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HAZARDOUS MATERIALS CONTAINMENT (2.0) '" '7".# ... MEMORANDUM 23 September 1986 TO: Craig Grabeel, Assistan~ sp the City Manager James Rhoden, Fire Chie~ FROM Carmen S Annunziato, Planning Director RE: QUANTUM PARK Attached to this memo you will find a copy of the proposed final Hazardous Waste Contamination Response Plan which I am forwarding for your information and/or comments. Lr- /bks ~ 16 MEMORANDUM 16 September 1986 TO Perry Cessna, Utilities Director James Golden, Assistant City Planner FROM Carmen S Annunziato, Planning Director RE Quantum Park Attached to this memo you will find a copy of the proposed final Hazardous Waste Contamination Response Plan submitted by Deutsch Ireland Properties in conpection with the Quantum Park of Commerce Please review this plan and forward your comments for incorporation into the final plan where appropriate, as this document must be approved by the City Council {~f ~'/~~/S' (d-?L./7u/ ?~?~J:... CARMEN S ANNUNZIATO ~ /bks cc City Manager r 1. ,~ ;;.:~ ~ FLi-li DEUTSCH IRELAND PROPERTIES REPLY TO "ORT L"'UDERD"',:E_Q!.~ICE September 11, 1986 Mr Carmen Annunziato, City Planner City of Boynton Beach 120 N E 2nd Avenue POBox 310 Boynton Beach, Florida 33435 Re: Approval of the Hazardous Waste Plan Contamination Response Dear Carmen In accordance with Condition 17 of the Development Order, Quantum Associates hereby submits to you their Hazardous Waste Plan for your final review and approval Please call me if there are any questions you have during your review process or if additional copies are needed in order for you to complete your review Thank you for your consideration on this matter Very truly yours, QUANTUM ASSOCIATES --!::k{l~.e tV "Zf.~#~-,m.q~ GEORGE W ZIMMERMAN ( a..~ VICE PRESIDENT OF DEVELOPMENT GWZ aem CC David S Pressly, Esq SUITE 1106-INTERNATIONAL BUILDING-2455 E, SUNRISE BOULEVARD-FORT LAUDERDALE, FLORIDA 33304. (305) 564-5114 THE BUILDING. 1125 NORTHEAST 125 STREET NORTH MIAMI, FLORIDA 33161 . (305) 891-6806 AFFILIATES: D/I REALTY & MANAGEMENT CORP MITA CONSTRUCTION CORP J. LAW ENVIRONMENTAL SERVICES DIVISION OF LAW ENGINEERING TE~TING CvMPAr-.,y 2749 DELK ROAD S E MARIETTA, GEORGIA 30067 (404) 952-9005 February 18, 1986 Mr. Thommas P. Misuraca Deutsch-Ireland Properties Suite 1106, International Building 2455 E. Sunrise Boulevard Fort Lauderdale, Florida 33304 Dear Mr. Misuraca Please find enclosed Revised Copy of Guidelines for the Preparation of Tenant Hazardous Materials Response Plans. If you have any questions, please do not hesitate to call_ Very truly yours, LlWl ENVIRONMENTAL SERVICES ~ov .. Neil D. Willi~.E. G,T7eCh:aJ)ie~ C l. -(__ i '.j/ -t" L,_ '- _1..&> -k'" J,~es L. Studer, P.E. v~enior Geotechnical Engineer Regi stered Fl od da 26878 NIli JLS/l sm Enclosure , GUIDELINES FOR THE PREPARATION OF TENANT HAZ ARDOOS MATERIALS RESPONSE PLANS BOYNTON BEAL'H PARK OF COMMERCE Prepar ed by L>>l ENVIRONfolENTAL SERVICES Marietta, Georgia Prepared for DEUTSCH-IRELAND PROPERTIES Ft. Lauderdale, Florida Ver si on 2.0 February 13, 1986 GUIDELINES FOR THE PREPARATION OF TENANT HAZ ARDOUS MATERIALS RESPONSE PLANS BOYNTON BEACH PARK OF COMMERCE 1. INTRODUCTION The Boynton Beach Park of Commerce is a 539.9 acre develop- ment between Ft. Lauderdale and West Palm Beach, Florida. The park is situated north and south of 22nd Avenue in Boynton Beach, Florida adjacent to Interstate 95 (see Figure 1). The park is bounded on the ea st by 1-95 and the Seaboar d Coastl ine Rail road, on the south by Canal C-16, on the west by Canal E-4 and on the north by farmland and other undev eloped property. It is antici- pated that the primary uses of the development will be 30.4 acres commercial, 133.1 acres office, 197.6 acres light industrial, and the remainder to include a Sea Pine Reserve, City Park, and state ri ghts- of-way. For the purposes of this aocument, the owners shall be considered the manager of the Park of Commerce. Tenants shall include all those personnel or companies which purchase or lease land or commercial space at the Park. Prior to occupancy, each tenant that uses, handles, stores or displays hazardous materials or generates hazardous waste as defined in 40 CFR Part 261 (7-1-85), shall meet the requirements of condition 16 of Ordinance No. 84-51 of the .Ordinance of the City of Boynton Beach, Florida, approving a comprehensive development of regional impact (DRI) for a proposed industrial office park comprising of approximately 539 acres located in the city of Boynton Beach, Florida pursuant to chapter 380, Florida Statues 1984, subject to special conditions, designating the city 1 manager of Boynton Beach as the local official responsible for assuring compliance with the development order.- The regulated substances described in 40 CFR Part 261 shall also include all waste materials which exceed the limits for ignitability, corrosivity, reactivity or EP toxicity as outlined in 40 CFR Part 261.20, 21, 22, 23 and 24. In addition, the fOllowing materials and uses shall be prohibited: 1. Dioxin and Dioxin containing materials 2. Materials or substances containing PCB's 3. Semi conductor manufacturing facilities 4. Wafer/chip manufacturing facilities 5. Underground Storage Tanks 6. Surface Impoundments 7. Landfilling or Burial of Waste Materials. This document provides guidance for the preparation of Tenant Hazardous Materials Response Plans as required by state Ordinance No. 84-51. The application for a hazardous waste facility permit must be completed by all persons who own or operate, or who intend to construct or close a hazardous treat- ment, storage or disposal facility as identified in Section 17- 30, Florida administrative code (PAC), unless exanpted in accor- dance with Section 17-30.27, FAC. No regulated material shall be used, stored, handled or manufactured for any purpose within 60 days of the date that the Tenant Hazardous Materials Response Plan and the necessary permits have been filed with and approved by the appropriate regulatory agencies. This document does not relieve the tenants of the normal 2 reporting, manifesting and regulatory procedures required by Federal, state or local agencies in the handling, storag~, inven- tory and reporting procedures for hazardous waste,s. Application for a hazardous waste facility permit, per form 17-1.207(3), must be completed in accordance wi th the requirements of section 17-30 of the FAC. This document provides an overview to assist tenants in identifying potential problem areas that might be encountered in early planning stages and provides the methodology for reporting of hazardous material leaks or spills, assessment pro- grams and demonstration of financial responsibility. This document does not a ttempt to address all the details outlined in the Federal Register for hazardous waste storage, treatment and disposal facili ties. This document briefly reviews the following items as required by Ordinance 84-51. Guidelines for the storage of chemicals and hazardous ma terial s. Guidelines and requirements for reporting of accidental releases of hazardous materials. Emergency response team co-ordination with the local hazardous material control unit. Specifications, guidelines and requirements for emer- gency ground-water monitoring in the event of an acci- dental release of hazardous waste. Guidelines for the design of surface water management and spill containment structures and facilities. Guidelines for the demonstration of financial responsi- bility. 3 2. GUIDELINES FOR THE STORAGE OF CHEMICALS AND HAZARDOUS MATER IAL S The guidelines for the storage of chemicals or hazardous materials identified in this section are in addition to the requirements specified in the Florida Administrative Code, the Code of Federal Regulations, and appropriate National Fire Associations Standards. It is the responsibility of the Tenant to design and construct chemical storage facilities which meet or exceed the requirements specifiE:d by applicable agencies or groups. No regulated chemicals or hazardous substances shall be stored, used or manufactured at the Tenant's facility within 60 days of the date that authorization has been granted by the appropriate regulatory agencies. The chemical or hazardous material areas shall be isolated from pedestrian or vehicular traffic. Signs shall be posted to identify all chemicals or hazardous materials stored at the f ac il i ty. In addition, "Danger-Keep Out" and "Unauthorized Persons - Keep Out" signs shall be conspicuously posted. The chemical or hazardous material storage areas shall be totally contained using berms or curbs. The volume of the head space contained within the berms or curbs shall be equal to 150\ of the maximum storage capacity of the tanks and drums plus 6 inches of free board. The floor system shall be sloped to drain to a dedicated sump for each storage area. The floor and sump shall be lined with low conductivity materials such as High Density Polyethylene sheet, in a similar manner to that shown in Figure 2. The storage area shall be covered and the storage area 4 and sump isolated from runoff. Potentially rea ct iv e chem ical s shall be stor ed in separ ate storage ar ease Cherni cal storage practices shall follow the prin- ciples of segregation, isolation and protection specified by the National Fire Protection Association. In no case shall strong OXidizing chemicals be stored with potentially combustible mat- erials or flammable liquids. In storage areas containing more than one type of chemical, each chemical or waste material shall be identified on a clearly visible area of the storage tank. The area shall be marked to identify the most severe health, flam- mability or reactivity hazard present. The storage tanks or containment facilities shall be specifically designed and certified for the chemicals or hazardous materials which they contai n. Any hazardous material or chemical spilled or used to clear the chemical containment system shall be collected and drummed from the sump and disposed or recycled. The design of the con- tairunent system is the responsibility of the tenant. The sche- matic shown in Figure 2 represents one possible alternative. 3. GUIDELINES AND R~UIREMENTS FOR REPORTING OF ACCIDENTAL RELEASES OF HAZARDOUS MATERIALS. After each tenant has met the requirements of the state and Federal regulations and the city ordinance 84-51 regarding stor- age and handling of hazardous waste, the tenant shall contact the fire department to make arrangem~nts for a preplan emergency response meeting (the phone number of the Boynton Beach fire department is 734-8111 Ext. 451). Prior to the preplan meeting, the tenant shall have com- 5 ~ pleted material data safety sheets on all chemicals which may be stored on site as required by OSHA. Copi es of th e mater~ al data I J I k 7~ j)~ JJ e"py 70 'The.. n',4;l.t:I/'l ~ saf ety sheets shall be provi ded to the Fi re Mar shall. Addi tionalli1dU~/4J... IAIl copies shall remain in the plant for the employees to read (see the attached cop.i of a material data safety sheets by the U.s. Department of Labor OSHA) in Appendix A. The tenant shall contact the fire department and arrange for a si te visi t to: 1. Review the material safety data sheets 2. Quantify total chemicals and storage area facilities 3. Assess sprinkler systems and fire fighting equi};ll\ent 4. Evaluate site logistics and general operating procedures, 5. Meet with the assigned emergency coordinators 6. Designate the Plant Emergency Coordinator, and 7. Discuss emergency evacuation procedures The purpose of this meeting is to provide the Fire Department available information necessary to respond promptly in an erner gency. 4. EMERGENCY RESPONSE TEAM COORDINATION WITH THE LOCAL HAZ ARDOUS MATERIAL CONTROL UN ITS. In the event of a sudden release of hazardous materials the following procedures shall be followed: Call the Boynton Beach Fi re Department at 911 Give the Plant's name and location State whether the emergency is Fir st Aid 6 ., Fire Hazardous Waste Release Call one of the Plant Emergency Coordinators to be on- site to assist the Fire Department. (If not at the plant si te) Call the Division of Emergency Management at (904)-488- 1320 and report the accident using a Reporting Form for Emergency Events found in Appendix A or equal. Call the National Response Center number at 1-800-424- 8802 and report the accident using a Reporting Form for Emergency Events found in Appendix A or equal. Assist in the removal of all non-essential personnel from the area. Coordinate remedial activities with the ,#1.4 riv2 ~.4Ls Boynton Beach Fire Department Hazardous W4lste Response Team. Contact the ground-water monitoring team to install wells (if necessary) and to assess the impact of the release on local surface-water and ground-water quali ty. 5. GUIDELINES FOR EMERGENCY GROUND-WATER MONITORING IN THE EVWT OF AN ACCIDWTAL RELEASES OF HAZARDOUS MATERIALS. The tenant shall comply with all federal, state and local regulatory requirements governing ground-water monitoring fol- lowing the sudden release of hazardous materials. In the event of an accidental r~lease of hazardous materials in the storage area, the hazardous materials collected in the chemical spill sump will be removed and recycled or disposed.b~ Jy The "lC?N4Nf 7 ---_._--~'"._---~~~_..........~--- .... Following removal of the hazardous material from the sump, the chemical spill sump and containment area shall he cleaned to remove hazardous materials to acceptable levels for safe oper- ation. No additional ground-water monitoring will be required. In the event of an accidental release of hazardous materials to the surface water sump which drains the runway, parking areas and loading dock, the required level of remedial action will depend upon the desi gn opti on. If a doubl e 1 iner and 1 eak detec- tion layer are installed under the runway then the spill area and sump shall be pumped dry and cleaned to acceptable levels. The Clean-up levels shall be approved by the appropriate federal, state and local regulatory agencies. No ground-water monitoring will be required if a double liner system is used and the spill is contained within the area draining to the surface water sump. If a double liner system is not installed, then within seven (7) days of the spill, a minimum of 4 ground-water monitoring wells, screened from the water table to a depth at least 10 feet below the water table, shall be installed (see Figure 3) at or near the perimeter of the containment area. Figure 3 shows a typical well construction detail. One monitoring well shall be installed up-gradient of the spill and three (3) wells down- gradi ent of the spill. The well s shall be moni tored monthly for a period of 12 months for the specific hazardous constituents which were spilled and which were used in the clean-up effort. If, after 12 months, the constituents are not detected in the ground-water sam pI es obtai ned f rom the moni tor i ng well s, sampl ing will be terminated. At that time, the monitoring wells may be closed by filling the riser pipe with a cement bentonite grout 8 ~ mixture to the top. In the event that a spill occurs in an area which does not drain to a surface water sump, or if an overflow condition causes hazardous materials to overflow the contairunent area, immediate action may be required to intercept potentially contaminated surface water and prevent it from entering the surface water retention basins. One surface water sample shall be obtained for every 200 lineal feet of contaminated ditch or runoff area. One additional monitoring well (total of 5) shall be installed immediately down gradient of the affected area. Clean-up of the affected area shall be to the levels prescrlbed and approved by the federal, state and local regulatory agencies. 6. GUIDELINES FOR THE DESIGN OF SURFACE WATER MANAGEMENT AND SPILL CONTAINMENT STRUCTURES AND FACIL ITIES. The tenant shall comply wi th all rules and regulations from the federal, state and local agencies governing the design of surface water management and spill contairunent structures. All drawings and plans must be submitted and approved by the appro- priate agencies prior to construction. Surface water discharge containment and hazardous chemical containment shall be addressed in the design of the facili ties. The surface water runoff from the runway, parking areas, and loading dock at the plant site shall be contained, collected and treated using an oil water separator system to remove any floating substances such as oil or gasoline. The collection system may be gravity controlled or collected and pumped. In the event a pump system is used, the water or fluid level in the sump 9 shall be maintained at a pumped down level so that the sumps always have adequate capacity to completely contain and store liquids from sp.lls and clean-up efforts. The rules and regulations for construction of ,surface water containment system and hazardous waste containment systems shall be researched and combined with the needs of each specific plant's requirements. The components of the containment system shall resist chemical degradation due to exposure to the chemi- cals used at the tenant's facility. Figures 4 and 5 are two general examples of a plant's typical layout showing surface containment control and hazardous waste control. Figure 4 shows a surface water control system which collects the runoff from the runway, parking area and loading dock in a small colI ecti on sump which is then pumped into a central collection sump and transfer system. Because of plant layout there may be more than one collection sump feeding a central collection sump. Surface water runoff is then fed into an oil/water separator system. The treated water is discharged to the surface water management system. Any oil collected is drummed and sent ei ther to a hazardous landfill or recycl ed in the plant. Figure 5 shows a simpler arrangement using an oil water separator for both the collection and treatment of surface water runoff. The surface water runoff is directed by gravity flow into the below grade oil/water separator. The treated water is discharged by gravity into the surface water management system. The oil is skimmed from the top and collected in drums for di spa sal . 