0 91 BOILING POINr (' F) 176 (80' C) MELTIN3 POINr (' F) ~ AVAILABLE FREEZING POINr (' F) ~ AVAILABLE VAPOR PRESSURE (r+1 HG) 26 VAPOR DENSITY (AIR=1.) 1 6 EVAPORATION RATE 1 6 LOSS ON DRYING ('") ~ AVAILABLE VOC (EPA ~OD 24/24A) ~ AVAILABLE OCfAN)L/WATER PARTITION COEFFICIENT ro DATA AVAILABLE SECfION 10 - STABILITY AND REACTIVITY STABILITY STABLE CONDITIONS TO AVOID HEAT, SPARKS, AND OPEN FLAMES HAZARDOUS POLYMERIZATION WILL ~ OCCUR CONDITIONS TO AVOID ~ KNOWN INCCMPATIBILITY STRONG OXIDIZING .AGENTS SECfION 11 - TOXlCOLOOICAL INFORMATION LD50 (ORAL-RAT) t.JNKt.l)WN M3/KG BODY WEIGHT DERMAL IRRITATION-RABBIT N:>T TESTED EYE IRRITATION-RABBIT ~ TESTED SECfION 12 - ECOLOOlCAL INFORMATION BIOLOOICAL ELIMINATION ~ '" ANALYSIS ~OD ~ AQUATIC TOXICITY SPECIES ~ SPECIES ~ SPECIES ~ LC1.00 ~ LC SO ~ LC 0 ~ foD/L TIME M3/L TIME M3/L TIME H H H I I BACI'ERIAL INHIBITICN ro INHIBITION (foD/L) ~ DETERMINED 50\ INHIBITION (foD/L) oor DETERMINED ~. MATERIAL SAFBTY DATA SHEET ~Clariant CLAR.IAN'l' CORPORATION 4000 MONROE ROAD CHPDT~, N C 28205 hemica1 Emergency J. CHEMTREC - Day or Night 1-800-424-9300 DIAHOLD 242580 A-503- VERSION 01 REVISED DATE 07/15/1999 Page 6 For MSDS Info CLARIANT Corporation (704) 331-7710 (704) 331-7000 SECTION 12 - ECOlOOICAL INFORMATION (CONT ) BIOCHEMICAL OXYGEN DEMAND (BOD5-M3/L) CHEMICAL OXYGEN DEMAND (COD-M3/L) NOT DETERMINED NOT DETERMINED ----------------------------------------------~--~-------------------------------------------------- SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL INFORMATION THIS PROoucr MAY YIELD WASTE SUBJEcr TO THE RCRA LAND DISPOSAL RES1RIcrIONS FOUND AT 40 CFR 268 THESE WASTES MUST BE TREATED ACCORDING TO THE TREA'IMENT STANDARDS AT 40 CFR 268 SUBPART D BEFORE LAND DISPOSAL RCRA HAZARDOUS WASTE YES - IF IT BEc:.u-ms A WASTE AS SOID RCRA # D001 FOLLOW ALL LOCAL, STATE, AND FEDERAL RmJIATIONS SEcrION 14 - TRANSPORT INFDRMATION rxrr REGUlATED YES RQ MET AT NONE /NA NlI1BER UNl866 PACKING GROUP II HAZARD CIASSIFlCATION 3 FLAf+1ABLE AND c:a-mUSTIBLE LIQUID SUBSIDIARY RISK 1 NONE SUBSIDIARY RISK 2 NONE POISON INHAlATION NO HAZARD ZONE NONE MARINE POLLUTANT NO oor LABEL (S) REQUIRED FLAM'WU.E LIQUID NORm AMERICAN EMERGENCY RES~E GUIDE NO 127 SHIPPING NAME RESIN SOwrICN oor REGUlATED BULK ONLY NO CANADIAN TRANSPORT REGUlATICN NOT DETERMINED INrERNATIONAL AIR TRANSPORTATICN RmJIATIONS UN/NA NU-mER UN1866 PACKING GROUP II HAZARD CIASS/DIVISICN 3 FLAf+1ABLE AND c:a-mUSTIBLE LIQUID SUBSIDIARY RISK 1 NONE SUBSIDIARY RISK 2 NONE PASSENGER AIRCRAFI' FORBIDDEN NO I I ~. MA1'ERIAL S A F E T Y D A T ASH.K E T ~Clariant CLARIANT CORPORATJ:oN DIAHOLD A-503- 4000 MONROE ROAD 242580 rnARLOTTE, N C 28205 hemical Emergency ... __ CHEM'l'REC - Day or Night 1-800-424-9300 VERSION 01 REVISED DATE 07/15/1999 Page 7 For MSDS Xnfo (704) 331-7710 CLARIANT Corporation (704) 331-7000 SECTION 14 - TRANSPORT INFORMATION (CONT ) SHIPPING NAME RESIN SOLUrION INI'ERNATICNAL MARITIME ~OUS GCODS REGUlATION oor DETERMINED r. SECTION 15 - REGUlAroRY INFORMATION TSCA ALL CCMPONENTS OF THIS PRODUCr ARE NOT REGISTERED UNDER. 'mE REGUlATIONS OF 'mE roXIC SUBSTANCES CONTROL ACT SARA (SECTION 311/312) REACTIVE HAZARD N PRESSURE HAZARD N FIRE HAZARD Y ~IATE/ActJI'E Y DElAYED/CHRONIC Y SARA(SECTION 302) C'C>m'AINS AN EXTREMELY HAZARDOUS SUBSTANCE N SARA(SECTION 313 - roXIC OiEMICAL) THIS PRODUCT DOES NOT CONTAIN ANY roXIC CHEMICAL LISTED UNDER. SECTION 313 OF 'mE EMERGENCY PI..ANNIro AND ca+1UNITY RIGHT-ro-IQDol ACr OF 1986 CLEAN WATER ACT - PRIORITY POLLUl'ANTS CONTAINS NO KNOWN PRIORITY POLimANTs AT CONCENTRATIONS GREATER 'mAN 0 1\ CLEAN AIR ACT - VOLATILE ORGANIC CCMPOUNDS VOC (EPA METHOD 24/24A) NOT AVAILABLE LOSS ON DRYING (\) NOT AVAILABLE CERClA (FOR cc:MPONENTS LISTED IN SECTICN 2) NO UlWEST RQ NONE RCRA HAZARrX)US WASTE YES - IF IT BECao1ES A WASTE AS SOLD RCRA # D001 FDA THIS PRODUCr IS NOT REGISTERED WITH 'mE FDA USDA THIS PRODUCT IS NOT REGISTERED WITH 'mE USDA I I CEPA LISTED AS PRIORITY SUBSTANCE NOT DETERMINED LISTED AS roXIC SUBSTANCE NOT DETERMINED EXPORT IS NOTIFIABLE NOT DETERMINED LISTED CN DSL NOT DETERMINED LISTED CN NDSL NOT DETERMINED CEPA STAros ~ MATERIAL SAFETY DATA SHEET ~Clariant CLARIANT CORPORATION DIAHOLD A-S03- 4000 r-oNROE ROAD 242S80 VERSION 01 REVISED DATE CHARLOTI'E, N C 2820S bemica1 Emergency '- CHEMrREC - Day or Night 1-800-424-9300 07/1S/1999 Page 8 For MSDS Info (704) 331-7710 CLARIANT Corporation (704) 331-7000 SECTION lS - REGULATORY INFORMATION (CONT ) PRODUCr NOT YET EVALUATED WHMIS NOT EVALUATED SECTION 16 - <miER INFORMATION CYI'HER PRECAtJrIONS WARNIN3 nus PRODtX:T IS TO BE USED AS A COSMETIC INGREDIENT ONLY PNY OTHER USE WILL SUBJECT THE USER TO PENALTIES UNDER THE TOXIC SUBSTANCES CONTROL Acr AND THE REGULATIONS ISSUED niEREUNDER STATE RmJIATORY INFORMATION PENNSYLVANIA AS NOTED PER SECTION 2 MASSAOIUSE'ITS PNY ca-1PONENT OF THIS PRODUCr WHICH IS A HAZARDOUS CHEMICAL AS LISTED IN THE MASSACHUSETl'S SUBSTANCE LIST IS SHOWN ABOVE IN SEcrION 2 OF THIS MSDS NON-HAZARDOUS C<::MPONENTS ARE BEING WInmEID AS TRADE SECRET INFORMATION ~1. INFORMATION _ _..:.1. HAZARDS CAurION ! MAY CAUSE EYE IRRITATION CAurION! MAY CAUSE IRRITATION TO UPPER RESPIRATORY TR.AC:l' WARNIOO ! FUlJwMABLE WARNING ! FOR COSMETIC USE ONLY PNY OTHER USE WILL BE SUBJEcr TO TSCA PMN REGULATION LABEL PRECAtJrIONS ./ AVOID CCNl'ACT WITH EmS WASH nIORou::;HLY AFrER HANDLIm tfEAR PROPER PROTECI'IVE ~PMENT AVOID BREATHIm FUfES AND VAPORS KEEP c:cNI'AINER CLOSED WHEN lDI' IN USE USE WITH ADmuATE VENTIlATION OR APPROPRIATE RESPIRATORY PRC7l'EcTION ~. MA~B:RIAL SAFBTY DATA SHBET ~Clariant CLARIANT CORPORATION 4000 MJNROE ROAD CHARLOTTE N C 28205 ~ bemical Emergency .... CHEMTREC - Day or Night 1-800-424-9300 DIAHOLD 242580 A-S03- VERSION 01 REVISED DATE 07/15/1999 Page 9 For MSDS Info (704) 331-7710 CLARIANT Corporation (704) 331-7000 SECfION 16 - arHER INFORMATION (CONT ) KEEP AWAY FRCM HEAT, SPARKS AND FLAME KEEP CONI'AINER CIDSED USE WITH ADEQUATE VENTILATION 00 NOT USE FOR PURPOSES arHER THAN AS A COSMETIC INGREDIENT IN ACCORDANCE WI'm GOOD PRACfICES OF PERSONAL CLEANLINESS AND HYGIENE, HANDLE WITH DUE CARE AND AVOID UNNECESSARY CONI'Acr WITH THIS PR()[){]C! THIS INFORMATION IS BEING SUPPLIED TO YOU UNDER OSHA "RIGHT TO KN)W" REGULATION 29 CFR 1910 1200 AND IS OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT AS A PRODUCT SPECIFICATION THE INFORMATION CONTAINED HEREIN IS BASED ON DATA AVAILABLE TO US AND IS BELIEVED TO BE TRUE AND ACCURATE NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OF THIS DATA, THE HAZARDS CONNECI'ED WITH THE USE OF THE MATERIAL, OR THE RESULTS TO BE OBTAINED FRCM THE USE THEREOF, IS MADE ClARIANI' CORPORATION ASSlMES NO RESPONSIBILITY FOR DAMAGE OR INJURY FRCM THE USE OF THE PRODUCT DESCRIBED HEREIN ClARIANI' CORPORATION i I ~ . UNION CARBIDE CORPORATION MATERIAL SAFETY DATA SHEET EFFECTIVE DATE 03/08/97 Umon Carbide urges eacb customer or recipient of this MSDS to study it carefully to become aware of and understand the hazards associated with the product. The reader should consider coDSUltina reference works or individuals who are experts ill ventilation, toxicology and fire preveution, as necessary or appropriate to use and understand the data contained ill this MSDS. To promote safe handliDg, eacb customer or recipient should: (1) DOtiIy its employees, agents, contractors and others whom it knows or be6eves will use this material or the informatioD ill this MSDS and any other information regarding hazards or safety; (2) furnish this same information to eacb of its customers for the product; and (3) reqeust its customers to notify their employ- ees, customers, and other users of the product of this information. I IDENTIFICATION PRODUCT NAME: ISOPROPANOL. ANHYDROUS CHEMICAL NAME: Isopropyl Alcohol CHEMICAL FAMILY Alcohols FORMULA. (CH3)2 CHOH MOLECULAR WEIGHT 60 10 SYNONYMS. 2-Propenol; dimethyl carbinol CAS # AND NAME: 67-63-0 2-Propenol II PHYSICAL DATA BOILING POINT 760 mm Hg: 82.3 C (1801 F) SPECifiC GRA VITY(H20 = 1)' 0 787 at 20/20 C FREEZING POINT -89 C (-127 F) V APOR PRESSURE AT 20'C. 33 mmHg Copy""" 1997 UDioa Carbide. EMERGENCY PHONE NUMBERS: 1-8OQ.UCC-HELP (NUMBER A V AlLABLE AT ALL TIMES) OR (304) 744-3487 UNION CARBIDE CORPORATION 39 Old ltidpbury Road, Daobary, CT 06817-0001 ~AGE L PRODUCT NAME ISOPROPANOL, ANHYDROUS VAPOR DENSITY (AIR , ). 2.1 EV APORA TION RATE (Butyl Acetate 1) 2.9 SOLUBILITY IN WATER by wt: 100% @ 20 C APPEARANCE: Transparent colorless ODOR: Slight ethanol/acetone-like PHYSICAL STATE: Liquid PERCENT VOLATilES (by weight). 100 III INGREDIENTS % MATERIAL CAS# EXPOSURE LIMIT -100 Isopropanol 67-63-0 See Section V IV FIRE AND EXPLOSION HAZARD DATA FLASH POINT 53 F 112 C) Tag Closed Cup ASTM 0 56 63 F 117 C) Tag Open Cup ASTM 01310 FLAMMABLE LIMITS IN AIR % by volume: LOWER: UPPER: 2.0 12,7 @ 200 F EXTINGUISHING MEDIA. Apply alcohol-type or a11-purpose-type foam by manufacturer's recommended techniques for large fires. Use carbon dioxide or dry chemical media for small fires. SPECIAL FIRE FIGHTING PROCEDURES. Use water spray to cool fire-exposed containers and structures. Use water spray to disperse vapors; re-ignition is possible. Use self-contained breathing apparatus and protective clothing. UNUSUAL FIRE AND EXPlOSION HAZARDS. Vapors form from this product and may travel or be moved by air currents and PAGE 3 PRODUCT NAME ISOPROPANOL, ANHYDROUS ignited by pilot lights. other flames. smoking. sparks. heaters. electrical equipment. static discharges or other ignition sources at locations distant from product handling point. Vapors from this material may settle in low or confined areas or travel a long distance to an ignition source and flash back explosively This material may produce a floating fire hazard Static ignition hazard can result from handling and use. Electrically bond and ground all containers and equipment before transfer or use of material. Use proper bonding and grounding during product transfer as described in National Fire Protection Association Document NFPA 77 See ~Other Precautions" in Section IX. Flame may be invisible. Approach fire with caution. V HEALTH HAZARD DATA EXPOSURE L1MIT(S)' Isopropanol: 400 ppm TW A. OSHA & ACGIH 500 ppm STEL. OSHA & ACGIH EFFECTS OF ACUTE OVEREXPOSURE: SWALLOWING Slightly toxic. May cause dizziness. faintness. drowsiness. decreased awareness and responsiveness. lack of coordination. abdominal discomfort. nausea. vomiting and diarrhea. SKIN ABSORPTION: Exposure to small quantities is not expected to cause adverse heelth effects. Widespread or prolonged exposure may result in the absorption of harmful amounts of materiel. particularly in infants. leading to signs and symptoms as described for swallowing. INHALATION: Vapor causes irritation of the respiratory tract. with coughing and chest discomfort. High concentrations of vapor may cause central nervous system depression. with weakness, drowsiness. and loss of consciousness. SKIN CONTACT May cause minor irritation with itching and possible slight local redness. Prolonged or repeated contact may cause defatting and drying of the skin. EYE CONTACT Causes irritation. experienced as stinging and discomfort or pain. Cornea' injury may occur EFFECTS OF REPEATED OVEREXPOSURE: Prolonged or repaated skin exposure mey causa defatting of the skin. OTHER HEALTH HAZARDS. None currently known. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: Skin contact may aggravate en existing dermatitis. ADDITIONAL TOXICITY INFORMATION: The following is a summary of TSCA Section 4 Tast Rule results: PAGE 4 PRODUCT NAME. ISOPROPANOL, ANHYDROUS Large doses (> 800 mgJkg/day) of isopropanol givan orally to pregnant rats during the critical period of gestation produced slight decreases in fetal weight. These doses also caused evidence of toxicity in the mothers. Oral doses as high as 480 mgJkg/day caused evidence of toxicity in pregnant rabbits but did not produce evidence of embryo or fetal toxicity Isopropanol did not produce an increased incidence of malformations (teratogenicity) in either species. An indication of reduced mating performance in 2nd generation male rats was noted at oral doses of 1000 mgJkg/day in a two generation reproductive study Increased neonatal mortality was also seen at doses of 500 mgJkg/day and greater in this study No evidence of neurotoxic effects was observed in studies specifically designed to assess neurobehaviorial functions in neonatal rats after oral dosing of mothers during gestation and lactation. In an acute vapor inhalation study high concentrations of isopropanol (1500 ppm and greater) caused a spectrum of transient effects indicative of narcosis. In repeated inhalation exposure studies. high vapor concentrations (5000 ppm) produced an increase in motor activity in rats first noted after 4 weeks of exposure. The effect was reversible completely resolving within 14 days after 13 weeks of exposure. No evidence of damage to nerve tissue was seen in this study lifetime exposure of laboratory animals to high concentrations of isopropanol vapor (greater than 1500 ppm) exacerbated chronic progressive nephropathy commonly seen in aged animals. The relevance of this finding to human health hazard evaluation is unknown. No evidence suggestive of carcinogenic activity was noted in chronic vapor inhalation studies with isopropanol in rats and mice. EMERGENCY AND FIRST AID PROCEDURES. SWALLOWING If patient is fully conscious. give two glasses of water Induce vomiting. This should be done only by medical or experienced first-aid personnel. Obtain medical attention. SKIN' Remove contaminated clothing. Wash skin with soap and water If irritation persists or if contact has been prolonged. obtain medical attention. INHALATION' Remove to fresh air Give ll1tificial respiration if not breathing. If breathing is difficult. oxygen may be given by qualified personnel. Obtain medical attention. EYES. Immediately flush eyes with water and continue washing for several minutes. Remove contact lenses. if worn. Obtain medical attention. NOTES TO PHYSICIAN: There is no specific antidote. Treatment of overexposure should be directed at the control of symptoms and the clinical condition of the patient. VI REACTIVITY DATA STABILITY Stable CONDITIONS TO A VOID' None known. INCOMPATIBILITY (materials to avoid) Strong oxidizing agents. Halogens. Strong inorganic acids. Aldehydes. Halogen compounds. PAGE 5 PRODUCT NAME. ISOPROPANOL, ANHYDROUS HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS. Burning can produce the following products: Carbon monoxide and/or carbon dioxide. Carbon monoxide is highly toxic if inhaled' carbon dioxide in sufficient concentrations can act as an asphyxiant. HAZARDOUS POLYMERIZATION' Will Not Occur CONDITIONS TO A VOID' None known. VII SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED' Extinguish and do not turn on any ignition source until the area is datermined to be free from fire or explosion hazard Wear suitable protective equipment. Avoid contact with eyes. Small spills can be flushed with large amounts of water' larger spills should be collected for disposal. WASTE DISPOSAL METHOD' Incinarate in a furnace where permitted under Federal. State, and local regulations. At very low concentrations in water this product is biodegradable in a biological wastewater treatment plant. VIII SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: Use self-contained breathing apparatus in high vapor concentrations. VENTI LA TION: General (mechanical) room ventilation is expected to be satisfactory where this product is stored and handled in closed equipment. Special. local ventilation is needed at points where vapors can be expected to escape to the workplace air PROTECTIVE GLOVES. Plastic Rubber EYE PROTECTION: Monogoggles OTHER PROTECTIVE EQUIPMENT Eye Bath. Safety Shower IX SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: WARNINGI FLAMMABLE. CAUSES EYE IRRITATION PAGE 6 PRODUCT NAME. lSOPROPANOL ANHYDROUS MAY CAUSE DIZZINESS AND DROWSINESS Keep away from heat. sparks and flame. Avoid contact with eyes. Keep container closed. Use with adequate ventilation. Vapor forms from this product and may travel or be moved by air currents and ignited by pilot lights, other flames, smoking, sparks. heaters, electrical equipment. static discharges or other ignition sources at locations distant from product handling point and may flashback explosively Wash thoroughly after handling. FOR INDUSTRY USE ONLY OTHER PRECAUTIONS. Vapors may settle in low or confined areas, or travel a long distance to an ignition source and flash back explosively ADDITIONAL INFORMATION: There may be edditional product safety information on this product. which may be obtained by calling your Union Carbide Corporation Sales or Customer Service Contact. PROCESS HAZARD: Sudden release of hot organic chemical vapors or mists from process equipment operating at elevated temperature and pressure. or sudden ingress of air into hot equipment under a vacuum, may result in ignitions without the presence of obvious ignition sources. Published -autoignition- or -ignition" temperature values cannot be treated as safe operating temperatures in chemical processes without analysis of the actual process conditions. Any use of this product in elevated-temperature processes should be thoroughly eveluated to establish and maintain safe operating conditions. Further information is available in a technical bulletin entitled -Ignition Hazards of Organic Chemical Vapors.- X REGULATORY INFORMATION STATUS ON SUBSTANCE LISTS. The concentrations shown are maximum or ceiling levels (weight %) to be used for calculations for regulations. Trade Secrets are indicated by -TS- FEDERAL EPA Comprehensive Environmental Response Compensation, and Liability Act of 1980 (CERCLA) requires notification of the National Response Center of ralease of quantities of Hazardous Substances equal to or greater than the reportable quantities (RQs) in 40 CFR 302.4 Components present in this product at a level which could require reporting under the statute are: . .. NONE ... Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires emergency planning based on Threshold Planning Quantities (TPQs) and release reporting based on Reportable Quantities (RQs) in 40 CFR 355 (used for SARA 302, 304 311 and 312) Components present in this product at a level which could require reporting under the statute are: NONE . Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III PAGE 7 PRODUCT NAME ISOPROPANOL, ANHYDROUS requires submission of annual reports of release of toxic chemicals that appear in 40 CFR 372 (for SARA 313) This information must be included in all MSDSs that are copied and distributed for this material Components present in this product at a level which could require reporting under the stetute are UPPER BOUND CHEMICAL CAS NUMBER CONCENTRA TION % This product does not contain toxic chemicals at levels which require reporting under the statute Toxic Substances Control Act (TSCAI STATUS The ingredients of this product are on the TSCA inventory STATE RIGHT TO-KNOW CALIFORNIA Proposition 65 This product contains no listed substances known to the State of California to cause cancer birth defects or other reproductive harm, at levels which would require a warning under the statute. MASSACHUSETTS Right-To-Know Substance List IMSL) Hazardous Substances and Extraordinarily Hazardous Substances on the MSL must be identified when present in products. Components present in this product at a level which could require reporting under the statute are: nAZARDOUS SUBSTANCES I = > 1 %) UPPER BOUND CAS NUMBER CONCENTRATION % 67-63-0 100 CHEMICAL Isopropanol PENNSYLVANIA Right-to-Know Hazardous Substance List Hazardous Substances and Special Hazardous Substances on the List must be identified when present in products. Components present in this product at a level which could require reporting under the statute are. HAZARDOUS SUBSTANCES I = > 1 %) UPPER BOUND CAS NUMBER CONCENTRATION % 67-63-0 100 CHEMICAL Isopropanol CALIFORNIA SCAQMD RULE 443 1 VOC'S. VOC 785 g/l; Vapor Pressure 33 mm Hg @ 20 C OTHER REGULATORY INFORMATION' EPA Hazard Categories: Immediate Health, Delaved Health, and Fire. NOTE The opinions expressed herein are those of qualified experts within Union Carbide. We believe that the information contained herein is current as of the date of this Material Safety Data Sheet. Since the use of this information and the conditions of the use of the product are not under the control of Union Carbide, it is the user's obligation to determine conditions of safe use of the product. REVISED SECTIONS Section IV FIRE AND EXPLOSION HAZARD DATA Section V HEALTH HAZARD DATA Section IX. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE ~, J EMERGENCY PHONE 517-636-4400 MIDLAND MI48674 DOW CHEMICAL U SA REPORT IDENTIFIER 000164 MATERIAL SAFETY DATA SHEET EFFECTIVE.101895 Glycerine, minimum Water TION ON INGREDIENTS CAS# 000056-81-5 96% CAS# 00n32-18-5 4% 3 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Water white liquid. Odorless. No significant hazards for emergency response are known. POTENTIAL HEALTH EFFECTS (See Section 11 for toxicological data.) EYE. May cause slight transient (temporary) eye irritation. Corneal injury is unlikely SKIN Prolonged or repeated exposure not likely to cause significant skin irritation. A single prolonged exposure is not likely to result in the material being absorbed through skin in harmful amounts. May be absorbed in potentially harmful amounts when applied in large quantities to severe burns (second or third degree) over large areas of the body as part of a cream or other topical application. Absorption under such circumstances can elevate serum osmolality and may result in osmotic shock. INGESTION Single dose oral toxicity is low Small amounts swallowed incidental to normal handling operations are not likely to cause injury; swallowing amounts largeer than that may cause injury Signs and symptoms of excessive exposure may be central nervous system effects and increased blood sugar levels. INHALATION At room temperature, vapors are minimal due to physical properties. If heated or sprayed as an aerosol, airborne material may cause upper respiratory irritation. SYSTEMIC (OTHER TARGET ORGAN) EFFECTS Repeated excessive exposure may cause increased fat levels in blood. Observations in animals include kidney, liver and gastrointestinal effects with very large oral doses. CANCER INFORMATION" Did not cause cancer in long-term animal studies TERATOLOGY Birth defects are unlikely Exposures having no adverse effects on the mother should have no effect on the fetus. f ) } REPRODUCTIVE EFFECTS. Reporductive effects seen in female animals are believed to be due to altered nutritional status resulting from extremely high doses in their diets. Similar effects have been seen in animals fed synthetic diets 4 FIRST AID EYES Flush eyes with plenty of water SKIN Wash off in flowing water or shower INGESTION If swallowed, seek medical attention Do not induce vomiting unless directed to do so by medical per~onnel. INHALATION Remove to fresh air if effects occur Consult a physician. NOTE TO PHYSICIAN No specific antidote. Supportive care. Treatment based on judgement of the physician in response to reactions of the patient. 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES FLASH POINT 390F,199C METHOD USED PMCC AUTOIGNITION TEMPERATURE. 