10 The system suggested in Figure 5 has a lower capital Equip- ment cost but may require additional planning and site grading. Figure 6 shows a surface water control area with a secondary containment system and a collection sump which pumps t9 the central collection sump. The transfer pump is controlled by a level control probe immersed in the pit alongside the submersible pump. The level indicator activates a switch which turns on the pump. As the level of the l~quid falls, the float switch con- tinues to fall with the liquid level until the lower set of switches is activated shutting off the pump. Secondary contain- ment may not be required in the surface water controlled area but is offered as an alternative. Figure 7 shows the surface runoff control area using the separator for both containment and treatment. This system is gravity fed and discharged. The system may require the use of a pump if proper grades cannot be achieved. The primary device used to treat surface water runoff from the runway, parking areas and loading dock is the oil/water separator. Figures 8 and 9 illustrates two different types of oil/water separators. Figure 8 shows a McTighe standard oil/ water separator with a mechani cal oil removal sy stern. Figure 9 shows a McTighe separator with petro-pak and a mechanical oil removal system. There are many variations of these units depending on the specific treatment objectives, vol- ume flow rate, regulations and site logistics. The oil/water separator should be designed for constant operation and low maintenance. As oily influent flows into the 11 separator, oil and sludge are removed and clean effluent is discharged to the surface water management system. The oil/water separator is comprised of a stationary tank, full of water, having an inlet at one end directing the incoming oily infl uent over a specially desi gned heavy corrugated plate, set at a 33 degree angle. Initially the flow is reversed and the influent passes over the corrugated plate. The corrugations in- duces agitation causing the oils or lighter density substances to break away. As the oil rises, it is joined by the other droplets of oil and due to thei r buoyancy ri se rapidly to the surface. The rate at which the soils and other floating industrial waste raise to the surface depends on the oil droplet size. The larger the droplet, the faster the rate of rise and separation. Sludge or heavy solids within the stream settle to the bottom of the separator, collecting at the center sludge baffle plate. The second phase of separation begins as the influent is directed between an incli ned ar rangement of cor rugated par all el plates, stacked upwardly, sloping at a 45 degree angle, and spaced 4 inches apart to prevent fouling by debris or gummy solids. It is here where buoyancy forces cause smaller oil droplets to rise and coalesce into sheets of oil on the underside of each of the corrugated plates, creep up to the surface, and finally break loose at the top in the form of large globules. Clean water flows in a downward path to the outlet where clarified water is permitted to escape fran the lower regions as the separated oil is withdrawn from the surface. The oil is collected and drummed for recycling or disposal. The sludge is collected and disposed at a licensed solid waste disposal 12 facility. It is the responsibility of the tenant to design or provide documentation for approval of the surface water control and hazardous waste containment systems. The containment areas and oil/water separators shall only be provided in the parking areas, truck runways, loading ramps and docks and chemical storage areas, where regulated chemicals or hazardous materials likely to be transported. 7. GUIDELINES FOR THE DEMONSTRATION OF FINANCIAL RESPONSIBILITY Each tenant that handl es, stores, uses or generates regu- lated chemicals or hazardous materials shall demonstrate financial responsibility as outlined in 40 CFR part 264.140-150. No regulated chemicals or hazardous materials shall be handled, stored, used or generated within 60 days of approval of the financial demonstration by the appropriate regulatory agencies. It is the responsibility of each tenant to prepare the financial demonstration and secure the approval of the appro- priate regulatory agencies. In addition to the requirements of 40 CFR, each tenant that handles, stores, uses or generates regulated chemicals or hazardous materials shall contribute $20,000 to the Emergency Action (EA) response fund. The fund shall be administered by the admini strative off icer of the Trea- sure Coast Regional Planning Council. In the event of a release of a regulated substance to the environment requiring payment form the EP response fund, the tenant responsible for the release will, in addition to any or all other costs for remedial action, reimburse the EA response fund for the exact dollar amount 13 ~- , expended f rom the fund. In accordance with 40 CFR Section 264.142 the tenant shall prepare a cost estimate for closure and post closure care of the facility. The estimate must be prepared in current dollars for the point in time during the operation of the facility when closure or remediation would be most expensive, as stated in the closure plan (see 40 CFR Part 264.112(a)). The tenant shall adjust the closure and post-closure cost estimates each year within 30 days of the anniversary of the approval of the financial demonstration. The adjustment in the cost estimates shall reflect inflation and changes in the opera- tion of the facility which make closure or post closure more less costly. The tenant shall establ ish financial assurance for closure and post-closure care of the facility using one or more of the following options 1. Trust Fund 2. Surety Bond Guaranteeing Payment into the Closure and Post-Closure Trust Funds. 3. Surety Bond Guaranteeing Performance of Closure and Post-Closure. 4. Closure and Post-Closure Letter of Credi t. 5. Closure and Post-Closure Insurance. 6. Financial Test and Corporate Guarantee for Closure and Post-Closur e. The closure and post-closure plans and cost estimates shall be prepared and certified by a registered professional engineer 14 .. and shall be approved by the EPA Regional Administrator after regulatory agencies. The basic requirements for the financial assurance options are stated in 40 CFR Parts 264.143 and 145. In addition, each tenant that handles, stores, uses or generates regulated substances shall wdemonstrate financial responsibility for bodily injury and property damage to third parties caused by sudden accidental occurrences arising fromw the operation of the facility (40 CFR part 264.147). The tenant shall mai ntai n liabil i ty cov era ge for sudden acci dental occur- rences of at least $1,000,000 per occurrence with an annual aggregate of $2,000,000, excluding legal defense costs. The liability demonstration requirements are stated in 40 CFR Part 264.147. 15 <t APPENDIX A ------- . \ ~ 0::' ------------- (") ______----co ".on (") 'Z ~ :;o~o o g, Gl';ac lJ') ~}1> z ~ U1' (J) '0 ';i 'Z C }1> - n ~1,'jj~2 \l~~ "i,'Z~; ;;\ S1 ) o~'" \~~~~~ ,,)-' \1\ \ \ \ ,,'- ~L \ \ \ " " \\\l" " " " \\l"'- '" (:- """"'........."""'" 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".. ~ NATIONAL FIRE PROTECTION ASSOCIATION t NTER NATIONAL 'Moving Mankind Toward Safety From Fire November 1, 1985 Dear Fire Chief, The National Fire Protection Association is pleased to enclose materials and information concerning the current federal requirements for small quantity generators of hazardous waste. Regulated small quantity generators are those businesses and industries that generate certain hazardous wastes in quantities between 100 and 1000 kilograms per month (or 220 to 2200 pounds per month) The U S Environmental Protection Agency and NFP A are asking for the help of your fire department in making local small businesses and industry aware of the EPA requirements. As you and members of your department contact business owners and operators on inspection and public education matters, please go over the manifest requirement with them. Knowing the types and quantities of hazardous waste in local businesses will also help you complete pre-fire plans, in case of an emergency incident. Your state may have additional or more stringent requirements for small quantity generators. Be sure to check with the State Fire Marshal's office or the state environmental control office, listed in the enclosed brochure. The September issue of NFP A's Fire Command@ magazine outlined several points concerning these requirements and their impact on the nation's fire services. Please review the enclosures carefully Small businesses in your community may be requesting additional assistance from you in complying with the requirements. More importantly, these requirements may even affect your fire department, requiring you to comply with the federal and/,or state legislation. Enclosed you will find a basic color brochure explaining the EP A manifest requirements for small quantity generators. Accompanying the brochure are a number of inserts, One insert is the "Uniform Hazardous Waste Manifest" that generators must complete when shipping the hazardous waste to a disposal site The other inserts deal with 14 key industries that EP A has identified as the most likely generators of hazardous waste in the regulated quantities. Each enclosed industry insert is provided in a reduced black and white version (81/z" x 11") for you to copy for distribution to small businesses and industries in your area. EXECUTIVE OFFICE: BATTERYMARCH PARK, QUINCY MASSACHUSETTS, U, S, A, 02269 . TELEPHONE (617) 770.3000. TELEX 200250 The nan-profit technical and educational organization: To promote the science and improve the methods of fire protection and prevention: to obtain and circulate Information on these SUbjects and to secure the co-operation of its members and the public in establishing proper safeguards against loss of life and property by fire. ~ Four (4) additional industry-inserts are currently under development, but were not completed in time to be included in this package These additional inserts are PAPER INDUSTRY, which covers - pulp and paper mills - operations that manufacture finished paper products such as boxes, tablets, etc FORMULATORS, which covers chemical formulators of - printing inks - pesticides and agricultural products - pharmaceutical preparations - other chemicals and chemical products. CLEANING AGENTS AND COSMETICS MANUFACTURING, which covers formulating or manufacturing of - soaps, detergents, or specialty cleaners - polishing or sanitizing compounds - surfactants, finishing agents or sulfonated oils and other assistants - perfumes - cosmetics - toilet preparations/sundries. LEATHER PRODUCTS MANUFACTURING, which covers - leather tanning and finishing - manufacturing of shoe and boot cut stocks and findings, non-rubber footwear, leather gloves and mittens, luggage, handbags and other leather goods. Copies of these inserts can be requested by calling the EPA RCRA Hotline, 800-424-9346, the EPA Small Business Hotline, 800-368-5888, or any EPA Regional Office. Following your contact, the local business owner or operator should be able to 1 Understand that hazardous waste requires special management 2. Identify those wastes he produces that are hazardous 3 Calculate the quantity of hazardous waste he generates in a month 4 Determine if this quantity makes him subject to regulation 5 Know where to go or who to contact to get. a. copies of the manifest he must complete b help in completing the manifest c information on transporters and facilities d an identification number - if required by the state 6 Anticipate further changes in hazardous waste laws to become effective as early as March 31, 1986 " In an effort to provide as much information to the fire service as possible, NFP A will be broad casting a television training program, entitled "Hazardous Waste - Small Quantities, Big Challenge," via satellite on November 21, 1985 The program will explain the structure of the federal hazardous waste and substances legislation and those specific reqUIrements for small quantity generators. The program will be broadcast twice on November 21. The satellites being used are Westar 5, Transponder 7X (Channel 14, audio 6.2/6.8 MHz) at 1 00 p.m - 2 00 p.m. Eastern Time and Satcom 4, Transponder 8 (audio 6.2/6.8 MHz) at 11 30 a.m. -12 30 p.m. Eastern Time Both broadcasts will be identical. To receive the program via satellite, contact any local owner or operator of satellite reception equipment and provide them with the above information, and ask them for help in receiving the broadcast. The regional offices of the Environmental Protection Agency (EP A) and the Federal Emergency Management Agency (FEMA), many local Chambers of Commerce, and USDA Cooperative Extension Service Offices have been notified about the broadcast. They also might be able to help your department get the program. Using the modern technology of satellite communications, NFP A and EP A hope to help you - the fire service professional- handle the challenge of hazardous waste in your community Sincerely, / ~(fzJ I These materials were prepared for the United States Environmental Protection Agency Office of Solid Waste Management under Grant no T901538-01 FOR ADDITIONAL INFORMATION \ Publications. Transportation of Hazardous Materials Code of Federal Regulations (49 CFR 171-177) U S Government Printing Office Washington DC Conducting Fire Inspections. A Guidebook for Field Use (SPP-75) NFPA. Quincy MA 1982 NFPA Inspection Manual, 5th Edition (SPP-llC) NFPA. Quincy MA 1982 Fire Protection Guide on Hazardous Materials, 8th Edition (SPP-lE) NFP A Quincy MA. Audio-Visual Programs Hazardous Waste and the Fire Service (Slide/tape program SL-110) NFPA. Quincy MA. Introduction to Fire Inspection (Slide/tape program SL-80) NFP A Quincy MA. \0 EPA/NFPA Awareness Program The Small Quantity Generator of Hazardous Waste These pages are provided for the fire department to make copies available to local owners/operators of businesses that may be required to comply with certain provisions of the Resource Conservation and Recovery Act Permission is granted to reproduce these inserts in their entirety for use in notifying and inform ing such businesses of applicable federal and/or state requirements. TABLE OF CONTENTS Titles Uniform Hazardous Waste Manifest Vehicle Maintenance Dry Cleaning and Laundry Plants Textile Manufacturing Wood Preserving Equipment Repair Furniture/Wood Manufacturing and Refinishing Pesticide End-Users/Application Services Chemical Manufacturers Construction Motor Freight Terminals/Railroad Transportation Printing and Allied Industries Laboratories Educational and Vocational Shops Metal Manufacturing Page Numbers A1A2 B1-B2 C1 D1 E1 F1-F2 G1-G2 H1-H8 11 14 J1-J2 K1-K3 L1-L3 M1-M3 N1-N4 01-03 These materials were prepared for the United States Environmental Protection Agency Office of Solid Waste Management under Grant no T901538-01 Please print or type, (Form designed for use on eljte (12-pitch) typewriter,) 1 Generator's US EPA 10 No, Form Approved. OMS No. 2000.0404. Expires 7.31.861 2, Page 1 Information in the shaded areas is not required by Federal of law A. State Manifest Document Number B. State Generator's 10 'f.~~-:f;h ,c -~~~;~, 6, US EPA 10 Number C, State Tra'1s~onllr'S)Df;~tii:if.~"R1'J~~~;~/, ,.