698F,370C. FLAMMABILITY LIMITS LFL. Not determined. UFL. Not determined. HAZARDOUS COMBUSTION PRODUCTS During a fire, smoke.may contain the original material in addition to unidentified toxic and/or irritating compounds. Hazardous combustion products may include and are not limited to Aldehydes, carbon monoxide, carbon dioxide. <<'" OTHER FLAMMABILITY INFORMATION: Violent steam generation or eruption may occur upon application of direct water stream. EXTINGUISHING MEDIA. Water fog or fine spray, carbon dioxide, dry chemical, foam. Alcohol resistant foams (ATC type) or protein foams may function, but much less effectively Do not use direct water stream. Will spread fire. MEDIA TO BE AVOIDED' Do not use direct water stream. FIRE FIGHTING INSTRUCTIONS Keep people away Isolate fire area and deny unnecessary entry Burning liquids may be moved by flushing with water to protect personnel and minimize property damage. Burning liquids may be extinguished by dilution with water Do not use direct water stream. May spread fire. PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helemt, coat, pants, boots, and gloves. If protective equipment is not available or not used, fight fire from a protected location or safe distance. tJ ,. ~~ \ r 6. ACCIDENTAL RELEASE MEASURES (See Section 15 for Regulatory I nformatio n) PROTECT PEOPLE. Keep unnecessary people away, isolate hazard area and deny unnecessary entry PROTECT THE ENVIRONMENT Keep out of sewers, storm drains surface water and soil. CLEANUP' Small spills. Cover with absorbent material, soak up and sweep into a drum. Large spills Dike around spill and pump into suitable containers. 7 HANDLING AND STORAGE .". HANDLING. Practice reasonable care and caution. STORAGE. Glycerine freezes at 64F Glycerine should be kept at temperatures above 64F but less than 130F 8. EXPOSURE CONTROLs/PERSONAL PROTECTION ENGINEERING CONTROLS Provide general and/or local exhaust ventilation to control airborne levels below the exposure guidelines PERSONAL PROTECTIVE CLOTHING EYE/FACE PROTECTION Use safety glasses. SKIN PROTECTION No precautions other than clean body-covering clothing should be needed. RESPIRATORY PROTECTION For most conditions no respiratory protection is needed. however, if material is heated or sprayed, use an approved air-purifying respirator EXPOSURE GUIDELINE. Glycerin' ACGIH TL V is 10 mglm3. OHSA PEL is 10 mg/m3 total, 5 mglm3 respirable. PELs are in accord with those recommended by OSHA, as in the 1989 revisions of PELs. 9 PHYSICAL AND CHEMICAL PROPERTIES BOILING POINT IBP 340F 171 C VAP PRESS 3 mmHg @ 20C V AP DENSITY 3.1 SOL. IN WATER Miscible SP GRAVITY 1 .252 @ 25/25C, minimum APPEARANCE Water-white liquid ODOR Odorless. 10 STABILITY AND REACTIVITY CHEMICAL STABILITY Stable. CONDITIONS TO AVOID' Avoid strong oxidizing agents (sodium hypochlorite, hypochlorous acid) INCOMPATIBILITY WITH OTHER MATERIALS Oxidizing material. ~) HAZARDOUS DECOMPOSITION PRODUCTS Acrolein. HAZARDOUS POLYMERIZATION Will not occur 11 TOXICOLOGICAL INFORMATION (See Section 3 for Potential Health Effects. For detailed toxicological data, write or call the address or non-emergency number shown in Section 1) SKIN The LD50 for skin absorption in rabbits is >10,000 mg/kg INGESTION The oral LD50 for rats is 17,00 to 27,200 mg/kg. INHALATION The LC50 for 6 hours in rats was>4 mglliter MUTAGENICITY In vitro mutagenicity studies were negative. 12. ECOLOGICAL INFORMATION (For detailed Ecological data, write or call the address or non-emergency number shown in Section 1) ENVIRONMENTAL FATE MOVEMENT & PARTITIONING. Based largely or completely on information for a similar material, Le. glycerine. Bioconcentration potenetial is Iwo (BCF less than 100 or Log Pow less than 3). Log octanollwater partition coefficient (Log Pow) is -1 76 DEGRADATION & PEERSISTENCE. Based largely or completely on information for a similar material, Le glycerine. Biodegradation under aerobic static laboratroy conditions is high (BOD20 or BOD28/ThOD greater than 4()01o) Biodegradation is expected to be achievable in a secondary wastewater treatment plant. Inhibitory concentration (ICSO) in OECD Activated Sludge Respiration Inhibition Test (OECD Test No 209) is greater than 1000 mg/L. 5-day biochemical oxygen demand (BOD5) is 0.54 pip 10-day biochemical oxygen demand (BOD10) is 0.98 pip. 20-day biochemical demand (BOD20) is 1 0 pip. Theoretical oxygen demand (ThO D) is calculated to be 1 .22 pip ECOTOXICITY Based largely or completely on information for a similar material, Le. glycerine. Material is practically non-toxic to fish on an acute basis (LC50 greater than 100 mglL) Acute LC50 for fathead minnow (Pimephales promelas) is 44000 mglL. Acute LC50 for goldfish (Carassius auratus) is greater than 5000 mg/L. 13 DISPOSAL CONSIDERATIONS (See Section 15 for Regulatory Information) DISPOSAL. DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WA TEA. All disposal methods must be in compliance with all Federal, StatelProvincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator THE DOW CHEMICAL COMPANY HAS NO CONTROL OVER THE MANAGEMENT t .,. PRACTICES OR MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION 2 (Compositionllnformation On Ingredients) FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred optiof.ls in- clude sending to a licensed, permitted recycler, reclaimer, incinerator or other thermal destruction device. As a service to its customers, Dow can provide lists of com- panies which recycle, reprocess or manage chemicals or plas- tics, and companies that manage used drums. Telephone Dow's Customer Information Center at 800-258-2436 or 517-832-1556 14 TRANSPORT INFORMATION U S DEPARTMENT OF TRANSPORTATION (DOl) For DOT regulatory information if required consult transportation regulations, product shipping papers or your Dow representative. CANADIAN TOG INFORMATION For TOG regulatory information, if required, consult transportation regulations, product shipping papers, or your Dow representative. 