~:1 0, Transporter's' Phone,;:"";;:i!JI:~{;~,;;t~\:\.,:~:,~;,,,, E, State Transporter's 10 ,F Ttllnsporter's' Phon" G, Sta~1'~i:;;i; US DOT Description (Including Proper Shipping Name, Hazard Class. and ID Number) No, Type 13, Total Quantity 11 G a, E N E R b, A T 0 R C, d, Handling Instructions and Additional Information EN RATOR'S CERTIFICATION: I hereby declare that the contents of this consignment are fully and accurately described above by proper shipping name and are classified, packed, marked, and labeled, and are in all respects in proper condition for transport by highway according to applicable international and national government regulations, Unless I am a small quantity generator who has been exempted by statute or regulation from the duty to make a waste minimization certification under Section 3002(b) of RCRA, I also certify that I have a program in place to reduce the volume and toxicity of waste generated to the degree I have determined to be economically practicable and I hav'! selected the method of treatment, storage, or disposal currently available to me which minimizes the present and future threat to human health and the environment. Printed/Typed Name Signature Month Day Year Signature T 17 Transporter 1 Acknowledgement of Receipt of Materials : Printed/Typed Name N S p o 18,Transporter 2 Acknowledgement of Receipt of Materials R T Printed/Typed Name E R Signature 19,Oiscrepancy Indication Space F A C I L I T Y 20,Facility Owner or Operator' Certification of receipt of hazardous materials covered by this manifest except as noted in Item 19, Printed/Typed Name Signature Month Day Year EPA Form 8700.22 (Rev 4.B5) Previous edition is obsolete, Al INSTRUCTIONS " lIem 3. Generator's Name and Mailing Address Enter the name and address of your business, Item 9. Designated Facility Name and Site Address Enter the company name and site address of the facility to which you are shipping the waste listed on this Manifest. The address must be the site address, which may be different from the company mailing address. Item 11. US. DOT Description [Including Proper Shipping Name, Hazard Class, and 10 Number (UN/NA)] Enter the US. DOT Proper Shipping Name, Hazard Class, and 10 Number (UN/NA) for each waste as identified in 49 CFR 171 through 171 Your hauler or the facility to which you are shipping the waste may be able to help you determine this information, You may also be able to obtain information and assistance from the US, Department of Transportation Materials Transport Bureau, your state transportation agency, your state hazardous waste management agency, or your trade association. Item 12. Containers (No. and Type) Enter the number of containers for each waste and the appropriate abbreviation for the type of container DM Metal drums, barrels, kegs DW Wooden drums, barrels, kegs DF Fiberboard or plastic drums, barrels, kegs TP Tanks portable TT Cargo tanks (tank trucks) TC Tank cars IJf Dump truck CY Cylinders CM Metal boxes, cartons, cases (including roll-offs) CW Wooden boxes, cartons, cases CF Fiber or plastic boxes, cartons, cases BA Burlap, cloth, paper or plastic bags Item 13. Total Quantity Enter the total quantity of waste described on each line, Youi measurement must include the weight of the container when the waste container is to be discarded (example: a drum containing waste), Do not use fractions or decimals. lIem 1,.. Unit (Wt.lVol.) Enter the appropriate abbreviation for the unit of measure for each quantity entered under Item 13, as follows: G Gallons P Pounds T Tons (2000 pounds) Y Cubic yards L Liters K Kilograms M Metric tons (1000 kilograms) N Cubic meters Item 16. Generator's Certification You must sign and date the Uniform Hazardous Waste Manifest after you have filled it out. A2 Vehicle Maintenance I IF YOU REPAIR OR MAINTAIN or if you ~ remove oil or grease ~ remove rust, dirt or paint ~ repair or rebuild ~ refinish or restore ~paint ~ replace lead-acid batteries the products you use on the vehicles, and on your equipment, tools. hands. or floor may contain hazardous materials, and the wastes generated by using these products may be hazardous wastes. ~ cars ~ vans ~ trucks ~ heavy equipment ~ farm equipment PRODUCTS CONTAINING HAZARDOUS MATERIALS Everyday mechanics, bodymen and others use products containing hazardous materials, Products like: ~ Rust removers, which contain strong acid or alkaline solutions ~ Carburetor cleaners, which contain flammable or combustible liquids ~ Used rags containing combustible or flammable solvents ~ Paints with flammable or combustible thinners or reducers ~ Auto and truck batteries contain chemicals or materials which are hazardous to human health and the environment. Table 1 lists typical operations/ processes which use products that may contain hazardous materials and which probably generate hazardous wastes. If you generate 220 pounds (about half of a 55-gallon drum) or more of hazardous waste per month, you must fill out a Uniform Hazardous Waste Manifest when you ship this waste off your property. UNIFORM HAZARDOUS WASTE MANIFEST Item II of the Uniform Hazardous Waste Manifest requires the proper Department of Transportation (DOT) shipping description, which includes: Table I TYPICAL OPERATIONS USING MATERIALS WHICH MAY GENERATE HAZARDOUS WASTES TYPICAL MATERIAL INGREDIENTS ON LABEL TYPICAL PROCESS/ OPERATION TYPICAL MATERIALS USED GENERAL TYPES OF WASTES GENERATED Oil and grease removal degreasers-(gunk), carburetor cleaners, engine cleaners. varsol, solvents, acids/alkalies Engine, parts and equipment cleaning degreasers-(gunk), carburetor cleaners, engine cleaners, solvents, acids/alkalies, cleaning fluids Rust removal naval jelly, strong acids. strong alkalies Paint preparation paint thinners. enamel reducers, white spirits Painting enamels. lacquers, epoxys, alkyds, acrylics, pri mers Spray booth, spray guns, and brush cleaning paint thinners. enamel reducers. solvents. white spirits Paint removal solvents, paint thinners, enamel reducers, white spirits Used lead acid batteries car, truck, boat, motorcycle, and other vehicle batteries petroleum distillates, aromatic hydrocarbons. mineral spirits petroleum distillates, aromatic hydrocarbons, mineral spirits. benzene, toluene. petroleum naphtha phosphoric acid, hydrochloric acid, hydrofluoric acid, sodium hydrox ide alcohols, petroleum distillates, oxygenated solvents, mineral spirits, ketones acetone, toluene, petroleum distillates, epoxy ester resins, methylene chloride, xylene, VM&P naphtha, aromatic hydrocarbons, methyl isobutyl, ketones ketones, alcohols, toluene. acetone. isopropyl alcohol, petroleum distillates. mineral spirits acetone, toluene, petroleum distillates. methanol, methylene chloride. isopropyl alcohol, mineral spirits, alcohols, ketones, other oxygenated solvents lead dross, less than 3% free acids ignitable wastes, spent solvents, combustible solids, waste acidl alkaline solutions ignitable wastes, spent solvents, combustible solids, waste acidl alkaline solutions waste acids, waste alkalies spent solvents, ignitable wastes, ignitable paint wastes, paint wastes with heavy metals ignitable paint wastes, spent solvents, paint wastes with heavy metals, ign it able wastes ignitable paint wastes, heavy metal paint wastes. spent solvents ign itable paint wastes, heavy metal paint wastes, spent solvents used lead acid batteries, strong acidl alkaline solutions Bl ~ the proper DOT shipping name for each waste, To help you complete this item, Table 2 provides this information for some of the hazardous wastes you are most likely to generate, To obtain the DOT shipping name, hazard class and UN/NA identification number' Select the typical process/operation from column I of Table I Match the ingredients from column 3 and the waste type generated from column 4 of Table I with the waste type and ingredient in column I of Table 2, Not all vehicle maintenance operations generate hazardous wastes, If you don't see a particular chemical that you use, or if you generate a waste not listed, or if you need any type of help, call your state hazardous waste management agency, NOTE: Under current federal law, you do not have to use a Manifest when you ship: ~ used/dead lead acid batteries that are destined for recycling ~ used motor oil. Be aware, however, that the regulations for used oil may change, You should still use environmentally sound methods for the collection, storage and recycling of used motor oil. Remember-your state may have its own requirements for lead acid batteries or used oil. Be sure to check with your state hazardous waste management agency, Table 2 WASTE DESCRIPTIONS' DESIGNATIONS/ DOT WASTE TYPE TRADE NAMES SHIPPING NAME STRONG ACID/ALKALINE WASTES Ammonium Hydroxide " Hydrobromic Acid Hydrochloric Acid Hydronuoric Acid Nitric Acid Phosphoric Acid Potassium Hydroxide Sodium Hydroxide Sulfuric Acid Chromic Acid IGNITABLE WASTES Ignitable Wastes NOS' Aromatic Hydrocarbons Petroleum Distillates IGNITABLE PAINT WASTES Ethylene Dichloride Benzene Toluene Ethyl benzene Chlorobenzene Methyl Ethyl Ketone SPENT SOLVENTS White Spirits, Varsol I,I,I-Trichloroethane Petroleum distillates Ammonium Hydroxide. NH40H. Spirit of Hartshorn. Aqua Ammonia Hydrobromic Acid, HBr Hydrochloric Acid. HCI. Muriatic Acid Hydronuoric Acid. HF, Fluorohydric Acid Nitric Acid. HN02, Aquafortis Phosphoric Acid. H3P04. Orthophosphoric acid Potassium Hydroxide. KOH. Potassium Hydrate. Caustic Potash. Potassa Sodium Hydroxide, NaOH. Caustic Soda. Soda 4e. Sodium Hydrate Sulfuric Acid. H2SO4, Oil of Vitriol Chromic Acid Carburetor Cleaners. Ignitable Wastes NOS Ethylene Dichloride. 1.2-Dichloroethane Benzene Toluene Ethyl benzene Chlorobenzene, Monochlorobenzene. Phenylchloride Methyl Ethyl Ketone, MEK, Methyl Acetone, Meetco, Butanone. Ethyl Methyl Ketone White Spirits. Mineral Spirits. Naphtha Aeothane TT. Chlorlen. Chloroethene, Methyl- Chloroform. Alpha, T. Chlorotene Petroleum Distillates PAINT WASTES WITH HEAVY METALS Heavy Metals Paint Paints with heavy metals Lead Nickel Chromium Waste Ammonium Hydroxide (containing not less than 12% but not more than 44% ammonia) (containing less than 12% ammonia) Waste Hydrobromic Acid (not more than 49% strength) Waste Hydrochloric Acid Waste Hydronuoric Acid Waste Nitric Acid (over 40%) (40% or less) Waste Phosphoric Acid Waste Potassium Hydroxide Solution Dry Sol id. Flake, Bead. or Granular Waste Sodium Hydroxide Solution Dry Solid, Flake. Bead, or Granular Waste Sulfuric Acid Waste Chromic Acid Solution Waste Flammable Liquid NOS Waste Combustible Liquid NOS Waste Flammable Solid NOS Waste Ethylene Dichloride Waste Benzene (benzol) Waste Toluene (toluol) Waste Ethyl benzene Waste Chlorobenzene Waste Methyl Ethyl Ketone Waste Naphtha Waste I,I.I-Trichloroethane Petroleum Distillate Hazardous Waste, Liquid or Solid, NOS B2 HAZARD CLASS Corrosive Material ORM-A Corrosive Material Corrosive Material Corrosive Material Oxidizer Corrosive Malerial Corrosive Material Corrosive Material Corrosi ve Material Corrosive Material Corrosive Material Corrosi ve Malerial Corrosive Material Flammable Liquid' Combustible Liquid' Flammable Solid Flammable Liquid Flammable Liquid Flammable Liquid Flammable Liquid Flammable Liquid Flammable Liquid Flammable Liquid Combustible Liquid ORM-A Flammable Liquid Combustible Liquid ORM-E UN/NA ID NUMBER NA2672 NA2672 UNI788 NA1789 UNI790 UN2031 NAI760 UNl805 UNI814 UNI8\3 UNI824 UNI823 UNI830 UNI755 UNI993 NAI993 UN\325 UNI184 UNIJJ4 UNI294 UNI175 UNII34 UNJJ93 UN2553 UN2553 UN2831 UNI268 UNI268 NA9189 '" c .g :; c o u o ~ :~ " !J ~ '" .s: u L1.; 8 N '" C '" L1.; L1.; ~ ~ ~ ~ :~ ~ ~ ~ ~ 11 c :;;; c ,~ I! ~ ] ~ ~ ~ Ou '= ~ ~ ~ ; ~ e ~ .c ~ ~ .~ ~ i :~ ~ g 0 ~ ~ ~ ~ " Z E " "'IE.o ~ '" E ] ~;?: c 8 t", 1- < ~ '" ~ ,= Drycleaning and Laundry Plants INDUSTRY OVERVIEW The establishments covered under Drycleaning and Laundry Plants include: ~ Retail drycleaning stores ~ Industrial and linen supply plants with dryclcaning operations ~ Leather and fur cleaning plants ~ Self-service laundromats with drycleaning equipment ~ Other establishments with drycleaning operations, While not all of these facilities will produce hazardous waste, those facilities using hazardous solvents may be subject to new Resource Conservation and Recovery Act (RCRA) provisions regarding the treatment, storage, disposal, and transportation of small quantities of hazardous waste, These solvents include: ~ Perchloroethylene, otherwise known as perc, PCE, or tetrachloroethylene ~ Valclene$ also known as fluorocarbon 113 or tri ch lorotri fI uoroetha ne ~ Petroleum solvents, such as Stoddard, quick-dry, low-odor and other solvents with a flash point less than 1400E (" 140-F solvent" and other solvents with a flash point equal to or greater than 1400F are not considered hazardous under EPA RCRA designation, If you are unsure of the flash point, check with the distributor of the solvent.) Table I TYPICAL QUANTITIES OF HAZARDOUS WASTE FROM DRYCLEANING (Pounds of waste per 1.000 pounds of clothes cleaned) CLEANING METHOD PETROLEUM WASTE TYPE PERC VALCLENE SOLVENTS Average Quantity of Hazardous Waste (pounds) Sri II Residues 25 10 Spent Cartridge Fi Iters: Standard (carbon core) 20 I ~ Adsorptive (split) 30 20 Cooked Powder Residue 40 NA Drained Filter Muck NA NA 20 NA 'Well-drained filter cartridges or drained filter muck are solids and do not meet the criteria for c1assificarion as an ignitable solid: therefore. they are not hazardous wastes. Table 2 WASTE DESCRIPTIONS' Information for Item 11 of the Manifest HAZARD UN/NA WASTE DOT SHIPPING NAME CLASS ID NUMBER Perc Waste Perchloroethylene or ORM-A UN 1897 Waste Tetrachloroethylene Valclene ORM-E UN 9189 Hazardous Waste. NOS Petroleum Solvents Waste Petroleum Distillate Combustible Liquid" UN 1268 Waste Petroleum Naphtha Combustible UN 1255 Liquid" 'In certain situations, other DOT descriptions may be applicable to the wastes listed, "If the flash point of the solvent or residue as disposed of is less than IOOoF the hazard class would be 'flammable liquid, Although the flash poin! of petroleum drycleaning solvents is above loooF the presence of contaminants (such as printing inks) could lower the overall flash point to below loooF , ..... HAZARDOUS WASTES FROM DRYCLEANING OPERATIONS Perchloroethylene plants potentially produce three types of hazardous wastes: ~ Still residues from solvent distillation (the entire weight) ~ Spent filter cartridges (total weight of the cartridge and remaining solvent after draining) ~ Cooked powder residue (the total weight of drained powder residues from diatomaceous or other powder filter systems after heating to remove excess solvent). Valclene plants potentially produce two types of hazardous wastes: , , d , , I , ..... ~ Still residues from solvent distillation (the entire weight) ~ Spent filter cartridges (total weight of the cartridge and remaining solvent after draining), Petroleum solvent plants potentially produce only one type of hazardous waste: ~ Still residues from solvent distillation (the entire weight), However, if 140-F solvent is used, the still residue will not normally be a hazardous waste, Well-drained filter cartridges or drained filter muck (powder residues from diatomaceous filter systems) are solids and do not meet the criteria for classification as an ignitable solid; therefore, they are not hazardous wastes, WASTE QUANTlnES AND DESCRIPTIONS If your plant produces 220 pounds or more of hazardous waste per month, you are subject to certain requirements, including the use of a Uniform Hazardous Waste Manifest when shipping hazardous waste off your premises. To determine whether your plant qualifies as a regulated small quantity generator and to complete the Manifest, you will have to weigh the hazardous waste your plant generates, Table I lists common types and average quantities of hazardous waste produced per 1,000 pounds of clothes cleaned, Item lIon the Mani fest is the Department of Transportation (DOT) descriptIon of the waste, which includes the proper shipping name, hazard class, and UN/NA identification number, This information is provided in Table 2 to aid in preparing the Manifest; other DOT descriptions and identification codes, however, may be applicable in some circumstances, WASTE DISPOSAL METHODS Generally there are three methods for proper disposal of hazardous wastes that are currently considered acceptable by both EPA and most state hazardous waste management agencies: ~ Disposal in an authorized hazardous waste landfill ~ Disposal at an authorized high-temperature incineration facility ~ Disposal through an authorized recycler of hazardous wastes, From an environmental perspective, recycling or incineration is generally preferable to land disposal. BAN ON LAND DISPOSAL OF PERC AND VALCLENE WASTES Under the new RCRA, EPA is required to issue, by November 8, 1986, new regulations that will ban the disposal on or into the land of hazardous waste containing certain solvents, including perchloroethylene and Valclene, In the near future, therefore, hazardous waste disposal options will be further restricted, Cl Textile Manufacturing \ INDUSTRY OVERVIEW The following Textile Manufacturing industry segments are covered by this summary' ~ Broad woven fabric mills. wool mills (including dyeing and finishing) ~ Knitting mills ~ Dyeing and finishing textiles, except wool fabrics and knit goods ~ Floor covering mills. While not all of these textile industnes will produce hazardous waste, those facilities using hazardous solvents may be subject to new Resource Conservation and Recovery Act (RCRA) provisions for treatment, storage, disposal, and transport of small quantities of hazardous waste, Some of the solvents used in textile manufacturing which are of concern include: ~ Perchloroethylene or tetrachloroethylene, also known as perc, Perclene, Tetralex, Nema, Tetracap. Persec. Antisal I Perawin, Didakene, and other names, ~ TrichloroethYlene, also known as TCE, Gemalgene, Lanadin, Lethurin, Nialk, Perm-a-Chlor, Triklone, Triad, Benzinol, Blacosolv, Cecolene, Trielin, Triline, Triol, Vestrol, Chlorylene, Dow-Tri, and Vitran, ~ Methylene Chloride or dichloromethane, also known as NCI- C50J02, Solaesthin, Aerothene MM, Narkotil, and Solmethine. ~ 1, 1, 1-Trlchloroethane, also known as Aerothane TT, Chlorten, Inhibisol, Chlorothen NU, NCI-C04626, Chlorothene, Methylchloroform, .Alpha, T, and Chlorotene, ~ Toluene or toluol, also known as methacide, methylbenzene, methylbenzol, phenyl methane, and Antisal lA, ~ Benzene or benzol. ~ Xylene or xylol. ~ Ethylene Dichloride. ~ varsol or Mineral Spirits, White Spirits, and Naphtha. These solvents are typically used in the dry-cleaning of 100 percent synthetic fiber knit fabrics, and woven and wool fabrics; in specialty operations such as tricot and lace splitting or solvent scouring; in dyeing operations; and in some finishing operations for impregnation or coating of textile fibers. In addition, solvents are used to clean machinery such as rollers and spinning machines used in textile manufacturing. If you generate more than 220 pounds (about half of a 55-gallon drum) of hazardous waste solvents or solvent still bottoms per month, you will be subject to certain requirements, including the use of a Uniform Hazardous Waste Manifest for shipment of your hazardous waste off your premises. Item lion the Manifest requires the proper Department of Transportation (DOT) shipping description, which includes the DOT shipping name, hazard class, and UN/NA identification number for each waste, This information for the various waste solvents and solvent still bottoms is provided in Table I to assist you in completing the required sections of the Manifest. Please note that these DOT designations could differ under various conditions. This is not a comprehensive list. If you suspect that you generate a waste which is not included in this summary, contact your state hazardous waste management agency or EPA Regional Office for assistance. Table 1 WASTE DESCRIPTIONS1 WASTE SOLVENT I SOLVENT STILL DOT HAZARD UN/NA ID BOTTOMS SHIPPING NAME CLASS NUMBER Perc Waste Tetrachloroethylene ORM.A UNIH97 or Perchloroethylene TeE Waste Trichloroethylene OR~l-A CNI710 Methylene chloride Waste Dichloromethane or ORM-A UNI593 Methylene chloride I, I, I-Trichloroethane Waste I.I.I-tnchloroelhane ORM,A UN2831 Chlorobenzene Waste Chlorobenzene Flammable UNI134 Liquid Toluene Waste Toluene or Toluol Flammable UNI294 Liquid Benzene \\ aste Benzene or Benzol Flammable UNlII5 Liquid Xylene Waste Xylene (xylol) Flammable UNI307 Liquid Ethylene dichloride W"le Ethylene Dichloride Flammable UNII84 Liquid Flammable UNI256 Liquid' Combustible UNI256 Liquid' I These descriptions may change given variations in waste characteristics or conditions, V.rsol White Spirits Mineral Spirits Waste Naphtha 2 A nammable liquid has a nash pointless than 1000E 3 A combustible liquid has a nash point between 1000 and 2000F Dl Wood Preserving , INDUSmy OVERVIEW A typical wood preserving operation uses any of the following wood conditioning processes: steaming. boultonizing. kiln or air drymg (either under pressure or vacuum) with one or more of the three principal wood preserving agents: ~ Creosote ~ Pentachlorophenol (PCP) ~ Inorganic arsenical compounds (CCA-Chromated Copper Arsenate or ACA-Ammoniacal Copper Arsenate). The wastewater treatment sludge that is generated from wood preserving processes that use creosote and/or pentachlorophenol is listed by EPA as a hazardous waste, The waste from using Inorganic Arsenicals is frequently a hazardous waste if it contains either chromium or arsenic in a concentration greater than or equal to 5,0 mg/I HAZARDOUS WASTES FROM WOOD PRESERVING OPERATIONS If you generate 220 pounds (about half of a 55-gallon drum) or more of hazardous waste per month, you must fill out a Uniform Hazardous Waste Manifest when you ship these wastes off your property. Item lion the Manifest requires the Department of Transportation (DOT) description of the waste. which includes the proper shipping name, hazard class and (UN/NA) identification number, This information is presented in Table 1 If you use a process or preserving agent which is not listed in Table I consult your state hazardous waste management agency to determine if your waste is hazardous. and if so, the proper DOT information needed for the Manifest. Table 1 WASTE DESCRIPTIONS1 DOT WOOD PRESERVING HAZARD UN/NA AGENTS DOT SHIPPING NAME CLASS ID NUMBER Creosote Hazardous Waste. Liqu id or Sol id. ORM-E NA9189 NOS' Pentachlorophenol Waste Pentachlorophenol. Liquid or OR!\.l-E NA2020 Solid Chromated Copper Wasle Arsenical Compounds. Solids Poison B UNI557 Arsenate Waste Arsenical Compounds. Liquids Poison.B UNl556 Ammoniacal Copper Waste Arsenical Compounds, Solids Poison B UNl557 Arsenate Waste Arsenical Compounds. Liquids Poison B UNI556 Other wood Hazardous Waste Liquid or Solid, ORM-E NA9189 preserving wastes NOS 'These descriptions may change given variations in waste characteristics and conditions, 'NOS-Nol otherwise specified, El Equipment Repair INDUSTRY OVERVIEW Your business is included in the Equipment Repair category if you operate a: ~ Radio and/or television repair shop ~ Refrigeration and air conditioning service or repair shop ~ Miscellaneous equipment repair shop (e.g, electrical household appliances or industrial equipment) or if you repair equipment used for' ~ Pipelines (except natural gas) ~ Communications ~ Power generation/transmission ~ Automatic merchandising machines ~ Amusement parks, Not all equipment repair operations produce hazardous wastes. However, if you use any strong acid/alkaline solutions, flammable/combustible liquids, combustible solids, or paints containing either flammable or combustible solvents, heavy metals or both, it is possible that the wastes generated from using these materials may be hazardous, If so, then you may be subject to new Resource Conservation and Recovery Act (RCRA) provisions regarding the transportation of small quantities of hazardous waste. PRODUCtS CONTAINING HAZARDOUS MATERIALS Everyday mechanics, repairmen and others use products containing hazardous materials, Products like: ~ Rust removers, whICh contain strong acid or alkaline solutions ~ Degreasers, which contain flammable or combustible liquids ~ Used rags containing combustible or flammable solvents ~ Paints with flammable or combustible thinners or reducers contain chemicals or materials which are hazardous to human health and the environment. Table 1 lists typical operations/ processes that use products which may contain hazardous materials and which probably generate hazardous wastes. If you generate 220 pounds (about half of a 55-gallon drum) or more of hazardous waste per month, you must fill out a Uniform Hazardous Waste Manifest when you ship hazardous waste off your property. UNIFORM HAZARDOUS WASTE MANIFEST Item II of the Uniform Hazardous Waste Manifest requires the proper Department of Transportation (DOT) shipping description, which includes: ~ the proper DOT shipping name ~ the hazard class ~ the UN/NA Identification Number for each waste. To help you complete this item, Table 2 provides descriptive information for some of the hazardous wastes you are most likely to generate, To obtain the DOT shipping name, hazard class and UN/NA identification number' Select the typical process/operation from column 1 of Table 1 Match the ingredients from column 3 and the waste type generated from column 4 of Table 1 with the waste type and ingredient in column I of Table 2, If you do not see a particular chemical that you use, if you generate a waste not listed, or if you need any type of help, call your state hazardous waste management agency. NOTE: Currently, you may not have to use a Manifest for used motor oil, but you should be aware that regulations may change in this area, You should still use environmentally sound methods for the collection, storage and recycling of used motor oil. Table I TYPICAL OPERATIONS USING MATERIALS WHICH MAY GENERATE HAZARDOUS WASTES TYPICAL MATERIAL INGREDIENTS ON LABEL TYPICAL PROCESSI OPERATION Oil and grease removal TYPICAL MATERIALS USED degreasers-(gunk). carburetor cleaners. engine cleaners. varsol. solvents. acids/alkalies Engine, parts and equipment cleaning degreasers-(gunk). carburetor cleaners, engine cleaners. solvents, acid~/akalics. cleaning. fluids Rust removal naval jelly. strong acids. strong alkalies Paint preparation paint thinners. enamel reducers, white spirits Painting enamels, lacquers, epoxy'. alkyds, acrylics. pri mefS Spray booth, spray guns and brush cleaning paint thinners, enamel reducers. solvents. white spirits Paint removal solvents. paint thinners, enamel reducers, white spirits petroleum distillates. aromatic hydrocarbons, mineral spirits petroleum distillates. aromatic hydrocarbons, mineral spirits. benzene. lolucnc. petroleum naphtha phosphoric acid. hydrochloric acid, hydrofluoric acid. sodium hydroxide alcohols, petroleum distillates, oxygenated solvents, mineral spirits, ketones acetone, toluene. petroleum distillates, epoxy ester resi ns. methylene chloride. xylene, YM&P naphtha, aromatic hydrocarbons, methyl isobutylketoncs ketones. alcohols, toluene. acetone, isopropyl alcohol. petroleum distillates. mineral spirits acetone. toluene. petroleum distillates, methanol, methylene chloride. isopropyl alcohol, mineral spirits, alcohol, ketones, other oxygenated-solvents GENERAL TYPES OF WASTES GENERATED ignitable wastes, spent solvents, combustible sol ids. waste acidl alkaline solutions ignitable wastes, spent solvents, combustible solids. waste acidl alkaline solutions waste acids, waste alkalies spent solvents. ignitable wastes, ignitable paint wastes, paint wastes with heavy metals ignitable paint wastes, spent solvents. paint wastes with heavy metals. ignitable wastes ignitable paint wastes, heavy metal paint wastes, spent solvents ignitable paint wastes, heavy metal paint wastes, spent solvents Fl Table 2 WASTE DESCRIPTIONS1 DESIGNATIONS/TRADE WASTE TYPE NAMES DOT SHIPPING NAME STRONO ACID/ALKALINE WASTES Ammonium Hydroxide Hydrobromic Acid Hydrochloric Acid Hydrofluoric Acid Nitric Acid Phosphoric Acid Potassium Hydroxide Sodium Hydroxide Sulruric Acid Chromic Acid IGNITABLE WASTES Ignitable Wastes NOS' Aromatic Hydrocarbons Petroleum Distillates IGNITABLE PAINT WASTES Ethylene Dichloride Benzene Toluene Ethyl Benzene Chlorobenzene Methyl Ethyl Ketone SPENT SOLVENTS White Spirits, Varsol I, I, I-Trichloroethane Petroleum distillates LEAD-ACID BATTERIES Lead-Acid Batteries Ammonium Hydroxide. NH40H, Spiril of Hartshorn. Aqua Ammonia Hydrohromic Acid. HBr Hydrochloric Acid, HCI. Muriatic Acid Hydrofluoric Acid, HF, Fluorohydric Acid Nitric Acid. HN02. Aquafortis Phosphoric Acid, H31'04, Orthophosphoric acid Potassium Hydroxide. KOH. Potassium Hydrate, Causlic Potash, Potassa Sodium Hydroxide. NaOH, Causlic Soda. So..la Lye. Sodium lIydrale Sulfuric Acid. H2S04, Oil of Vitriol Chromic Acid CarburelOr Cleaners, Ignitable Wastes NOS Ethylene Dichloride. 1.2-Dichloroethane Benzene Toluene Elhyl benzene Chlorobenzene, Monochlorobenzene, Phenylch loride Methyl Ethyl Ketone, MEK. Methyl Acetone, Meelco. Butanone, Elhyl Melhyl Ketone White Spirits, Mineral Spirits, Naphlha Aeothane TT, Chlorlen. Chloroethene. Methyl Chloroform, Alpha, T, Chlorolene Petroleum Distillates Lead-Acid Balleries PAINT WASTES WITH HEAVY METALS Heavy metal paints with: Lead Nickel Chromium Heavy Melal Paints Waste Ammonium Hydroxide (containing not less Ihan 12% but not more than 44ck ammonia) (comaining less than 12% ammonia) Wasle Hydrohromic Acid Waste Hydrochloric Acid Waste Hydrofluoric Acid Waste Nilric Acid (over 40%) (40% or less) Waste Phosphoric Acid Waste Potassium Hydroxide Solution Dry Solid, Flake, Bead, or Granular Wasle Sodium Hydroxide Solulion Dry Sol id. !'lake. Bead. or Granu lar Wasle Sulfuric Acid Waste Chromic Acid Solution Wasle Flammable Liquid NOS Wasle Combuslible Liquid NOS Waste Flammable Solid NOS Wasle Ethylene Dichloride Waste Benzene (benzol) Waste Toluene (loluol) Waste Ethyl benzene Waste Ch lorobcnzene Wasle Methyl Elhyl Kelone WaSle Naphtha Waste I,I,I-Trichloroelhane Petroleum Distillate Lead Dross (containing 3% or more free acid) Hazardous Waste, Liquid or Solid, NOS F2 UN/NA HAZARD CLASS ID NUMBER Corrosive Material NA2672 ORM-A NA2672 Corrosive Material UNI788 Corrosive Material NA1789 Corrosive Material UNI790 Oxidizer UN2031 Corrosive Material NAI760 Corrosive Material UNI805 Corrosive Material UN1814 Corrosive Malerial UNI813 Corrosive Material UNI824 Corrosive Malerial UNlllB Corrosive Material UN1832 Corrosive Material UNI755 Flammable Liquid' UN1993 Combustible Liquid' NAI993 Flammable Solid UNI325 Flammable Liquid UNl184 Flammable Liquid UNII14 Flammahle Liquid UNI294 Flammable Liquid UNI175 Flammable Liquid UNI134 Flammable Liquid UNI193 Flammable Liquid UN2553 ORM-A UN2831 Flammable Liquid Combustible Liquid UNI268 UNI268 ORM-C NAI794 ORM-E NA9189 .,; c .g '0 c o u ~ ~ :~ ~ u ~ '" .c u ~ '" ~ u.. 8 .... '0 C '" .8 ~ g-;; .9 - ~ .~ :t ~ '" .2] ;. ]- c _ c ~ ,= '8- 'CD 8..c o 'ti ..c (,I) ~ ~ ~~ ~ 'u c: cO ~ ~ ~] E ~ oJ: "'0 ~ .~ ;;'g. .9 ~ g~ c.. (5 ~:o .~ ~ ~.~ ~ I ~~ l!~~c8 t-, :f. < ,= Furniture/Wood Manufacturing and Refinishing , INDUSTRY OVERVIEW Your business is included in the Furniture/Wood Manufacturing and Refinishing category if you manufacture or refinish: ~ Wooden kitchen cabinets ~ Hardwood veneer and plywood ~ Softwood veneer and plywood ~ Particleboard ~ Wooden household furniture (except that which is upholstered) ~ Household furniture, not elsewhere classified (new or upholstered) ~ Wooden office furniture, lockers, office and store fixtures ~ Furniture (reupholstery and repair), Not all furniture/wood manufacturing or refinishing operations produce hazardous wastes, However, if you use any solvents, flammable or combustible liquids, combustible solids, or ignitable paints containing flammable solvents, it is possible that the wastes generated from using these materials may be hazardous, and you may be subject to new Resource Conservation and Recovery Act (RCRA) provisions regarding the transportation of small quantities of hazardous waste, Table I lists typical operations/processes that use products which may generate hazardous wastes, HAZARDOUS WASTES FROM THE MANUFACTURINGI REFINISHING OF FURNITURE AND WOOD Furniture and wood manufacturers and refinishers generally produce one or more of the wastes listed in Table 2. If you produce 220 pounds (about half of a 55 gallon drum) or more of hazardous wastes per month, you are subject to certain requirements, including the use of a Uniform Hazardous Waste Manifest when you ship hazardous waste off your premises.t Item lion the Manifest requires the Department of Transportation (DOT) description of the waste, which includes the proper shipping name, hazard class and UN/NA identification number. To help you complete this item, Table 2 provides this information for some of the hazardous wastes you are most likely to generate. To obtain the DOT shipping name, hazard class and UN/NA identification number' Select the typical process/ operation from column I of Table 1. Match the ingredients from column 3 and the waste type generated from column 4 of Table I with the waste type and ingredient in column I of Table 2. If you generate a waste which is not on this list, please consult your state hazardous waste management agency 10 determine if your waste is hazardous, and to obtain the proper DOT information necessary for the Manifest. ISome slates require the manifesting of less than 220 pounds of hazardous materials. Check with your state hazardous waste management agency to determine your requirements under stale law. Table 1 TYPICAL OPERATIONS USING MATERIALS WHICH MAY GENERATE HAZARDOUS WASTES TYPICAL PROCESS! OPERATION Wood cleaning and wax removal TYPICAL MATERIAL INGREDIENTS petroleum di,tillate,. mineral spirits TYPICAL MATERIALS USED petroleum di,lillate,. white 'pirits Refinishing/ Stripping paint removers, varnish rcmovcr~. enamel removers. ,hellac removers, painl solvents, turpentine acelone. toluene, petruleum di,tillate,. methanol. methylene ch loride. alcohols. ketones. oxygenated solvents Staining stains mineral spirits. alcohol, pigments Painting enamels, lacquers. epoxy. alkyds. acrylics toluene, pigments. titanium dioxide. epoxyester resi ns. aromatic hydrocarbon,. glycol ether. halogenated hydrocarbons, vinylacetate acrylic Finishing varn ish. shellac, polyurethane. lacquer> with re,idues denatured alcohols, re,ins. shellac, petroleum distillates. loluene diisocyanate Brush cleaning and spray gun cleaning paint thinners. enamel reducers. varn ish removers, shellac removers, wh ite spirits acetone. toluene, petroleum distillates. methanol. methylene chloride. isopropanol, mineral spirits. alcohols GENERAL TYPES OF WASTES GENERATED ignitable wastes. spent solvents ignitable wa'tes, ignitable paint wastes. solvent slill bottoms ignitable wastes, spent solvents. solvent still bottoms, ignitable paint wastes, ign itable wastes. solvent still bottoms. paint wastes conlaining heavy metals ignitable wastes. spent ,olvent,. solvent still bottoms ignitable paint wastes, ignitable wastes. spent solvents. solvent still bottoms Gl Table 2 WASTE DESCRIPTIONS' DESIGNATIONSI UN/NA WASTE TYPE TRADE NAMES DOT SHIPPING NAME HAZARD CLASS ID NUMBER IGNITABLE WASTES Ignitable Wastes NOS' Ignitable Wastes NOS Waste Flammablc Liquid Petroleum distillates Solvents NOS Flammable Liquid UNI993 Waste Combustible Liquid NOS' Combustible Liquid NAI993 Waste Flammable Solid NOS Flammable Solid UNI325 Waste PClroleum Dislillalcs Flammable Liquid UNI268 IGNITABLE PAINT WASTES CONTAINING Ethylene Dichloride Ethylene Dichloride. Waste Ethylene Dichloride Flammable Liquid UN1I84 I. 2-Dichloroethane Benzene Benzene Waste Benzene (benzol) Flammable Liquid UNII14 Toluene Toluene Waste Toluene (toluol) Flammable Liquid UNI294 Ethyl benzene Ethyl benzene Waste Ethyl benzene Flammable Liquid UN 1175 Chlorobenzene Chlorobenzene. Waste Chlorobenzene Flammable Liquid UNI134 Monochlorobenzene. Phenyl Chloride Methyl Ethyl Ketone Methyl Ethyl Ketone. MEK. Waste Methyl Ethyl Ketone Flammable Liquid UNll93 Methyl Acetone, Meetco, Butanone. Ethyl Methyl Ketone SPENT SOLVENTS AND STILL BOTTOMS Acetone Acetone Waste Acetone Flammable Liquid UN 1090 White Spirits White Spirits. Mineral Waste Naphtha Flammable Liquid UN2553 Spirits. Naphtha Kerosene Kerosene. Fuel oi I # I Waste Kerosene Combustible Liquid UNI223 Methylene Chloride Dichloromethane. Methane Waste Diehloromethane or ORM-A UNI593 Dichloride, Methylene Methylene Chloride Bichloride. NCI-C50102. Solaesthin, Aerothene NarkOlil. Solmethine Toluene Toluene, Methacide, Wasle Toluene (Toluol) Flammable Liquid UNI294 Methylbenzene, Methylbenzol, Phenyl methane, Toluol. Antisal IA Benzene Benzene. Benzol Wasle Benzene (Benzol) Flammable Liquid UN 1114 Ethanol Elhanol. Ethyl Alcohol Waste Ethyl Alcohol Flammable Liquid UNI770 'These descriptions may change given variations in waste characteristics or conditions, 'NOS-not otherwise specified, A liquid is nammable if it has a nash point below 1000F. A liquid is combustible if it has a nash point between 