15. REGULATORY INFORMATION (Not meant to be all-inclusive--selected regulations represented) NOTICE The information herein is presented in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied is given. Regulatory requirements are subject to Change and may differ from one location to another' it is the buyer's responsibility to ensure that its activities comply with federal, state or provincial, and local laws. The following specific information is made for the purpose of complying with numerous federal, state or provincial, and local laws and regulations. See other sections for health and safety information. SARA HAZARD CATEGORY This product has been reviewed according to the EPA 'Hazard Categories" promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories Not to have met any hazard category CANADIAN REGULATIONS --------------------- --------------------- WHMIS INFORMATION The Canadian Workplace Hazardous Materials Information System (WHMIS) Classification for this product is This product is not a "Controlled Product" under WHMIS 16 OTHER INFORMATION x - XDENTXFXCATXON RESOURCE NO 3412 REV 7 OATE 08/93 RHOOAPEX CO-436 TRADE NAME RHOOAPEX CO-436 FORMER TRADE NAME ALl PAL CO-436 SURFACTANT fORMER EXPORT NAME fENOPON CO-436 SURfACTANT CAS REGISTRY NO: 00068649-55-8 CAS REGISTRY MAKE POLY(OXY-1,2-ETHANEDIYL), AlPHA-SULFO-OMEGA-(NONYLPHENOXY)-, BRANCHED, AMMONIUM SALT SYNONYM: AMMONU.14 SALT OF SULfATED NONYLPHENOXY(BRANCHED)ETHYLEMEOXY) ETHANOL MOLECl./lAR fOlJlJLA: C2JH43NOaS MOLECUlAR WEIGHT 493 00 xx - PHYSXCAL , HEALTH BAZARD ZNGREDXENTS CAS REGISTRY NO. 00000064-17-5 CAS REGISTRY IWE ETIWIOl CaKlIC IWE ETHYL ALC01tOL HAZARD % 12.00 - 16.00 HAZARD REFERENCE TLV:~ 1000 PPM PEL ~ 1000 PPM CAS REGISTRY NO. CAS REGISTRY MAKE CaKlIC IW4E HAZARD % : <0 1 HAZARD REFERENCE OOOOCl2J-91-1 1,4-010XANE 1,4-DIOXANE REPORTED AS A YARNING FOR A CALIfORNIA PROPOSITION 65 COMPONENT AT THIS LEVEL CAS REGISTRY NO : M/A CAS REGISTRY NAME NClNTl.PHENOl, (BRANCHED), SUlFATED AND ETHOXYLATED, AII40NIUM SAlT COMMON NAME NONYLPHENOl, (BRANCHED), SUlFATED ~ ETIlOXYLATED, AlM)NIUM SAlT HAZARD % LESS THAN 21 00 HAZARD REFERENCE SARA 313 GLYCOL ETHER CHEMICAL FAMILY AT THIS CONCENTRATION. REPRESEJlTS ALL CCJ4BINED 1,2, & 3 MOl.E ETHOXlLATES xxx - PHYSXCAL , CHElUCAL CBARACTERZSTXCS BOILING POINT VAPOlI. PRESSURE VAPOlI. DENSITY (AIR-l) YATER SOLUlILITY MELTING/FREEZING POINT APPEAlAIICt SPECIfIC GRAV. (YATER-'): PERCENTAGE VOLATILES: EVAPORATION ItA Tt PH Of SOLUTION COOl 85 00 DEG C -25.00 .. HI DUE TO - 40% YATER AND ETHAH<X. CClMPLETE c 0 DEG. C. CLEAJt LlCU ID 1.0650 APPROlC. 15% ETIWlOl; APPROlC 25% YATER >1 00 (BUTYL ACETATE - 1) 6.50 - 7.50 10% SOlUTION ALCOIlOlIC xv - PHYSXCAL HAZARD DATA RESOURCE NO. 3412 REV 7 DATE 08/93 RHOOAPEX CO-436 IV - PHYSICAL HAZARD DATA (CONT.) fLASH POINT AUTOIGNITION TEMP fLAMMABLE LIMITS 80.93 DEG. F , (CC/P") NO DATA fCUND 3.30 % 19.00 X ETHANOL \JATER / DRY CHEMICAL / CARBON DIOXIDE fiRE fiGHTING MEDIA SPECIAL fiRE fiGHTING PROCEDURES: IDlE ICHCMI fiRE/EXPLOSION HAZARDS IIOCE DlCMI IfPA HAZARD CODES . HEALTH/fLAMMABILITY/REACTIVITY HMIS HAZARD CODES - HEALTH/fLAMMABILITY/REACTIVITY 2 2 3 3 o o V REACTIVITY DATA STABILITY KAZARCQJS POt. YMER I ZA T ION: STABLE YILL NOT OCCUR aJlDlTlONS TO AVOID lONE DICMI INCOMPATIBLE MATERIALS: STRONG OXIDIZING OR REDUCING AGENTS. KAZARCQJS DECCMPOS I TI ON PRCOUCT S: lONE KJlCMI VI - HEALTH HAZARD DATA - ACUTE TOXICITY - ORAL TOXICITY RAT LD50 8000 MClICG DERMAL TOX I CITY 110 DATA fCUJll) INHALATlOll TOXICITY 110 DATA fCUJll) SlCIN IRRITATlOll IAIIIT: TESTED AS 15% ACTIVE SOLUTlOIl: PRIMAlY IRIlITATlON INDEX: 2.29: MILD I RIUTAMT . EYE I RR ITA TI 011 RAlIIT: SEVERE IRRITAMT YITHOUT A \JASHOUT, MODERATE IRRITAMT VITH A WASHOUT 3O-SECONDS AfTER INSTILLATION. SENSITIZER NO DOT CORROS I 'IE NO RESOURCE NO 3412 REV 7 DATE 08/93 RHCOAPEX CO-436 VI - HEALTH HAZARD DATA (CONT.) PRIMARY ROUTE(S) OF ENTRY INHALATION 1 CONTACT - SICHS & SYMPTOMS OF EXPOSURE - SYMPTOMS OF INGESTION NO EFFECTS OF EXPOSURE EXPECTED SYMPTOMS OF INHALATION WILL CAUSE IRRITATION OF MUCOUS MEMBRANES, MOSE, EYES AND THROAT COUGHING, DIFFICULTY III BREATHING. SYMPTOMS OF SICIN CONTACT CONTACT MAY CAUSE IRRITATION, REDNESS, SWElLIIIG OR DERMATITIS. SYMPTOMS OF EYE CONTACT: VAPORS SLIGHTLY UNCOMFORTABLE. SPLASHES IRRITATING. "ILL CAUSe PAINFUl BURNING OR STINGING OF EYES AND LIDS, WATERING OF EYES AND IIIFLAMMATlON OF CONJUNCTIVA. - EMERGc:NCY FIRST AID PROCEDURES - FIRST AID FOR INGESTION GENERAL PRECAUTIONARY MEASURES SUGGEST INDUCING VOMITING IMMEDIATELY BY GIVING TWO ClASSES OF WATER AND STlClCING FINGER DOW THROAT. NEVER GIVE AJlYTHING BY MC1JTH TO AJI UNCONSCIOUS PERSON CAll A PHYSJCIAJI. FIRST AID FOR INHALATION Ra.ovE TO FRESH AIR IF HOT BREATHING, GIVE ARTIFICIAL RESPIRATION, PREFERABLY MCUTH-TO'MCUTH IF saEATHING IS DIFFICULT, GIVE OXYGEN CALL A PHYSICIAJI FIRST AID FOR SlCIN CONTACT: FLUSH SKIN WITH WATER FIRST AID FOR EYE CONTACT IMMEDIATELY FLUSH EYES WITH PlENTY OF WATER FOR AT LEAST 15 MINUTES CALL A PHYSICIAJI MEDICAL CONOIT1ONS AGGRAVATED BY EXPOSURE NO DATA FOUND EXPOSURE LlMITS SU SECTION 02 FOR PHYSICAL & HEALTH KAZARO INCREDIEIITS - OTHER TOXICITY - OTHER ACUTE TOXICITY 110 DATA FOUND sua CHRONIC ORAL TOXICITY 90 DAY suaCHRONIC ORAL - RAT AND DOG; 0.5, 1 AJlD 2% Of DIET; DATA SIICNEO NO SICMIFlWT CJWCGES III)1CATlVE OF PIWtMACOTOXIC EFFECTS, ALTHQJCH CROIITH DEPRESSION WAS OBSlRVED III THE RAT AT THE HIGH DOSE LEVEL ANO IN THE DOG AT THE MID AND HIGH DOSE LEVELS. SUB ClIRONIC INHALATION TOXICITY NO DATA FOUND SUB CHRONIC MISCELLANEOUS TOXICITY: NO DATA FOUNO AQUATIC TOXICITY 110 DATA FOUNO T~IGEN1CITY 110 DATA FOUNO HUT AGEN 1 C ITY 110 DATA FQJNO REPRCOUCT1VE TOXICITY NO DATA FOUNO IUSCELLAJlEClJS TOXICITY NO DATA FOUIlO RESOURCE NO 3412 REV 7 DATE 08/93 RHCOAPEX CO-436 VII - OCCUPATIONAL CONTROL PROCEDURES VENTILATION USE ~ITH ADEQUATE VENTILATION RESPIRATORY PROTECTION MIOSH-APPROVED RESPIRATOR, WERE TLV OR PEL MAY BE EXCEEDED EYE PROTECTION CHEMICAL GOCGLES S1C11I PROTECTION IMPERVIWS GLOVES PERSONAL HYGIENE WASH THOROUGHLY AFTER HANDLING PROTECTIVE MEASURES DURING REPAIR/MAINTEHANCE Of EQUIPMENT \lASH EQUIPMENT THORClJCHLY ~lTH STEAM OR \IARM \lATER UNTIL ClEAJI CHECIC FOR FlNI4ABLfS ~ITH All "OPLOSION METER- AMO ALSO CHECIC THE OXYGEII LEVEL ~ITH All OXYGEN METER III ALL CASES, FOLL~ CCOD INDUSTRIAL SAFETY PRACTICES BEFORE EIITER1NG EQUIPMENT VIII - PRECAUTIONS FOR SAFE BANDLING,STORAGE, AND USE PRECAUTIONAIlY MEASURES A\/OIO CONTACT ~ITH EYES AHO SJCII \lASH THORClJCJIU AfTER IWIDLUIG_ A\/OID BREATHIIIG VAPOIt use: ADEQUATE VEIITlLATlON_ KEEP THIS CONTAIIIER Am VAPOItS FROM THIS CONTAINER A\lAY FROM HEAT, SPARKS AHD FLAME KEEP CONTAINER CLOSED SPILL/LEAK ClEAN-UP PROCEDURES: ELIMINATE SOURCES OF IGNITION ABSORB ~ITH EARTH, SAND OR SIMILAR INERT MATERIAL AND DISPOSE OF ~ITH SOlID YASTE ACCORDING TO FEDERAl, STATE AND LOCAL REQJlATlONS_ FLUSH SPILL AREA ~lTH YATER_ DISPOSAL METHCO DISPOSE OF ~ITH LIQUID \lASTE ACCOllOING TO FEDERAL, STATE AJIO LOCAl REQJLATlONS EPA HAZAllDClJS SUSSTAHCE REPORTABLE CXJAHTlTY:NOT LISTED RCIA CLASS lGNITIBLE 0001 IX - TRANSPORTATION DATA - DOMESTIC DATA - DOT SHIPP1HG NAME FlAMMABLE LIQUID, IIOS DOT HAZARD CLASS FlAMMABLE LIQUID IlAZAllDClJS INGltEOIENT(S) ETIWIOl UN NUMBER 1993 . EXPORT DATA . EXPORT SHIPPING MAKE FLAMMABLE LIQUID, NOS EXPORT HAZARD CLASS FUMMAIILE LIQUID HAZAlDClJS 1NGltED1ENT(S) ETIWIOl UN NUMBER 1993 RESOURCE NO 341Z REV 7 DATE 08/93 RHOOAPEX CO-436 PREPARED BY Health, Safety and Environmental Affairs The Informetion herein is given In good faith bolt no warranty is expressed nor I~l ied. Effective Date: 08/10/93 END OF MATERIAL SAFETY DATA SHEET PRELIMINARY ENVIRONMENTAL ASSESSMENT FOR QUANTUM PARK LOTS NUMBER 47, 47B, 47C, 47D +3.60 ACRES BOYNTON BEACH, FLORIDA DECEMBER 2000 For Quantum LImIted Partners, Ltd. 2500 Quantum Lakes Dnve, SUIte 101 Boynton Beach, Flonda 33426 ENVIRONMENT AL SERVICES, INC 1001 North U.S. Highway 1, Suite 304 Jupiter, Florida 33477 561-743-5141 EP00095 TABLE OF CONTENTS I. INTRODUCTION 1 II. METHODS 2 III RESULTS 3 A. Sods 3 B VegetatIOn CommurutIes 3 C LIsted SpecIes 4 D Wetlands 4 IV SUMMARY 4 A. VegetatIOn CommumtIes 4 B LIsted SpeCIes 4 C Wetlands 4 REFERENCES 7 LIST OF FIGURES Figure 1 FIgure 2 Figure 3 SIte LocatIOn Map Site SoIls Map VegetatIOn CommunIty Map .2 5 6 PRELIMINARY ENVIRONMENTAL ASSESSMENT FOR QUANTUM PARK LOTS NUMBER 47, 47B, 47C, 47D +3.60 ACRES BOYNTON BEACH, FLORIDA I. INTRODUCTION On December 19,2000 Environmental ServIces, Inc., (ESI) conducted a prehmmary environmental assessment of approxImately 360 acres on Quantum Park Parcels 47, 47B, 47C and, 47D to determme If any state or federally hsted plant or anImal specIes, JunsdIctiOnal wetlands, or natIve upland vegetatIon, occur on the SIte. The SIte IS located m the CIty of Boynton Beach, Flonda, withm the Quantum Corporate Park and IS bordered by Park R.1dge Boulevard on the north, a fencehne to the west, the South Flonda Water Management DIstnct (SFWMD) C-16 Canal on the south, and an eXIstmg road WIth cul-de-sac to the east. These parcels he wIthm SectiOn 20, TownshIP 45 South, Range 45 East (FIgure 1) The four-parcel SIte has been preViOusly cleared of vegetatiOn. Parcel 47 IS already developed and contams a manufacturmg operatiOn. The maJonty of Parcels 47D, 47C, and 47D IS dommated by early-successiOn grasses and forbes typIcal to dIsturbed areas. The remamder of the SIte IS hmIted to concentrated areas of slash pme (Pinus elliottii), cabbage palm (Sabal palmetto) and scrub oak (Quercus spp) Exotic speCIes noted mclude, Austrahan pme (Casuarina equisetifolia), BrazIhan pepper, (Schinus terebinthifolius), and earleaf acaCIa (Acacia auriculiformis). The area IS httered WIth debns. II. METHODS Palm Beach County aenal photographs (1995), US G S 7.5 Minute Quadrangle Topograpruc Map, Lake Worth Quad, (1945, PhotorevIsed 1986), and the Soil Survey of Palm Beach County Area, Florida, USDA, SCS (1978) were reVIewed pnor to the SIte VISIt for purposes oflocatmg potential wetlands and IdentIfymg typIcal vegetatiOn commumtIes. ESI SCIentists conducted the prehmmary envIronmental assessment by walkmg a senes of transects across the sIte to document the occurrence of any JUrIsdIctiOnal wetlands, natIve upland vegetatiOn, ,or hsted specIes of plants and wIldhfe. Native tree speCIes greater than 3" dbh were quantified and recorded on an aenal field map and m field notes along WIth other plant and anImal observatiOns Soil profiles were exammed to determme the presence ofhydnc soils, and eVIdence of hydrologIc mdIcators were also recorded. Photographs were taken to document eXIstmg condItions. Wetland protectIon IS mandated under both federal and state regulatiOns. The U S Army Corps of Engmeers (CE) regulates actIVItIes m Waters of the Umted States (WOUS) pursuant to the Clean Water Act (PL92-500 SectiOn 404) as further defined m the CE regulatory program (33 CFR 320- 330). The State of Flonda Department of Envlfonmental ProtectiOn (DEP) has estabhshed wetland G.a Ole Ole 0lC &.c 6S-A 6S-B 1AD_ lal1. L_.. 0fC 67-8 UJO .. '''~iil .~A lot'-.c so-c 48-0 t 'SIk- ..,.. &$'K SouIh flonda Waler ManAgement Dislncl C- 16 CatW . Scale' NTS ~ ENVIRONMENTAL SERVICES, INC JupIter, Flonda Quantum Corporate Park Lots 47, 47b, 47c 47d Boynton Beach, Florida Figure Date: Project No. SIte Location Map 1 December 2000 EP00095 N t IdentIficatIon and pemllttmg processes at Chapter 62-330, 62-340, and 62-312 of the Flonda AdmmIstratIve Code (F AC) Current federal and state wetland defimtIons are denved from the ongmal defimtIon found m 33 CFR 328 3, IdentIfymg wetlands as "those areas that are mundated, or saturated by surface or ground water at a frequency and duratIOn sufficIent to support, a prevalence of vegetatIon tYPIcally adapted to hfe m saturated SOlI condItlons" DehneatIOn of federally regulated JunsdIctIOnal wetlands IS determmed by the Corps of Engineers Wetlands Delineation Manual (USAE Waterways Expenment Statlon EnvIronmental Laboratory 1987) DelmeatIOn of wetlands regulated by DEP and South Flonda Water Management DIstnct IS done accordmg to Chapter 62-340 FAC, DehneatIOn of the Landward Extent of Wetlands and Surface Waters. The Florida Wetlands Delineation Manual (GIlbert et al. 1995) serves as a gUide to Chapter 62-340 Both manuals, whIch emphaSIze the IdentIficatIOn of hydnc SOlIs, hydrophytlc vegetatlon, and wetland hydrologIC condItIOnS m malang wetland determmatlons, were used m thIS mvestlgatIOn. LIsted speCIes of plants and wIldlIfe are