1000 and 2OOoF. G2 Pesticide End-Users/Application Services , INDUSTRY OVERVIEW Several industries are included under 'Pesticide End-Users/ Application Services ~ Agricultural pesticide application services ~ Lawn, garden, and tree services ~ Disinfecting and structural pest control services ~ Arboreta, botanical, and zoological gardens ~ Public golf courses and other facilities regularly using pesticides. Use of pesticides can generate hazardous waste, The type and quantity of waste generated determines what RCRA generator provisions, if any, apply. Even if quantities generated are below small quantity generator levels, hazardous waste should be carefully managed to prevent future health and environmental problems, Farmers using pesticides are exempted from most RCRA provisions, including preparation of a Manifest, provided that pesticide containers are triple rinsed and the rinse solution is either used or disposed of on their own farms in accordance with the pesticide label instructions, HAZARDOUS WASTES GENERATED BY PESTICIDE END-USERS AND APPUCATORS Numerous pesticides are in common use in applications ranging from protection of food and structures to pest and disease control in home gardens, Pesticides, like other chemicals, can be harmful if not used and disposed of properly, that is, in accordance with EPA-approved pesticide label instructions, Several types of wastes from pesticide end-users and applicators are common: ~ Rinsewater" Solutions used to rinse application equipment and product containers and not used per label instructions ~ Empty Containers: Which contain pesticide residues (unless/until triple rinsed) ~ Unused Pesticides: Unusable or unidentifiable material ~ Contaminated Soil: Soil or other material contaminated from spilIs, Some very dilute rinsewater or soils contaminated with very low pesticide concentrations may not be hazardous, but should be treated as hazardous waste unless known to be non-hazardous from label information, chemical analysis, or other reliable source. Pesticide containers that are triple rinsed are not hazardous waste, although the rinse solution may be hazardous, Some pesticide formulations may contain flammable solvents or other material that make the pesticide solution an ignitable (and therefore hazardous) waste, See Table I inside UNIFORM HAZARDOUS WASTE MANIFEST If you generate between 220 and 2,200 pounds (100 to 1,000 kilograms) of hazardous waste per calendar month, you are subject to new small quantity generator provisions requiring the use of a Uniform Hazardous Waste Manifest when you ship hazardous wastes off your premises. Item lIon the Manifest requires the Department of Transportation (DOT) shipping name, hazard class, and UN/NA identification number. This information is included in the following table for a variety of common pesticides, Some pesticides no longer in common use are included in the table because they may be found in storage, DOT descriptions other than those provided in the following table may be applicable to some wastes depending on the waste constituents and their concentrations. For example, if the waste pesticide contains flammable solvents, it may be classified as a combustible liquid (flash point less than 2000F and greater than or equal to lOOOF) or as a flammable liquid (flash point less;han lOOOF), If the waste is combustible or flammable, these classifications should be used instead of other possibly applicable classifications including Poison B, aRM-A, or ORM-E that may be shown in the table. Different hazard classifications generally receive different identification numbers. Some flammable compounds occasionally used in pesticides are included in the table. In order to assess whether RCRA generator requirements are applicable, the entire weight of each waste (e.g., the weight of any contaminated soil), not just the weight of the pesticide, is considered. Even if you generate less than 220pounds (100 kilograms) per calendar month of hazardous waste, you may be subject to state requirements, Regardless of the quantity generated, pesticide wastes should either be used or disposed of in accordance with EPA-approved pesticide container label instructions, FOR MORE INFORMATION If you are not sure whether you produce hazardous waste, whether you are subject to the new small quantity generator provisions, or what the proper DOT description is for your waste, please contact your EPA Regional Office or state hazardous waste management agency for assistance, HI Table 1 PESTICIDE END USERS AND APPLICATION SERVICES WASTE DESCRIPTIONS' WASTE DOT SHIPPING NAME HAZARD CLASS2 UN/NA ID NUMBER , PESTICIDES CONTAINING ARSENIC Arsenic pentoxlde Waste Arsenic Pentoxide, Solid arsenic acid anhydride arsenic (v) oxide Arsenic trioxide arsenic sesquioxide arsenic (111) oxide arsenious acid (anhydride) white arsenic Cacodylic acid hydroxydimethylarsine oxide dimethylarsinic acid Phytar Monosodium methanearsonate MSMA Ansar 170 H.c. and 529 H.C. Arsanote Liquid Bueno 6 Daconate 6 Dal.E-Rad Herb-All Merge 823 Mesamate Monate Trans-Vert Weed-E-Rad Weed-Hoe D1sodlum monomethanearsonate DSMA Ansar 8100 Arrhenal Arsinyl Dinate Di-Tac DMA Methar 30 Sodar Versar DSMA-LQ Weed-E-Rad 360 Poison B UNI559 Waste Arsenic Trioxide, Solid Poison B UNI561 Waste Arsenical Pesticide, Solid, NOS) Poison B UN2759 Waste Arsenical Pesticide, Liquid, NOS Poison B UN2759 Waste Arsenical Pesticide, Liquid, NOS Flammable Liquid UN2760 Waste Arsenical Pesticide, Solid, NOS Poison B UN2759 Waste Arsenical Pesticide, Liquid, NOS Poison B UN2759 Waste Arsenical Pesticide, Liquid, NOS Flammable Liquid UN2760 Waste Arsenical pesticide, Solid, NOS Waste Arsenical Pesticide, Liquid, NOS Waste Arsenical Pesticide, Liquid, NOS Poison B Poison B Flammable Liquid UN2759 UN2759 UN2760 PESTICIDES CONTAINING CARBAMATES Thmlk Waste Carbamate Pesticide, Solid, NOS Aldicarb OMS 771 UC 21149 Waste Carbamate Pesticide, Liquid, NOS Waste Carbamate Pesticide, Liquid, NOS Poison B UN2757 Poison B UN2757 Flammable Liquid UN2758 Poison B UN2777 Poison B UN2777 Flammable Liquid UN2778 Poison B UN2777 Poison B UN2777 Flammable Liquid UN2778 PESTICIDES CONTAINING MERCURY 2-Methoxyelhylmercurlc chloride Waste Mercury Based Pesticide, Solid, NOS ~;~~ Waste Mercury Based Pesticide, Liquid, NOS Cekusil Universal-C Waste Mercury Based Pesticide, Liquid, NOS Ceresan-Universal-Nassbeize Emisan 6 Phenylmercuric acetate PMA PMAS Agrosan Cekusil Celmer Gallotox Hong Nien Liquiphene Mersolite Pamisan Phix Seedtox Shimmer-ex Tag HL 331 Waste Mercury Based Pesticide, Solid, NOS Waste Mercury Based Pesticide, Liquid, NOS Waste Mercury Based Pesticide, Liquid,.NOS 'Other DOT descriptions may be appropriate depending on the formulation, 2 A pesticide normally classed as 'Poison B" or 'ORM-A" (when shipped in containers of I 10 gallons or less) is classified as a 'flammable liquid" if mixed with a solvent such that the resulting solution has a flash point of less than lOOoE Similarly, a pesticide normally classed as 'ORM-E" or 'ORM-A" (when shipped in containers of more than 110 gallons) when mixed with solvents may be classified as a 'flammable liquid" (flash pointless than looOF) or as a combustible liquid" (flash point greater than or equal to 1000F and less than 2oo0F), Note that UN/NA 10 numbers are generally different for different hazard classifications, 3Not Otherwise Specified, H2 ~ Table I (ContInued) PESTICIDE END USERS AND APPLICATION SERVICES WASTE DESCRIPTIONS WASTE DOT SHIPPING NAME UN/NA ID NUMBER HAZARD CLASS2 PESTICIDES CONTAINING NICOTINE Nicotine Waste Poison B. Solid. NOS Black Leaf 40 Waste Poison B, Liquid. NOS Wastc Flammable Liquid. Poisonous. NOS PESTICIDES CONTAINING SUBSTITUTED NITROPHENOLS Dinitrocresol Waste Substituted Nitrophenol Pesticide. Solid. NOS g~~ Waste Substituted Nitrophenol Pesticide. Liquid, NOS Chemsect Waste Substituted Nitrophenol Pesticide. Liquid. NOS Detal Elgetol 30 Nitrador Selinon Sinox Trifocide Trifrina Dinoseb DNBP Basanite Caldon Chemox General Chemox PE Dinitro Dinitro General Dynamite Elgetol 318 Gebutox Hel-Fire Nitropone C Premerge 3 Sinox General Subitex Vertac General Weed Killer Vertac Selective Weed Killer Waste Substituted Nitrophenol Pesticide. Solid. NOS Waste Substituted Nitrophenol Pesticide. Liqu id. NOS Waste Substituted Nitrophenol Pesticide. Liquid. NOS ORGANOPHOSPHATE PESTICIDES Dimethoate AC 12880 Bi 58 EC Cekuthoate Cygon Daphene De-Fend Demos-L40 Dcvigon Dimet Dimethogen Perfekthion Rebelate Rogodial Rogor Roxion Trimetion Waste Organophosphorous Pesticide. Solid. NOS Waste Organophosphorous Peslicide. Liquid. NOS Waste Organophosphorous Pesticide. Liquid. NOS Disulfoton BAY 19639 and S276 Dithiodemeton Dithiosystox Di-Syston Ethylthiodemeton Frumin AL M-74 Solvirex Thiodemeton Waste Disulfoton Waste Disulfoton Mixture. Dry Waste Disulfoton Mixture, Liquid Waste Organophosphorous Pesticide, Liquid. NOS Famphur Bash Bo-Ana Dovip Famfos Warbex Wasle Organophosphorous Peslicide. Solid, NOS Waste Organophosphorous Pesticide. Liquid, NOS Waste Organophosphorous Pesticide. Liquid. NOS H3 Poison B Poison B Flammable Liquid Poison B Poison B Flammable Liquid Poison B Poison B Flammable Liquid Poison B Poison B Flammable Liquid Poison B Poison B Poison B Flammable Liquid Poison B Poison B Flammable Liquid UN28 II UN28 10 UN J 992 UN2779 UN2779 UN2780 UN2779 UN2779 UN2780 UN2783 UN2783 UN2784 NA2783 NA2783 NA2783 UN2784 UN2783 UN2783 UN2784 Table I (Continued) PESTICIDE END USERS AND APPLICATION SERVICES WASTE DESCRIPTIONS ~ WASTE DOT SHIPPING NAME HAZARD CLASS2 UN/NA ID NUMBER Methyl parathion Cekumethion E-601 Devithion Folidol M Fosferno M50 Gearphos Metacide Metaphos Nitrox 80 Parataf Paratox Partron M Penncap-M Wofatox Waste Methyl Parathion, Liquid Waste Methyl Parathion Mixture, Dry Waste Methyl Parathion Mixture, Liquid, (containing 25% or less methyl parathion) Waste Methyl Parathion Mixture, Liquid, (containing more than 25% methyl parathion) Waste Organophosphorous Pesticide, Liquid, NOS Poison B Poison B Poison B NA2783 NA2783 NA2783 Poison B NA2783 Flammable Liquid UN2784 Parathion AC 3422 Alkron Aileron Aphamite Bladan Corothion E-605 ENT 15108 Ethyl Parathion Etilon Folidol E-605 Fosferno 50 Niran Orthophos Panthion Paramar Paraphos Parathene Parawet Phoskil Rhodiatox Soprathion Stathion Thiophos Waste Parathion, Liquid Waste Parathion Mixture, Dry Waste Parathion Mixture, Liquid Waste Organophosphorous Pesticide, Liquid, NOS Poison B Poison B Poison B Flammable Liquid NA2783 NA2783 NA2783 UN2784 STRYCHNINE PESTICIDES Strychnine strychnine salts Waste Strychnine, Solid Waste Strychnine Salt, Solid TRIAZINE PESTICIDES Amitrole Amerol Amino Triazol Weedkiller 90 Amizol AT-9O AT Liquid Azolan Azole Cytrol DiuroJ Farmco Herbizole Simazol Weedazol Weedazol TL Waste Triazine Pesticide, Solid, NOS Waste Triazine Pesticide, Liquid, NOS Waste Triazine Pesticide, Liquid, NOS Poison B UNI692 Poison B UNI692 Poison B NAI707 Flammable Liquid UN 1992 Poison B UN2763 Poison B UN2763 Flammable Liquid UN2764 THALLIUM SULFATE PESTICIDES Thallium sulfate Waste Thallium Sulfate, Solid Thallous sulfate Ratox Waste Flammable Liquid, Poisonous, NOS Zelio H4 . Table 1 (Continued) PESTICIDE END USERS AND APPLICATION SERVICES WASTE DESCRIPTIONS WASTE DOT SHIPPING NAME HAZARD CLASS2 UN/NA ID NUMBER FLAMMABLE SOLVENTS USED IN PESTICIDES Methyl Alcohol Waste Methyl Alcohol Methanol Ethyl Alcohol Ethanol Alcohol Isopropyl Alcohol Isopropanol Toluene Methyl benzene Toluol Xylene Dimethyl benzene Xylol Solvent Mixtures PHENOXY PESTICIDES 2,4-D Amoxone Brush Killer Brush-Rhap Chloroxone Crop Rider D50 DMA4 Dacamine Oed-Weed Oesormone Dinoxo] Emulsamine BK and E3 Envert Dr and 17] Hedonal Miracle Pennamine D Rhodia Salvo Super-D Weedone Verton Visko-Rhap Weed Tox Weed-B-Gone Weed-Rhap Weedar Weedone Weedtrol \ { 2,4,S-T Brush-Rhap Dacamine Oed-Weedon Esteron Farmeo Fence Rider Forron Inverton 245 Line Rider Super D Weedone Tormona Transamine U46 Veon 245 Weedar Weedone Silvex 2,4,5-TP Fenoprop AquaVex Double Strength Fruitone T Kuron Kurosal Silvi-Rhap Weed-B-Gone Flammable Liquid UNl230 Waste Ethyl Alcohol Flammable Liquid UNI170 Waste Isopropanol Flammable Liquid UN12]9 Flammable Liquid UN]294 Flammable Liquid UNI307 Combustible NAI993 Liquid' Flammable Liquid' UNI993 ORM-A NA2765 ORM-E NA2765 Flammable Liquid UN2766 Waste Toluene (toluol) Waste Xylene (xylol) Waste Combustible Liquid, NOS Waste Flammable Liquid, NOS Waste 2,4-Dichlorophenoxyacetic Acid Waste 2,4-Dichlorophenoxyacetic Acid Ester Waste Phenoxy Pesticide, Liquid, NOS Waste 2,4,5-Trichlorophenoxyacelic ACId Waste 2,4,5-Trichlorophenoxyacetic Acid (amine, ester, or salt) Waste Phenoxy Pesticide, Liquid, NOS ORM-A ORM-E NA2765 NA2765 Flammable Liquid UN2766 Waste 2-(2,4,5-Triehlorophenoxy) Propionic Acid Waste 2-(2.4,5-Trichlorophenoxy) Propionic Acid Ester Waste Phenoxy Pesticide, Liquid, NOS NA2765 NA2765 UN2766 ORM-A ORM-E Flammable Liquid 'Substances with a flash point less than loooF are classified as .F1ammable Liquid" substances with a flash point greater than or equal to loooF and less than 2000F are classified as 'Combustible Liquid, H5 Table I (Continued) PESTICIDE END USERS AND APPLICATION SERVICES WASTE DESCRIPTIONS WASTE DOT SHIPPING NAME HAZARD CLASS2 UN/NA ID NUMBER ORGANOCHLORINE PESTICIDES Aldrin Waste Aldrin HHDN Aldrex 30 Aldrite Aldrosol Altox Drinox Octalene Seedrin Liquid Flammable Liquid NA276 I NA276 I NA2761 NA2762 NA2762 UN2762 Waste Aldrin Mixture, Dry (with more than 65% Aldrin) Waste Aldrin Mixture, Dry (wilh 65% or less Aldrin) Waste Aldrin Mixture. Liquid (with more than 60% Aldrin) Waste Aldrin Mixture. Liquid (with 60% or less Aldrin) Waste Organochlorine Pesticide, Liquid, NOS Poison B Poison B ORM-A Poison B ORM-A Chlordane Belt Chlordan ChlorKiI Chlortox Corodane Gold Crest C 100 Kypehlor Vesicol 1068 Topiclor 20 Niran Octachlor Octa-Klor Ortho-Klor Synklor Termi-Ded Waste Chlordane, Liquid Waste Chlordane, Liquid Flammable Liquid Combustible Liquid NA2762 NA2762 DDf Dedelo Didimac Digmar Genitox Gyron Hildit Kopsol Neocid Pentachlorin Rukseam Zerdane Waste Dm Waste Organochlorine Pesticide, Liquid, NOS ORM-A Flammable Liquid NA276 I UN2762 EndosulCan Beosit Chlorthiepin Crisulfan Cyclodan Endocel EnSure FMC 5462 Hildan Hoe 2671 Malix Thifor Thimul Thiodan Thiofor Thionex Tiovel Waste Dichloropropene Flammable Liquid UN2047 Waste Dieldrin ORM-A NA276 I Waste Organochlorine Pesticide, Liquid. NOS Flammable Liquid UN2762 Waste Endrin Poison B NA276 I Waste Endrin Mixture, Liquid Poison B NA2761 Waste Organochlorine Pesticide, Liquid. NOS Flammable Liquid UN2762 Waste Endosulfan Poison B NA2761 Waste Endosulfan Mixture, Liquid Poison B NA2761 Waste Organochlorine Pesticide, Liquid. NOS Flammable Liquid UN2762 Dlchloropropene 1,3-Dichloropropene Telone II Soil Fumigant Dieldrin Dieldrex Dieldrite Octalox Panoram D-31 Endrin Endrex Hexadrin Heptachlor Gold Crest H-60 Drinox H-34 Heptamul Heptox Waste Heptachlor Waste Organochlorine Pesticide, Liquid, NOS ORM-E NA2761 UN2762 Flammable Liquid Kepone Chlordecone GC 1189 Waste Kepone Waste Organochlorine Pesticide, Liquid, NOS H6 ORM-E Flammable Liquid NA276 I UN2762 Table 1 (Continued) PESTICIDE END USERS AND APPLICATION SERVICES WASTE DESCRIPTIONS .. HAZARD UN/NA ID WASTE DOT SHIPPING NAME CLASS2 NUMBER Li nda ne WaSle Lindane ORM-A NA2761 Exagama Waste Organochlorine Pesticide, Liquid, NOS Flammable Liquid UN2762 Forlin Gallogama Gamaphex Gammex Inexit Isotox Lindafor Li ndagam Lindagrain Lindagranox Lindalo Lindamul Lindapoudre Lindaterra Novigam Silvanol Methoxychlor Waste Methoxychlor ORM-E NA2761 Flo Pro McSeed Protectant Waste Organochlorine Pesticide, Solid, NOS Poison B UN2761 Marlate Waste Organochlorine Pesticide, Liquid, NOS Poison B UN2761 Waste Organochlorine Pesticide, Liquid. NOS Flammable Liquid UN2762 Propylene Dichloride Waste Propylene Dichloride Flammable Liquid UNI279 1,2-Dichloropropane Toxaphene Waste Toxaphene ORM-A NA2761 AUac 4-2, 4-4 6,6-3,8 Waste Organochlorine Pesticide, Liquid, NOS Flammable Liquid UN2762 Camphochlor Motox Phenacide Phenatox Strobane T-90 Toxakil Toxon 63 OTHER PESTICIDES Thiram Waste Thiram ORM-A NA277 I TMTD Waste Flammable Liquid, Poisonous, NOS Flammable Liquid UNI992 AAtack Arasan Aules Evershield T Seed Protectant Fermide 850 Fernasan F10 Pro T Seed Protectant Hexathir Mercuram Nomersan Pomarsol forte Polyram-Ullra Spotrete-F Tetrapom Thimer Thioknock Thiotex Thiramad Thirasan Thiuramin Tirampa Trametan Tripomol Thylate Tuads Vancide TM Warfarin Hazardous Waste, Solid, NOS ORM-E NA9189 Co-Rax Hazardous Waste, Liquid, NOS ORM-E Cov-R-Tox NA9189 Kypfarin Waste Flammable Liquid, NOS Flammable Liquid UNI993 Liqua-Tox Waste Combustible Liquid, NOS Combustible NA 1993 RAX Rodex Liquid Rodex Blox Tox-Hid H7 Table 1 (Contmued) PESTICIDE END USERS AND APPLICATION SERVICES WASTE DESCRIPTIONS WASTE UN/NA ID NUMBER ., Pentachlorophenol pcp Penta Penchlorol Pentacon Penwar Sinituho Santophen Pentachloronltrobenune PCNB Avicol Botrilex Brassicol Earthcide Folosan Kobu Pentagen Saniclor 30 Terraclor Tilcarex Tritisan Hexaehlorobenzene Perchlorobenzene Anticarie Ceku C.B, HCB No Bunt 1,2-Dibromo J-Chloropropane DBCP Nemafume Nemanox Nemaset Nematocide DOT SHIPPING NAME HAZARD CLASS2 ORM-E NA2020 UN 1993 NAI993 NA9189 NA9189 UNI993 NA I 993 NA9189 NA9189 UNI993 NAI993 NA9l89 NA9189 UNl993 NAl993 Waste Pentachlorophenol Waste Flammable Liquid. NOS Waste Combustible Liquid, NOS Flammable Liquid Combustible Liqu id Hazardous Waste, Solid Hazardous Waste, Liquid Waste Flammable Liquid, NOS Waste Combustible Liquid. NOS ORM-E ORM-E Flammable Liquid Combustible Liquid Hazardous Waste, Solid, NOS Hazardous Waste, Liquid, NOS Waste Flammable Liquid, NOS Waste Combustible Liquid, NOS ORM-E ORM-E Flammable Liquid Combustible Liquid Hazardous Waste, Solid, NOS Hazardous Waste, Liquid, NOS Waste Flammable Liquid, NOS Waste Combustible Liquid, NOS ORM-E ORM-E Flammable Liquid Combustible Liquid H8 Chemical Manufacturers Your business is included in the Chemical Manufacturers category if you manufacture: ~ Industrial inorganic chemicals ~ Industrial organic chemicals ~ Pigments ~ Plastics ~ Pesticides ~ Synthetic rubber ~ Explosives ~ Synthetic fibers ~ Gum and wood chemicals, HAZARDOUS WASTES FROM CHEMICAL MANUFACTURING Although the wide range of products and processes used in the chemical manufacturing industry prevents a comprehensive discussion, chemical manufacturing in general produces a variety of hazardous wastes, EPA regulates wastes that exhibit any of the following characteristics as hazardous wastes: ~ Ignltablllty, Ignitable wastes include liquids with a flash point of less than 140oF' solids that ignite spontaneously through absorption of moisture or through friction and burn vigorously' flammable gases; and oxidizers. ~ Corroslvlty, Corrosive wastes include aqueous solutions with a pH less than or equal to 2 or greater than or equal to 12.5 and liquids that corrode steel at a rate of greater than 0,25 inch per year. ~ Reactivity, Reactive wastes include substances that are unstable and readily undergo violent change; react violently with water' form potentially explosive mixtures with water' are capable of detonation or explosive reaction when exposed to a strong initiating source; or generate significant quantities of toxic gases when exposed to water or, in the case of cyanide or sulfide bearing wastes, pH conditions between 2 and 12,5. ~ EP Toxicity, Wastes are EP toxic if an extract from the waste contains more than the concentrations of arsenic, barium, cadmium, chromium, lead, mercury, selenium, silver, endrin, lindane, methoxychlor, toxaphene, 2,4-D, or 2,4,5-TP specified in RCRA regulations, EPA also regulates additional wastes which are specifically listed in regulations because of one or more of the above characteristics or because of the followi ng criteria: See Table I inside ~ Acute hazard, Wastes are acutely hazardous if they are fatal to humans in low doses, are capable of contributing to serious irreversible or incapacitating reversible illness, or have been shown to have an oral LD50 (rat) of less than 50 mgtkg, an inhalation LC50 (rat) of less than 2 mgll, or a dermal LD50 (rabbit) of less than 200 mgtkg, ~ Toxicity, Wastes are generally considered to be toxic if they contain any of a number of toxic constituents listed in Appendix VIII of 40 CFR Part 261. The generator has the responsibility for determining whether a waste is hazardous. In making this determination, it is advisable to consult the RCRA regulations found in the Code of Federal Regulations, Title 40, Part 261 that describe the hazard characteristics and specify test methods. Typical wastes from chemical manufacturing plants include spent solvents, distillation bottoms and side cuts, off-specification or unused chemicals, wastewater treatment sludges, emission control sludges, filter cake, spent catalysts, byproducts, reactor c1eanout wastes, and container residues, If you generate between 220 and 2,200 pounds of hazardous waste per calendar month, you are subject to new small quantity generator provisions requiring the use of a Uniform Hazardous Waste Manifest when you ship hazardous wastes off your premises, Item 11 of the Manifest requires the Department of Transportation (DOT) shipping description, which includes the proper DOT shipping name, hazard class, and UNtNA identification number for each waste, The following table provides some examples of typical chemical manufacturing wastes and their DOT descriptions, If you are not sure whether your wastes are hazardous or if you need guidance on determining the proper DOT description, please contact your state hazardous waste management agency or EPA Regional Office for assIstance. 11 Table I CHEMICAL MANUFACTURING WASTE DESCRIPTIONS' DESIGNATIONSI DOT HAZARD UN/NA WASTE TYPE TRADE NAMES SHIPPING NAME CLASS ID NUMBER SPENT SOLVENTS AND STILL BOTTOMS2 White Spirits White Spirits, Waste Naphtha Combustible UN2553 Mineral Spirits, Liquid' Naphtha Waste Naphtha Flammable Liquid" UN2553 Waste Naphtha, Solvent Combustible UNl256 Liqu id Wa,'e Naphtha, Solvent Flammable Liquid UNI256 Kerosene Kerosene Waste Kerosene Combustible UN 1223 Fuel oil # I Liquid Benzene Benzene Waste Benzene (Benzol) Flammable Liquid UNll14 Ethyl Benzene Ethyl Benzene Waste Ethyl Benzene Flammable Liquid UN1l75 Toluene Toluene, Methacide, Waste Toluene (Toluol) Flammable Liquid UNI294 Methylbenzene, Methylbenzol, Phenyl methane, Toluol, AntisallA Toluene Diisocyanate Toluene Diisocyanate Waste Toluene Di isocyanate Poison B UN2078 Xylene Xylene, Xylol Waste Xylene Flammable Liquid UN 1307 Ethanol Ethanol, Ethyl Alcohol WastClEthyl Alcohol Flammable Liquid UNI170 Isopropanol Isopropanol, Isopropyl Alcohol Waste Isopropanol Flammable Liquid UNl219 Acetone Acetone Waste Acetone Flammable Liquid UN 1090 Methyl Ethyl Ketone Methyl Ethyl Ketone Waste Methyl Ethyl Ketone Flammable Liquid UNl193 1etrahydrofuran Tetrahydrofuran, THF Waste Tetrahydrofuran Flammable Liquid UN2056 Methylene Chloride Dichloromethane, Methane Waste Dichloromethane or ORM-A UNI593 Dichloride, Methylene Bichloride, Methylene Chloride NCI-C50102, Solaesthin, Aerothene, Narkotil, Solmethine I,I,I-Trichloroethane I I I-Trichloroethane, Aerothane Waste I I I-Trichloroethane ORM-A UN2831 IT, Chlorten, lnhibisol, 'Il"ichloroethane, Chlorothene NV, NCI-C04626, Methylchloroform, Chlorothene VG, Chlorothane NU, Chlorotene Trichloroethylene Perm-A-Chlor, Trielin, Triline, Waste Trichloroethylene ORM-A VNI710 Triol, Vestrol, Chlorylene, Dow- Tri, Vitran, TeE, Nialk, Philex IGNITABLE WASTES NOT OTHERWISE SPECIFIED (NOS) Ignitable Wastes Ignitable Wastes Waste Flammable Liquid. NOS Flammable Liquid UNl993 Waste Combustible Liquid, NOS Combustible NAI993 Liqu id Waste Flammable Solid, NOS Flammable Solid UNl325 lThese descriptions may change given variations in waste characteristics and conditions, 25till bonoms may not be hazardous if the concentration of the hazardous materials in the still bonom are sufficiently low, 'Formulations with a flash point less than 2000F and greater than or equal to loooE 'Formulations with a flash pointless than lOOOE 12 Table 1 (Continued) CHEMICAL MANUFACTURING WASTE DESCRIPTIONS WASTE TYPE UN/NA ID NUMBER DESIGNATIONS/ TRADE NAMES DOT SHIPPING NAME HAZARD CLASS STRONG ACID/ALKALINE WASTES Ammonium Hydroxide Ammonium Hydroxide, NH40H, Spirit of Hartshorn, Aqua Ammonia Hydrobromic Acid Hydrochloric Acid Hydronuoric Acid Nitric Acid Phosphoric Acid Potassium Hydroxide Sodium Hydroxide Sulruric Acid Chromic Acid Hydrobromic Acid. HBr Hydrochloric Acid, HCI. Muriatic Acid Hydrofluoric Acid, HF. Fluorohydric Acid Nitric Acid. HN02. Aquafortis Phosphoric Acid, H3P04 Or! hophosphoric Acid Potassium Hydroxide. KOH. Potassium Hydrate. Caustic Potash, Potassa Waste Ammonium Hydroxide Corrosive Material (containing not less than 12% but not more than 44% ammonia) \V,lsIC Ammonium Hydroxide (colllaining less than 12(,*~ ammonia) ORM-A NA2672 NA2672 UNl788 NAl789 UNI790 UN203l NAI760 UNI805 UNl814 UNI813 Sodium Hydroxide. NaOH, Waste Sodium Hydroxide Corrosive Material UNI824 Caustic Soda. Soda Lye. Sodium Solution Hydrate Waste Sodium Hydroxide. Dry Corrosive Material UNI823 Solid, Flake. Bead, or Granu lar Sulfuric Acid, H2SO4 Oil of Waste Sulfuric Acid. Spent Corrosive Material UNI832 Vitriol Chromic Acid Waste Chromic Acid Solution Corrosive Material UN 1755 OTHER REACTIVE WASTES Hypochlorite Hypochlorite, Sodium Hypochlorite (or other salts). Hypochlorous Acid. Oorox Waste Hydrobromic Acid Corrosive Material Waste Hydrochloric Acid Mixture Corrosive Material Waste Hydrofluoric Acid Solution Corrosive Material Waste Nitric Acid (over 40%) Oxidizer Waste Nitric Acid (40% or less) Corrosive Material Wastc Phosphoric Acid Corrosive Matcrial Waste Potassium Hydroxide Corrosive Material Solution Waste Potassium Hydroxide Corrosive Material Dry Sol id. Flake, Bead, or Granular Waste Hypochlorite Solution (containing not more than 7% available chlorine by weight) Waste Hypochlorite Solution (containing more than 7% available chlorine by weight) ORM-B NAl791 UNl791 Organic Peroxides Organic Peroxide Waste Organic Peroxide, (liquid Organ ic Perox ide NA9183 or solution), NOS Sodium Perchlorate Sodium Perchlorate Waste Sodium Perch lorale Oxidizer UN1502 Potassium Perchlorate Potassium Perchlorate Waste Potassium Perchlorate Oxidizer UNI489 Potassium Permanganate Potassium Permanganate Waste Potassium Permanganate Ox idizer UNI490 Sodium Permanganate Sodium Permanganate Waste Sodium Permanganate Oxidizer UNI503 Potassium Sulfide Potassium Sulfide Waste Potassium Sulfide Flammable Solid UNI382 Sodium Sulfide Sodium Sulfidc. Sodium Sulfuret Waste Sodium Sulfide. Flammable Solid UNI385 Anhydrous 13 Corrosive Material Table 1 (Continued) CHEMICAL MANUFACTURING WASTE DESCRIPTIONS WASTE TYPE DESIGNATIONS I TRADE NAMES DOT SHIPPING NAME HAZARD CLASS UNINA ID NUMBER EMISSION CONTROL DUSTS AND SLUDGES Flue dusts from degassing Heavy metal dust containing agents used in glass Arsenic, Barium, Cadmium, production Chromium, Mercury, Lead, Silver, andlor Selenium Hazardous Wasle, Sol id, NOS ORM-E NA9l89 SPENT CATALYSTS Waste heavy metal catalysts from plastic materials, synthetic spinning and polymerization Heavy metal sludges with organics containing Antimony, Cadmium, Cobalt, Manganese, andlor Zinc Hazardous Waste, (Liquid or Solid), NOS ORM-E NA9189 14 Table 1 (continued) CONSTRUCTION WASTE DESCRIPTIONS' WASTE TYPE DESIGNATIONSI DOT HAZARD UN/NA TRADE NAMES SHIPPING NAME CLASS ID NUMBER IGNITABLE WASTES NOS Ignitable Wastes NOS Ignitable Wastes NOS Waste Flammable Liquid NOS Flammable Liquid2 UNI993 Waste Combustible Liquid NOS Combustible Liquid J NAI993 Waste Flammable Solid NOS Flammable Solid UNI325 Waste Flammable Solid. Corro- Flammable Solid UN2925 sive, NOS SPENT SOLVENTS Methylene Chloride Aerothene MM, Narkotil Waste Dichloromethane or ORM-A UNI593 Methylene Chloride Carbon Thtrachloride Perchloromethane, Tetraform, Waste Carbon Tetrachloride ORM-A UNI846 Carbona, Halon 104 Trichlorotrinuoroethane Fluorocarbon 113 Freon 113 Hazardous Waste, Liquid, NOS ORM-E NA9189 Ucon 113 Freon TF, Frigen 113 I 13TR-T, Arcton 63 Toluene Toluol, Methercid, Methyl Ben- Waste Toluene (toluol) Flammable Liquid UNI294 zene, Methylbenzol, Phenyl- methane, Antisol IA Xylene Xylene, Xylol Waste Xylene (xylol) Flammable Liquid UNI307 Kerosene Kerosene, Fuel Oil #1 Waste Kerosene Combustible Liquid UNI223 Mineral Spirits White Spirits, Naphtha Waste Naphtha Flammable Liquid UN2553 Acetone Acetone Waste Acetone Flammable Liquid UN 1090 STRONG ACIDI ALKALINE WASTES Ammonium Hydroxide Ammonium Hydroxide, NH40H, Waste Ammonium Hydroxide Corrosive Material NA2672 Spirit of Hartshorn, Aqua (containiQg not less than 12% but Ammonja not more than 44% ammonia) (containing less than 12% ammo- ORM-A NA2672 nia) Hydrobromic Acid Hydrobromic Acid. HBr Waste Hydrobromic Acid Corrosive Material UNI788 Hydrochloric Acid Hydrochloric Acid, HCI Waste Hydrochloric Acid Corrosive Material NA 1789 Muriatic Acid Hydrofluoric Acid Hydrofluoric Acid, HF, Fluoro- Waste Hydrofluoric Acid Corrosive Material UNI790 hydric Acid Nitric Acid Nitric Acid, HN02, Aquafortis Waste Nitric Acid (over 40%) Oxidizer UN2031 (40% or less) Corrosive Material NAI760 Phosphoric Acid Phosphoric Acid, H3P04 Ortho- Waste Phosphoric Acid Corrosive Material UNI805 phosphoric Acid Potassium Hydroxide Potassium Hydroxide, KOH, Po- Waste Potassium Hydroxide Corrosive Material UNI814 tassium Hydrate, Caustic Potash, Solution Potassa Dry Sol id, Flake, Bead. or Corrosive Material UNI813 Granular Sodiunl Hydroxide Sodium Hydroxide, NaOH, Waste Sodium Hydroxide Corrosive Material UNI824 Caustic Soda, Soda 4'e, Solution Sodium Hydrate Dry Solid. Flake, Bead, or Corrosive Material UNI823 Granular Sulfuric Acid Sulfuric Acid, H2SO4, Oil of Waste Sulfuric Acid, Spent Corrosi ve Material UNI832 Vitriol 'These descriptions may change given variations in waste characteristics or conditions. 2 A flammable liquid has a flash point less than lOOoF, J A combustible liquid has a flash point between 1000 and 2OOoF, J2 Construction INDUSTRY OVERVIEW You are included in the Construction Industry if you provide services in the following areas: ~ Plumbing, heating, and air conditioning ~ Painting, paper hanging, and decorating ~ Mobile home construction ~ Prefabricated wood buildings and components ~ Terazzo, tile, marble, and mosaic work ~ Floor laying and other floorwork, not elsewhere classified ~ Roofing and sheet metal work ~ Glass and glazing work If your operation is involved in one of the above activities and you use strong acid or alkaline solutions, paints, solvents, or other ignitable or flammable compounds, you may be subject to new provisions of the Resource Conserva~ion and Recovery Act (RCRA) for small quantity generators of hazardous waste. Not all construction industry operations produce hazardous waste, but if you use any of these materials, it is possible that the wastes generated during their use may be hazardous, HAZARDOUS WASTES FROM THE CONSTRUCTION INDUSTRY The wastes from this industry fall into four major categories: ~ Ignitable Paint Wastes These wastes are generated by painting and other associated processes, including paint preparation and brush and spray gun cleaning. ~ Ignitable Wastes, Not Otherwise Specified (NOS) These wastes may include paint and varnish removers, paint brush cleaners, and epoxy resins and adhesives and are generated by processes such as painting, cleaning, and degreasing, All of the construction activities listed above were identified as producing ignitable wastes. ~ Spent Solvents Solvents may come from many processes, including painting, cleaning, degreasing, air conditioner maintenance, and fluxing, ~ Strong Acid! Alkaline Wastes Strong acid and alkaline solutions may be used in cleaning, degreasing, and plumbing operations, Some businesses may generate spent heat transfer boxes that contain PCBs, PCBs are not regulated under RCRA, however, they are regulated under the Toxic Substances Control Act (TSCA), If you have spent heat transfer boxes, contact your state hazardous waste management agency to determine your responsibilities, In addition to these wastes, your operations may generate used oil. Currently, most used oil is exempt from EPA hazardous waste regulation if it is recycled, If you recycle your oil, it doesn't need to be manifested or counted in determining your monthly hazardous waste generation rate, Some states, however, currently regulate used oil differently than does EPA. Contact your state agency for more information. EPA is now in the process of developing new regulations for used oil. Although not all businesses produce each of the wastes listed, it is likely that your business produces some of them. If you produce 220 pounds or more of hazardous waste per month, you are subject to certain requirements, one of which is the use of the Uniform Hazardous Waste Manifest when you ship such wastes off your premises. Item I I on the Manifest requ ires the Department of Transportation (DOT) description of the waste, which includes the proper DOT shipping name, hazard class, and UN/NA identification number. This information for the hazardous wastes described above is provided in Table L While some trade/product names are provided, you should check any products you use for the compounds listed to determine whether or not the product is hazardous. You may also produce hazardous wastes not addressed in this waste summary. If you suspect that you do or if you have any questions concerning hazardous waste regulation in your state, contact your state hazardous waste management agency or EPA regional office. Table I CONSTRUCTION WASTE DESCRIPTIONS1 WASTE TYPE DESIGNATIONS/ DOT HAZARD UN/NA TRADE NAMES SHIPPING NAME CLASS ID NUMBER IGNITABLE PAINT WASTES Ethylene Dichloride Ethylene Dichloride, Waste Ethylene Dichloride Flammable Liquid UNII84 1,2-Dichloroethane Benzene Benzene Waste Benzene (benzol) Flammable Liquid UNII14 Totuene Toluene Waste Toluene (toluol) Flammable Liquid UNI294 Ethyl Benzene Ethyl Benzene Waste Ethyl Benzene Flammable Liquid UNIl75 Chlorobenzene Chlorobenzene, Monochloroben- Waste Chlorobenzene Flammable Liquid UNI134 zene, Phenylchloride Methyl Ethyl Ketone Methyl Ethyl Ketone, MEK, Waste Methyl Ethyl Ketone Flammable Liquid UNIl93 Methyl Acetone, Meetco, Buta- none, Ethyl Methyl Ketone Methyl Isobutyl Ketone Shell MIBK Waste Flammable Liquid NOS Flammable Liquid UNI993 'These descriptions may change given variations in waste characteristics or conditions, Jl Table I continued on back, Table 1 (contInued) TYPICAL OPERATIONS USING MATERIALS WHICH MAY GENERATE HAZARDOUS WASTES TYPICAL PROCESS/ OPERATION TYPICAL MATERIALS USED TYPICAL MATERIAL INGREDIENTS ON LABEL GENERAL TYPES OF WASTES GENERATED Spray booth, spray guns, and brush cleaning paint thinners, enamel re- duccrs, solvents, white spirits ketones, alcohols, tolu- ene, acetone. isopropyl alcohol. petroleum dis- tillates, mineral spirits Paint removal solvents, paint thinners, enamel reducers. white spirits acetone, toluene, petro- leum distillates, metha- nol, methylene chloride, isopropyl alcohol, min- eral spirits, alcohols, ke tones, other oxygenated solvents Used lead acid batteries lead dross, less than Yk free acids car, truck, boat, mowrcy' cle, and other vehicle bat- teries ignitable paint wastes, heavy metal p"int w"stes, spent solvents ignitable paint