found m Florida s Endangered Species, Threatened Species and Species of Special Concern, Official Lists (Flonda Game and Fresh Water FISh ConumssIOn 1997) Any occurrences of lIsted speCIes were mapped on an aenal photograph. Land uses were IdentIfied m accordance wIth Florida Land Use, Cover and Forms Classification System Handbook (FLUCFCS) (Flonda Department of TransportatIOn 1999). III. RESULTS A. Soils Basmger fine sand IS mdlcated as the property's mapped SOlI (FIgure 2) ThIS SOlI occurs m broad grassy sloughs m eastern Palm Beach County NatIve vegetatIon tYPIcally supported by thIS soIl may mclude slash pme (Pinus elliottii), cypress (Taxodium spp ), S1. John's wort (Hypericum spp) blue maldencane (Amphicarpum muhlenbergianum), and pmeland three- awn (Aristida rhizomophora) The SOlI actually present on the SIte IS fill matenal, very SImIlar to SOlIs claSSIfied as Arents- urban land complex m Soil Survey of Palm Beach County Area, Florida ThIS complex conSIsts of nearly level, somewhat poorly dramed, sandy SOlIs, and urban land. ThIS sOlI IS formed m thIck layers of sandy fill matenal that has been placed over low, wet, mmeral soIls to make the surface SUItable for urban use ThIS complex IS found throughout the project SIte, and IS common to areas such as golf courses, subdIVISiOns, condommIUm developments, roadways, bus mess or mdustnal areas, reclaimed borrow pIts, and other areas that have been filled but not yet developed. B. Vegetahon Twenty-two (22) cabbage palm, seven (7) umdentlfied commerclallandscapmg trees, and three (3) slash pme were found along a 15 foot-WIde pen meter of the eastern border road and cul-de-sac The western fencehne border of the entIre project area conSists pnmarIlv of BrazilIan pepper, scrub oak and fetterbush (Lyonia lucida) 3 Parcel 47 IS 1 48 acres that has already been developed and IS currently mamtamed by commercIallandscapmg practIces. Parcel47b IS 0 71 acre. ThIrteen (13) slash pme, two (2) cabbage palm and three (3) scrub oak were found on thIS parcel. One scrub oak IS +20 feet m heIght. The center of the area IS slIghtly lower m topography than the surroundmg land. Parcel47c IS:f: I 04 acres and contams ten (10) slash pme and four (4) cabbage palm. Parcel 47d IS :f: 0.38 acre and IS the southern-most parcel adjacent to the SFWMD C-16 Canal Nine (9) slash pme and four (4) cabbage palm were recorded. C. Listed Species No specIes of plants regulated by the Flonda Department of Agnculture and Consumer ServIces were observed on the property No wIldlIfe speCIes lIsted by U S Fish and WildlIfe ServIce or Flonda FIsh and WildlIfe ConservatIon CommISSIon were observed on the property D Wetlands No wetlands occur on the property IV SUMMARY A. Vegetation Communities The dIsturbed nature of thIS property IS mdIcated by the occurrence of fill matenal and exotIC and nUIsance vegetatIOn across the SIte. Local government ordmances may reqUIre preservatIOn or relocatIOn of mdIvIdual natIve trees and plants. AddItIonally, m accordance WIth the Quantum Park Development Order and With local government rules, all exotIC plant speCIes occumng on the property must be eradIcated. All earleaf acaCIa, AustralIan pme, and BrazIlIan pepper WhICh occur on SIte must be removed dunng the development process. B. Listed Species No lIsted speCies were observed on the property c. Wetlands No wetlands occur on the property 4 . ,," ..~. ..' '?'.<< ~' A,f; ~~: i' J ;. '- Ba IcJ ~ ~ ..., QAB Q It" ~ o OJ ~ IcJ II) .1' ... ':'. ........ -- ,"' .,.. Y"\'I' !q~ ;-' r ! P.bB .... -'t ~. t' "", .'. t' ,I.' ,f/ ~ .. ~ ~.. Ba " t), ~f ~' . '!~, :;. ~. (. .;;"'~ . .' . ;~;~ -~: ~. . '~', t ..t ,;': , Scale: I" = 1 000 ~. ENVIRONMENTAL SERVICES, INC JupIter, Florida ~ , ~ ~ . .. r: "- - '~ sue..... . , ~ \ .;. . ",;.t . ,,' .~{.. ~.... '< ...--,- ,.- f,~~ ]4 .~. ~&t. .".J . . , ~ ~S ~~ - Site Soils Map Quantum Corporate Park Lots 47 47b, 47c, 47d Boynton Beach, Florida Figure 2 Date: December 2000 Project No. EP00095 N 1 ~ i -~ i \ . ; PlqUf~. !llpHI~ q~", ~,!,dl! 'i- ,>. ~.<" · .~~'~'':f9' hi'; .( ~J' .., ~...) ""#;~ ,~.,. .,. ~~. .f: __1.- i! It. .....;. l'l ;0"1" ~. '"! }...">Of ~~~i} 1\ ..~; i~' ,~ /~ ~ ( ~.. ~>ii~,~t ~ ;frI,... ~ ),. 'fllfl!tt ,,~1 'f L, ., " ~ ~ 1: > -, . ~ ~ ,:i: \"~~~ ;}Ji~t:~i~~~~)r" 11 .;..ii!t All ""_':F iii- . <" .~ \\~-~ ~~' F1;~~. til. ~ .Ii ~. .~ :r ,~m;"i' ., it ~-t 1 50 \,1, 1.. ~ .. .r '.. . ". :~ .. ~l ":_'" ti;~ :~/eJ;' ,l.>. ~;~~ ".,... ~. .;. _.;~~tijj.. ,- ~ FLUCFCS 193 = Urban Land in transition without positive indicators of intended activity FLUCFCS 150 = Industrial Palm Beach County Aerial Photograph, March 1999 Range 43, Township 45, Section 20 Scale: 1" = 200' ~ ENVIRONMENTAL SERVICES, INC. Jupiter, Flonda Quantum Corporate Park Lots 47, 47b, 47c, 47d Boynton Beach, Florida Vegetation Community Map Figure 3 Date: December 2000 Project No.. EP00095 I REFERENCES Flonda Department of Agnculture and Consumer ServIces, DIVIsIon of Plant Industry October 1998 PreservatIOn of NatIve Flora of Flonda, Chapter 5B-40 Flonda Department of TransportatIOn. 1999 Flonda Land Use, Cover & Forms ClassIficatIOn System Handbook. Tallahassee, Flonda. 91 p Flonda Game and Fresh Water FISh COIrumssIOn. 1997 Flonda's Endangered SpecIes, Threatened SpecIes and SpecIes of Special Concern, OffiCial LIStS. Tallahassee, Flonda. 15p GIlbert K., J Tobe, R. Cantrell, M. Sweeley and J Cooper 1995 The Flonda Wetlands DelmeatIOn Manual. The Flonda Department of EnvIronmental ProtectIOn, South Flonda Water Management DIstnct, St. Johns River Water Management DIStrICt, Suwanee River Water Management DIstnct, and Northwest Flonda Water Management Dlstnct. 197 p U S Army Corps of Engmeers Waterways Expenment StatIOn EnvIronmental Laboratory 1987 Corps ofEngmeers Wetlands DelmeatIon Manual, Technical Report Y-87-1, US Army Engmeer Waterways Expenment StatIOn, Vicksburg, Miss. U S Department of Agnculture, SOlI ConservatIOn ServIce 1978 SoIl Survey of Palm Beach County Area, Flonda. 132 p + maps. 7