wastes. heavy metal pain! wastes, spent solvents used lead acid batteries. strong acid/alkaline solu- tions Table 2 WASTE DESCRIPTIONS' WASTE TYPE DESIGNATIONS/ DOT HAZARD UN/NA TRADE NAMES SHIPPING NAME CLASS ID NUMBER STRONG ACID/ALKALINE WASTES Ammonium Hydroxide Ammonium Hydroxide, NH40H, Waste Ammonium Hydroxide Corrosive Material NA2672 Spirit of Hartshorn, Aqua (containing not less than 12% but Ammonia not more than 44% ammonia) (containing less than 12% ORM-A NA2672 ammonia) Hydrobromic Acid Hydrobromic Acid, HBr Waste Hydrobromic Acid (more Corrosive Material UNI788 than 49% strength) Hydrochloric Acid Hydrochloric Acid, HCi, Muriatic Waste Hydrochloric Acid Mixture Corrosive Material NA 1789 Acid Hydrofluoric Acid Hydrofluoric Acid, HF. Fluorohy- Waste Hydrofluoric Acid Solution Corrosive Material UNI790 dric Acid Nitric Acid Nitric Acid, HN02, Aquafortis Waste Nitric Acid (over 40%) Oxidizer UN2031 (40% or less) Corrosi ve Material NAI760 Phosphoric Acid Phosphoric Acid, H3P04 Ortho- Waste Phosphoric Acid Corrosive Material UNI805 phosphoric acid Potassium Hydroxide Potassium Hydroxide, KOH, Po- Waste Potassium Hydroxide Corrosive Material UNI814 tassium Hydrate, Caustic Potash, Solution Potassa Dry Sol id, Flake, Bead, or Corrosive Material UNI813 Granular Sodium Hydroxide Sodium Hydroxide, NaOH, Caus- Waste Sodium Hydroxide Corrosive Material UNI824 tic Soda, Soda Lye. Sodium Solution Hydrate Dry Sol id. Flake, Bead, or Corrosive Material UNI823 Granul"r Sulfuric Acid Sulfuric Acid, H2SO4 Oil of Waste Sulfuric Acid, Spent Corrosive Material UN1832 Vitriol Chromic Acid Chromic Acid Waste Chromic Acid Solution Corrosive Material UNl755 'These descriptions may change given variations in waste characteristics or conditions, K2 Table 2 (contInued) WASTE DESCRIPTIONS' DESIGNATIONSI TRADE NAMES WASTE TYPE IGNITABLE WASTES Ignitable Wastes NOS' Carburetor Cleaners Aromatic Hydrocarbons Petroleum Distillates Ignitable Wastes NOS IGNITABLE PAINT WASTES Ethylene Dichloride Ethylene Dichloride, 1,2-Dichloroethane Benzene Benzene Toluene Toluene Ethyl Benzene Ethyl Benzene Chlorobenzene Chlorobenzene, Monochloroben- zene, Phenylchloride Methyl Ethyl Ketone Methyl Ethyl Ketone, MEK, Methyl Acetone, Meetco, Buta- none, Ethyl Methyl Ketone SPENT SOLVENTS White Spirits. Varsol Whitc Spirils, Mineral Spirits, Naphtha t,t,l-Trichloroethane Aeothane TT, Chlorlen, Chloro- ethene, Methyl Chloroform, Alpha. T, Chlorotene Petroleum Distillates Petroleum Distillates LEAD-ACID BATTERIES Lead-Acid Batteries Lead-Acid Baneries PAINT WASTES WITH HEAVY METALS Heavy metal paints Heavv Metal Paints with: ' Lead Nickel Chromium DOT HAZARD UN/NA SHIPPING NAME CLASS ID NUMBER Waste Flammable Liquid, NOS Flammable Liquid' UNI993 Waste Combustible Liquid, NOS Combuslible Liquid' NAI993 Waste Flammable Solid, NOS Flammable Solid UN1325 Waste Ethylene Dichloride Flammable Liquid UNI184 Waste Benzene (benzol) Flammable Liquid UNII14 Waste Toluene (Ioluol) Flammable Liquid UNI294 Waste Ethyl Benzene Flammable Liquid UNI175 Waste Chlorobenzene Flammable Liquid UNII34 Waste Methyl Ethyl Ketone Flammable Liquid UNI193 Waste Napht ha Flammable Liquid UN2553 Waste I I I-Trichloroethane ORM-A UN283l Waste Petroleum Distillate Flammable Liquid UNI268 Combustible Liquid UNI268 Lead Dross (containing 3% or ORM-C NA 1794 more free acid) Hazardous Waste, Liquid or ORM-E NA9189 Solid, NOS IThese descriptions may change given variations in wasle characterislics or conditions. 'NOS-Not otherwise specified 'A flammable liquid has a flash point below looof A combustible liquid has a flash point between 1000 and 2000P however, wastes with flash points above 1400F are nol hazardous by EPA stan- dards, and need not be manifesoed, Note: For definitions of 'mixture and 'solution, see 49 CFR 171 K3 Motor Freight Terminals/ Railroad Transportation INOOSTRY OVERVIEW Your industry is classified under Motor Freight Terminals! Railroad Transportation if you are primarily engaged in: ~ the operation of terminal facilities used by highway vehicles ~ the maintenance and service of trucks and other highway vehicles ~ line haul railroad operations ~ the furnishing of terminal facilities for rail passenger or freight -traffic for line hau I serv ice ~ the movement of railroad l:ars between terminal yards, If your business falIs into one of the categories mentioned above and you use solvents, strong acid or alkaline solutions, paints, or lead acid batteries, you may be subject to new Resource Conservation and Recovery Act (RCRA) provisions for the treatment, storage, transport, and disposal of smalI quantities of hazardous waste, HAZARDOUS WASTES FROM MOTOR FREIGIfT TERMINALS/RAILROAD TRANSPORTAnON Motor Freight Terminals may perform a variety of activities including: loading and unloading dry packaged goods, cleaning tank trucks that have been offloaded, cleaning and painting trucks, and maintaining highway vehicles, For the purpose of this summary we have included alI wastes which could be associated with Motor Freight Terminal activities. While alI operations involve loading and unloading activities, not alI Motor Freight Terminals are equipped with maintenance facilities, Therefore, it is possible that a particular terminal or facility docs not generate some or any of the wastes included in this summary, Operations that involve cleaning the inside of tank trucks that have been offloaded wilI generate wastes that contain smalI amounts of the substance that was being shipped, This waste may also be hazardous, Wastes from the Railroad Transportation industry come predominantly from maintenance operations in which trains are cleaned and repaired. Routine operations, similar to those carried out by motor freight terminals, may generate wastes that include strong acid or alkaline materials, spent cleaning and degreasing solvents, ignitable paint wastes, and lead acid batteries. In addition, older freight cars with plan... bearings may generate lead- contaminated lubricating pads which may also be hazardous, If you produce more than 100 kilograms (220 pounds or about half of a 55-gallon drum) of hazardous waste per month you must fill out a Uniform Hazardous Waste Manifest when the waste is shipped off-site. Item 11 of the Manifest requires the Department of Transportation (DOT) description of the waste, including the proper shipping name, hazard class, and UN/NA identification number. Table I is a summary of some maintenance operations that generate hazardous waste, Table 2 provides some of the information required for Item II of the Manifest. If you have questions concerning your wastes or the Manifest requirements, contact your state hazardous waste management agency or EPA regional office, ( ., Table 1 TYPICAL OPERATIONS USING MATERIALS WHICH MAY GENERATE HAZARDOUS WASTES TYPICAL PROCESS/ OPERATION TYPICAL MATERIAL INGREDIENTS ON LABEL GENERAL TYPES OF WASTES GENERATED TYPICAL MATERIALS USED Oil and grease removal degreasers-(gunk) car buretor cleaners, engine cleaners, varsol, solvents, acids/alkalies petroleum distillates, aro- matic hydrocarbons, min- erai spirits, chlorinated hydrocarbons Engine, parts and equipment cleaning degreasers-(gunk) car buretor cleaners, engine cleaners, solvents, acids/ alkalies, cleaning fluids petroleum distillates, aro- matic hydrocarbons, min- erai spirits, benzene, tolu- ene, petroleum naphtha Rust removal naval jelly, strong acids, strong alkalies phosphoric acid, hydro- chloric acid, hydrofluoric acid, sodium hydroxide Paint preparation paint thinners, enamel re- ducers, white spirits alcohols, petroleum dis- tillates, oxygenated sol- vents, mineral spirits, ketones Painting enamels, lacquers, epoxys, alkyds, acrylics, primers acetone, toluene, petro- leum distillates, epoxy ester resins, methylene chloride, xylene, VM&P naphtha, aromatic hydro- carbons, methyl isobutyl ketones Table 1 continued on inside. ign it able wastes, spent solvents, combustible sol- ids, waste acid/alkaline solutions ignitable wastes, spent solvents, combustible sol- ids, waste acid/alkaline solutions waste acids. waste alkalies spent solvents, ignitable wastes, ignitable paint wastes, paint wastes with heavy metals ignitable paint wastes, spent solvents, paint wastes with heavy met- als, ignitable wastes Kl Printing and Allied Industries Your firm is included in Printing and Allied Industries if it is involved in: PreparaUon ~ Typesetting ~ Lithography ~ Letterpress ~ Gravure ~ Engraving (stationery) ~ Photoengraving Printing ~ Heatset Lithography ~ Non Heatset Lithography ~ Thermography ~ Business Form Printing ~ Sheetfed Lithography ~ Letterpress Printing (including tlexography) ~ Gravure Printing ~ Screen Press Printing Finishing Operations ~ Looseleaf Binder Manufacturers ~ Trade Binding Operations ~ Book Binding Operations ~ In House Binding Operations ~ Magazine and Catalog Binding Operations Not all printing or allied industry operations produce hazardous waste. However if you use ignitable (tlash point",. 1400F) solvents, strong acid/alkaline solutions, paint or ink containing solvents or heavy metals (in concentrations greater than the EP Toxicity levels) or both, the wastes you generate may be hazardous. If so, you may be subject to new Resource Conservation and Recovery Act (RCRA) provisions concerning the generation and transportation of hazardous wastes. Table I lists typical processes/operations in the printing and allied industries which could produce hazardous wastes. See Tablcs I and 2 insidc HAZARDOUS WASTES FROM PRINTING AND AllIED INDUSTRIES ~ ~ ~ ~ r' ~ ~ ~ (f ~ ~ ~ , Printing generates waste ink and ink sludges that may contain solvents and sometimes heavy metals, The composition of inks used in printing and allied industries varies greatly depending on whether an ink is to be used for lithography letterpress, gravure, tlexography or screen printing, Oil-based or paste inks are generally composed of colorant or pigments (carbon black, i/lorganic and organic) varnish (drying oils, alkyd, resin- phenolic, resin-ester) drier (cobalt, manganese, or zirconium fatty acid compounds) sometimes an extender solvents and modifiers (waxes, petroleum solvents, and magnesia) Fluid inks contain a vehicle comprised of resin and solvent or oil and additives such as waxes, drier and wetting agents, While not all waste inks and ink sludges will be hazardous, those containing solvents or heavy metals generally are Photographic processes are used in all of the major printing operations for image conversion and plate-making Photographic wastes therefore comprise a large portion of the hazardous waste generated in these industries Photographic processing solutions, developers hardeners, plating chemicals, fountain solutions, or fixing baths that are sent to publicly-owned treatment works (POTWS) for disposal however are exempt from new (RCRA) requirements Silver-containing solutions that pass through electrolytic chemical replacement, or ion exchange silver recovery units located on your premises are similarly exempt. However if you send your wastes off-site for recycling (i e silver recovery or solvent recovery) the wastes must be accompanied by a Manifest. If your business produces 220 pounds or more of hazardous waste per month, you are required to use a Uniform Hazardous Waste Manifest when you ship such wastes off your premises. Item lion the Manifest requires the Department of Transportation (DOT) shipping description, the proper DOT shipping name, hazard class, and UN/NA identification number This information is provided in Table 2. If you do not find your waste listed here, but suspect it may be hazardous, please contact your state hazardous waste management agency for additional assistance. .... E ~ ( , ~ ~ ~ , , CJ r: ~ ( CJ Ll Table 1 HAZARDOUS WASTES GENERATED BY VARIOUS PRINTING OPERATIONS TYPICAL PROCESS/ TYPICAL TYPICAL MATERIAL GENERAL OPERATION MATERIALS USED INGREDIENTS WASTE TYPES PLATE PREPARATION .Counter-etch to re- move oxide .Deep-etch coating of plates .Etch baths Apply light sensitive coating Develop plates Wash/clean plates, type, die, press blan- kets and rollers · Apply lacquer Using Ink (lithogra- phy, letterpress, screen printing. flexography) Making gravure cyl- Inders Phosphoric acid Deep etch bath Multimetal plate and plate coating Resins, binders. emul- sion. photosensitizers. gelatin, photoinitiators Developer Alcohols. solvents Resins, solvents, vinyl lacquer, lacquer develop- ers Pigments. dyes, varnish, drie~ extender, modifie~ fountain solutions Acid plating bath Phosphoric acid Ammonium dichromate, ammonium hydroxide Ferric chloride (copper), aluminum/zinc chloride/ hydrochloric acid (chro- mium). nitric acid (zinc. magnesium). gum arabic PYA/ammonium dichro- mate. polyvinyl cinna- mate, fish glue/albumin. silver halide/gelatin emulsion, gum arabic/ ammonium dichromate Lactic acid. zinc chloride, magnesium chloride. hy- droquinone Ethyl alcohol, benzene, toluene, xylene, isopropyl alcohol. methyl ethyl ke- tone, trichloroethylene, perchlorocthylene, carbon tetrachloride, gasoline. naphtha, kerosene PVC, PYA, maleic acid, methyl ethyl ketone, cy- clohexanone. isophorone Titanium oxide, iron blues. molybdated chrome orange, phthalo- cyanine pigments. oils, hydrocarbon solvents, waxes, cobalt/zinc/man- ganese oleates, plasticiz- ers, barium-based pig- ments Copper. chromic acid, chrome STENCIL PREPARATION FOR SCREEN PRINTING Lacquer stencil film Solvents, polyester film, Aliphatic acetates, vinyl film. dyes cellulose-based lacquer, plasticizers Photographic stencil film Photoemulsion Blackout (screen filler) Organic acids, gelatin (pigmented), polyester film base Resins, binders, photo- sensitizers. dyes Pigmented polymers, sol- vents. acetates Acids, alkalis, peroxide forming compounds. plasticizers. surfactants PYA. PVAC, ammonium or potassium bichromate. diazonium compounds Methylene chloride, methanol, methyl cellu- lose acetates Acid/alkaline waste Acid/alkaline waste, heavy metals, waste etch bath Waste etch bath. acid/ alkaline waste, heavy metal wastes Photographic waste Photographic waste Spent solvents Spent solvents Waste ink with solventsi chromiu mt lead/ bariu m, ink sludges with chrom- ium/lead/barium Spent plating waste Spent solvents Hydrogen peroxide Photographic waste .Older technologies Spent solvents Table 2 notes: 'These descriplions may change given variations in wasle characteristics and condilions. 2-frade names will differ among manufacturers. Check Material Safety Data Sheets for the presence of the following chemicals. Jrhe difference between the combustible and flammable liquid hazard class designations is based on the flash point of the material (flammable O-loooF' combustible lOO-2000F). The flash point will depend in large part on the solvents in the waste. "Not Otherwise Specified. L2 Table 2 WASTE DESCRIPTIONS1 DESIGNATION/ DOT TRADE NAMES2 SHIPPING NAME WASTE TYPE HAZARD CLASS UN/NA ID NUMBER ORM-E PHOTOGRAPHIC WASTES Heavy Metal Solutions Photographic processing waste containing heavy metals Trichloroethylene Trichloroethylene. Trichloro- ethene, Ethinyltrichloride, Tri- Clcnc, Trielcnc. Tri SPENT SOUfENTS Carbon Thtrachloride Carbon tetrachloride, Perchloro- methane, Necatorina, Benzino- form, CCl4 Ethanol Ethanol, Ethyl alcohol Isopropanol Isopropanol, Isopropyl alcohol Ethyl Benzene Ethyl benzene l,l,l-Trichloroethane I I I-Trichloroethane, Aerothane TT. Chlorten, lnhibisol. Trichlor- oethane, Chlorothen NU. NCI-C04626, MClhylchloroform. Chlorothene VG, Chlorothane NU, Chlorotene Methylene Chloride Dichloromethane, Methane di- chloride, Mcthylene bichloride. NCl-CSOI02, Methylene dichlo- ride, Solaesth i n, Aerothene N M, Narkotil. Solmethine WASTE INK WITH SOUfENTS OR HEAVY METALS Waste Ink Various Constituent Solvents: Carbon tetrachloride. Chloro- form. Methylene chloridc. I I I-Trichloroethane, 1,2-Dichloroethane, Benzene, Toluene. Ethyl benzene, Tetra- chloroethylene. Trichloroethylene Various Constituents from Pig- ments: Chromium, Coppe~ Lead, Zinc. Cyanide. Aluminum, Cad- mium. Nickcl. Cobalt STRONG ACID/ALKALINE WASTES Ammonium hydroxide Ammonium hydroxide, Aqua Ammonia, Spirit of Hartshorn, NH.OH Hydrochloric Acid Hydrochloric acid, Muriatic acid, HCl Nitric Acid Nitric acid. Aquafortis. HNO, Phosphoric Acid Phosphoric acid, Orthophosphoric acid, H,PO. Sodium Hydroxide Sodium hydroxide. Caustic Soda, Soda Lye. Sodium hydrate. NaOH Sulfuric Acid Sulfuric acid, Oil of Vitriol. H2S0. Chromic Acid Chromic acid SPENT PLATING WASTES Spent Plating Wastes Spent etch baths, spent plating so- lutions and sludges. stripping and cleaning baths INK SLUDGE WITH CHROMIUM OR LEAD Ink sludge with Chro- Ink sludge containing heavy mium or Lead metals IGNITABLE WASTES NOS Ignitable Wastes NOS Ignitable Wastes NOS Hazarduus Waste Solution cun- taining Cadmium. Chromium, Lead, and/or Cyanide NA9189 Waste Trichloroethylene ORM-A UNI710 Waste Carbon Tetrachloride ORM-A UNI846 Waste Ethyl Alcohol Flammable Liquid UNl170 Waste Isopropanol Flammable Liquid UNl219 Waste Ethyl Benzene Flammable Liquid UNI175 Waste I I I-Trichloroethane ORM-A UN2831 Waste Dichloromethanc or Meth- ylcnc Chloride UNI593 ORM-A Waste Ink UN2867 Combustible Liquid' Flammable Liquid UNl210 Waste Ammonium Hydroxide Corrosive Material NA2672 (containing not less than 12%. but not more than 44% ammonia) (containing less than 12% amrno- ORM-A NA2672 nia) Waste Hydrochloric Acid Mixture Corrosi ve Material NAI789 Waste Nitric Acid (over 40%) Oxidizer UN2031 (40% or less) Corrosive Material NAI760 Waste Phosphoric Acid Corrosive Malerial UNl805 Waste Sodium Hydroxide Solu- Corrosive Material UNI824 tion Dry Sol id. Flake, Bead, or Corrosive Material UNI823 Granular Waste Sulfuric Acid. Spent Corrosive Material UNl832 Waste Chromic Acid Solution Corrosive Material UNI755 Hazardous Waste. Liquid or ORM-E NA9189 Solid, NOS. Hazardous Waste, Liquid or Solid. NOS ORM-E NA9189 Waste Flammable Liquid, NOS Wasle Combustible Liquid. NOS Flammable Liquid Combustible Liquid Flammable Solid UNl993 UNI993 Waste Flammable Solid. NOS UNl325 L3 Laboratories INDUSTRY OVERVIEW Laboratories that use chemicals arc likely to generate hazardous waste. These laboratories include: ~ Research and Development laboratories. such as government labs (e.g., National Institutes of Health, Food and Drug Administration) and industrial labs (e.g. chemicals. pharmaceuticals). ~ Commercial Testing Laboratories, including labs that analyze hazardous waste samples. ~ academic Laboratories, such as university and high school labs, and labs of educational or scientific organizations. ~ Medical laboratories, including hospital and dental labs. HAZARDOUS WASTES FROM LABORATORIES The variety of wastes generated by laboratories is too great to specifically identify each of the possible wastes. Instead, the following discussion identifies the general sources of laboratory waste, describes the characteristics of hazardous waste, and provides examples of specific wastes potentially generated by laboratories. The following wastes are commonly generated by laboratories: ~ Spent solvents used in cleaning. extraction. or other processes. ~ Unused reagents that are no longer needed or that do not meet specifications, are contaminated. have exceeded their storage life, or are otherwise unusable in the lab. ~ Reacllon products, which may be of either known or unknown composition, often produced by research and academic labs. (To facilitate disposal, labs should try to identify or characterize reaction products to the extent possible. and label them with this information.) ~ Testing samples that are not entirely consumed by the test procedure. ~ Contaminated materials, such as glassware, paper, and plastic products. Spent solvents and unused reagents generally constitute the majority of laboratory wastes. Chemical wastes generated by laboratories are likely to be hazardous. EPA regulations define wastes that exhibit any of the following characteristics as hazardous: ~ Ignltablllty. Ignitable wastes include liquids with a flash point of less than 1400P solids that ignite spontaneously through absorption of moisture or through friction and burn vigorously' flammable gases; and oxidizers. ~ Corroslvlly. Corrosive wastes include aqueous solutions with a pH less than or equal to 2 or greater than or equal to 12.5, and liquids that corrode steel at a rate of greater than 0.25 inch per year. ~ Reactivity. Reactive wastes include substances that are unstable and readily undergo violent change; react violently with water' form potentially explosive mixtures with water are capable of detonation or explosive reaction when exposed to a strong initiating source; or generate significant quantities of tOXIC gases when exposed to water or, in the case of cyanide or sulfide bearing wastes, pH conditions between 2 and 12.5. ~ EP Toxicity. Wastes are EP toxic if an extract from the waste contains more than the concentrations of arsenic, barium. cadmium, chromium, lead. mercury, selenium, silver, endrin, lindane, methoxychlor, toxaphene. 2,4-D. or 2.4.5-TP specified in RCRA regulations. EPA also regulates additional wastes which are specifically listed in regulations because of one or more of the above characteristics or because of thc following criteria: ~ Acute hazard. Wastes are acutely hazardous if they are fatal to humans in low doses, are capable of contributing to serious irreversible or incapacitating reversible illness, or have been shown to have an oral LD50 (rat) of less than 50 mg/kg, an inhalation LCso (rat) of less than 2 mg/l. or a dermal LDso (rabbit) of less than 200 mg/kg. ~ TOXIClly. Wastes are generally considered to be toxic if they contain any of a number of listed toxic constituents. Because of the great variety of wastes generated by laboratories, it is advisable to consult the RCRA regulations found in the Code of Federal Regulations, Title 40, Part 261 to determine whether a waste is hazardous. If you generate between 220 and 2,200 pounds of hazardous waste per calendar month, you are subject to new small quantity generator provisions requiring the use of a Uniform Hazardous Waste Manifest when you ship hazardous wastes off your premises. Item 11 of the Manifest requires the Department of Transportation (DOT) shipping description. which includes the proper DOT shipping name. hazard class. and UN/NA identification number. The following table provides some examples of typical laboratory wastes and their DOT descriptions. In the case of waste mixtures, general waste classifications [e.g. Flammable Liquid, Not Otherwise Specified (NOS)] may be appropriate. Some of these general classifications are included in the table as well. Where the shipping name of a mixture or solution does not identify the constituents making it hazardous, the name(s) of the hazardous constituents should be included in parentheses after the shipping name. Radioactive wastes, generated by some labs. are generally regulated under the Atomic Energy Act and therefore excluded from regulation under RCRA. Nuclear Regulatory Commission and DOT regulations, however, may apply' contact the Nuclear Regulatory Commission. the DOT Materials Transport Bureau, or your state transportation agency for more information concerning proper transport and disposal of these wastes. If you are not sure whether your wastes are hazardous or if you need gUidance on determining the proper DOT description. please contact your state hazardous waste management agency, EPA Regional Office, or trade association for assistance. WASTE IISPOSAL METHODS Most laboratories dispose of wastes off-site in an authorized hazardous waste landfill. Because laboratories often generate small quantities of a number of hazardous wastes, these wastes are frequently sent to landfills in 'lab-packs. which consist of individual containers packed in vermiculite in a 55-gallon drum. Other waste management options include: ~ Waste reduction. or minimizing the amount of waste that must be treated or disposed o( ~ Thermal treatment in a high-temperature incinerator. ~ Chemical, physical. or biological treatment (e.g.. solidification, neutralization. ion exchange, OXidation. or precipitation). ~ Waste recovery, recycling, or reuse. From an environmental perspective. waste reduction. recovery. or destruction is generally preferable to land disposal. Ml Table 1 WASTE DESCRIPTIONS1 WASTE DOT SHIPPING NAME HAZARD UN/NA CLASS ID NUMBER Flammat>le Liquid UNI090 Flammable Liquid UNII14 ORM-A UNl888 Flammable Liquid UN1l65 SOUfENTS Acetone Waslc Acetone Benzene Waste Benzene Chloroform Trichloromethane Waste Chloroform l,4-Dioxane Diethylene Ether I 4-Diethylene Oxide Diethylene Oxide Dioxyethylene Ether Waste Dioxane Ethanol Ethyl Alcohol Grain Alcohol Waste Ethyl Alcohol Flammable Liquid UNl170 Ethyl Ether Ether Diethyl Ether Diethyl Oxide Waste Ethyl Ether Flammable Liquid UNl155 Formalin Formaldehyde Solution (I) flash point greater than l410F Waste Formaldehyde Solution ORM-A (or Com- bustible Liquid if shipped in contain- ers larger than 110 gallons) UN2209 (2) flash point less than or equal to 1410F Waste Formaldehyde Solution ORM-A (or Com- bustible Liquid if shipped in contain- ers larger than 110 gallons) UNI198 Hexane n-Hexane Waste Hexane Flammable Liquid UN 1208 Isopropanol Isopropyl Alcohol TPA Dimethyl Carbinol 2-Propanol Waste Isopropanol Flammable Liquid VN12l9 Methanol Methyl Alcohol Wood Alcohol Waste Methyl Alcohol Flammable Liquid UNl230 Waste Methyl Ethyl Ketone Flammable Liquid UNl193 Waste Dichloromethane (or Waste Mcthylenc Chloride) ORM-A UNl593 Waste Pentane Flammable Liquid UNI265 Waste Petroleum Ether Flammable Liquid UNI271 Waste Tetrahydrofuran Flammable Liquid UN2056 Waste Toluene Flammable Liquid UNl294 Waste Xylene Flammable Liquid UNl307 Waste Carbon Tetrachloride ORM-A UNI846 Methyl Ethyl Ketone MEK 2-Butanone Methylene Chloride Dichloromethane Pentane Petroleum Ether Tetrahydrofuran THF Thluene Toluol Methyl Benzene Xylene Xylol Dimethyl Benzene Carbon Tetrachloride Carbon Tet Tetrachloromethane Perchloromethane Ignitable Liquids Waste Flammable Liquids. NOS Waste Combustible Liquids. NOS Flammable Liquid' Combustible Liquid' UNI993 NAI993 'These descriptions may change given variations in waste characteristics, conditions or process modifications. 2Substanees with a flash point less than loooF are classified as 'Flammable Liquid" substances with a flash point greater than or equal to loooF and less than 2000F are classified as 'Combustible Liquid. M2 Table 1 (Continued) WASTE DESCRIPTIONS WASTE DOT SHIPPING NAME HAZARD UN/NA CLASS ID NUMBER Corrosive Material UN2789 Corrosive Material UN2790 Corrosive Material UNl789 Oxidizer UN2031 Corrosive Material NAI760 Oxidizer UN2032 Oxidizer UN1802 Oxidizer UN1873 Forbidden' Corrosive Material UNI830 Corrosive Material UN1832 Corrosive Material NAl831 ORM-A NA2672 Corrosive Material NA2672 Corrosive Material UNI813 Corrosive Material UNI814 Corrosive Material UN1823 Corrosive Material UN1824 Corrosive Material UNI760 Corrosive Material UNI759 Oxidizer NA9193 Oxidizer NA9194 Ox id izer UNi479 Poison B UN2810 Poison B UN28 II Corrosive Material UN2922 Poison B UN2928 Oxidizer NA9l99 Oxidizer NA9200 ORM-E NA9189 ORM-E NA9l89 ACIDS/BASES Acetic Acid Waste Acetic Acid, Glacial Waste Acetic Acid, Solution Hydrochloric Acid Waste Hydrochloric Acid Nitric Acid Waste Nitric Acid, over 40% Waste Nitric Acid. 40% or less Waste Nitric Acid, Fuming Perchloric Acid Waste Perchloric Acid, not over 50% acid Waste Perchloric Acid, exceeding 50% but not exceeding 72% acid Waste Perchloric Acid, exceeding 72% acid Sulfuric Acid Waste Sulfuric Acid, Waste Sulfuric Acid, Spent Oleum Fuming Sulfuric Acid Waste Oleum Ammonium Hydroxide Ammonia Solution Aqueous Ammonia Waste Ammonium Hydroxide. containing less than 12% ammonia Waste Ammonium Hydroxidc. containing not less than 12% but not more than 44% ammonia Potassium Hydroxide Caustic Potash Waste Potassium Hydroxide, Solid Waste Potassium Hydroxide, Liquid Sodium Hydroxide Caustic Soda Lye Waste Sodium Hydroxide, Solid Waste Sodium Hydroxide, Liquid NON.SPECIFIC WASTES Corrosive Liquids Waste Corrosive Liquids. NOS Corrosive Solids Waste Corrosive Solid, NOS Oxidizer, Corrosive, Liquid Waste OxidIzer. Corrosive. Liquid, NOS Oxidizer, Corrosive, Solid Waste Oxidizer, Corrosive. Solid. NOS Oxidizer Waste Oxidizer. NOS Poisonous Liquid" Waste Poison B. Liquid, NOS Poisonous Solid Waste Poison B. Solid, NOS Corrosive, Poisonous Liquid Waste Corrosive Liquid, Poisonous. NOS Poisonous, Corrosive Solid Waste Poisonous Solid. Corrosive, NOS Poisonous, Oxidizing Liquid Waste Oxidizer, Poisonous. Liquid, NOS Poisonous, Oxidizing Solid Waste Oxidizer. Poisonous, Solid. NOS Hazardous Waste Hazardous Waste, Liquid, NOS Hazardous Waste5 Hazardous Waste, Solid, NOS 'Forbidden materials are prohibited from being offered or accepted for transportation. 'Certain gases and volatile liquids (e.g., cyanogen, phosgene) are classed as Poison A. If classed as Poison A, the gases and liquids have a different UN/NA 10: NA 1953 for poisonous liquid or gas, flammable, NOS. or NA 1955 for poisonous liquid or gas, NOS. 5Materials (e.g., disposable labware) contaminated with small quantities of a variety of hazardous substanceS can generally be classified as Hazardous Waste, NOS, unless a more specific DOT shipping name applies. The entire weight of the contaminated material, not just the weight of the substance(s) making it hazardous, is considered when determining quantity. M3 Educational and Vocational Shops Educational and vocational institutions may include shops conducting: ~ Automotive and small engine repair ~ Automobile body repair ~ Metalworking ~ Graphic arts production (e.g.. printing. photography) ~ Woodworking. Wastes generated from laboratories are not addressed in this discussion; a separate pamphlet on laboratory wastes is available. HAZARDOUS WASTE FROM EDUCATIONAL AND VOCATIONAL SHOPS The majority of hazardous wastes from educational and vocational shops are: ~ Solvents (e.g., paint removers, thinners, and cleaning solvents) ~ Paint wastes ~ Strong acid or alkaline solutions (e.g.. cleaning solutions). Automobile body repair and woodworking operations generate waste solvents and paints. The solvents may be flammable or toxic, and paints may contain heavy metal pigments as well as hazardous solvents. Graphic arts production may generate several types of wastes, depending on the activities. Printing wastes include strong acid solutions used to clean, etch. and coat plates, and solvents used to clean plates, to apply light-sensitive coatings, and to develop plates. The use of inks generates wastes containing solvents and/or heavy metals. Photographic wastes include processing solutions, developers. hardeners, and fixing baths. Metalworking and automotive repair generate waste solvents and acid or alkaline solutions used to clean metal and remove rust. Table I lists some typical shop operations and processes that may produce hazardous waste. lf you produce between 220 and 2,200 pounds of hazardous waste per calendar month, you are subject to new small quantity generator provisions requiring the use of a Uniform Hazardous Waste Manifest when you ship hazardous waste off your premises. Item II of the Manifest requires the Department of Transportation (DOT) shipping name, hazard class, and UN/NA identification number for each waste. This information is provided in Table 2 for a number of hazardous wastes potentially generated by educational and vocational shops. To obtain the DOT shipping name, hazard class, and UN/NA identification number, select the typical process/ operation from column I of Table I and match the ingredients from column 3 and the waste type from column 4 of Table I with the substances listed in Table 2. FOR MORE INFORMATION If you are not sure whether your wastes are hazardous or if you need guidance on determining the proper DOT shipping description. please contact your state hazardous waste management agency or EPA Regional Office for assistance. Table 1 TYPICAL OPERATIONS USING MATERIALS WHICH MAY GENERATE HAZARDOUS WASTES TYPICAL PROCESS/ OPERATION TYPICAL MATERIAL INGREDIENTS ON LABEL GENERAL TYPES OF WASTES GENERATED TYPICAL MATERIALS USED AUTOMOBILE ENGINE AND BODY REPAIR, METALWORKING Oil and grease removal; solvents, varsol, carbure petroleum distillates, aro- metal/tool cleaning; en- tor cleaners, degreasers, matic hydrocarbons. min- gine, parts and equip- cleaning fluids, acids/al- eral spirits. benzene. tolu- ment cleaning kalies. engine cleaners ene, petroleum naphtha Rust removal naval jelly, strong acid/ alkaline solutions phosphoric acid, hydro- chloric acid, hydrofluoric acid. sodium hydroxide Painting enamels, lacquers, epoxys, alkyds, acrylics, primers acetone, toluene, petro- leum distillates, epoxy ester resins. methylene chloride, xylene, VM&P naphtha. aromatic hydro- carbons. methyl isobutyl ketones Spray booth, spray guns. hrush cleaning; paint re- moval/paint preparation solvents, paint thinners, enamel reducers. wh ite spirits acetone, toluene, petro- leum distillates, metha- nol. methylene chloride, isopropanol, mineral spir its, alcohols, ketones, other oxygenated solvents Used lead acid batteries (excluding those sent for recycling) car. truck, boat, motor cycle, and other vehicle balleries lead dross, less than 3% free acids See Tables I and 2 inside ign it able wastes, spent solvents, combustible solids, waste acid/alka- line solutions waste acid/alkaline solutions ignitable paint wastes, spent solvents, paint wastes with heavy met- als, ignitable wastes ignitable paint wastes, heavy metal paint wastes. spent solvents lead acid ball eries, strong acid/alkaline solutions Nl TYPICAL PROCESS/ OPERATION Table 1 (Contmued) TYPICAL OPERATIONS USING MATERIALS WHICH MAY GENERATE HAZARDOUS WASTES TYPICAL TYPICAL MATERIAL MATERIALS USED INGREDIENTS ON LABEL GENERAL TYPES OF WASTES GENERATED GRAPHIC ARTS Plate preparation Counter-etch to remove phosphoric acid phosphoric acid acid/alkaline waste oxide Deep-etch coating of deep etch bath ammonium dichro- acid/alkaline waste. plates mate, ammonium hy- heavy metal solutions, drox ide waste etch bath Etch baths etch baths for plates ferric ch loride (cop- waste etch bath, per). aluminum chlo- acid/alkaline waste. ride/zinc chloride/ heavy metals hydrochloric acid (chromium), nitric acid (zinc, magnesium) Apply light sensitive resins. binders, emul- PYA/ammonium di- photographic waste coating sion, photosensitizers, chromate, polyvinyl gelatin, photoinitiators cinnamate, fish glue/albumin. silver halide/gelatin emul- sion, gum arabic/ ammonium dichromate Develop plates developer lactic acid, zinc photographic waste chloride, magnesium chloride Wash/clean plates alcohols, solvents ethyl alcohol, isopropyl spent solven!s alcohol, methyl ethyl ketone, trichloroethy- lene, perchloroethylene Apply lacquer resins, solvents, vinyl PVC, PYA. maleic spent solvents lacquer acid, methyl ethyl ketone Ink pigments, dyes, var- titanium oxide, iron waste ink with sol- nish, drier, extende~ blues, molybdated vents/heavy metals, modi fier chrome orange, phthal- ink sludge with chro- ocyanine pigments, mium/lead oils. hydrocarbon sol- vents. waxes, cobalt! zincimanganesc ole ates, plasticizers Making gravure acid plating bath coppe~ hydrochloric spent plating waste cylinders acid Painting signs/bill- solvents, paint with ethylene dichloride. paint wastes, ignitable boards solvents/heavy metals benzene, toluene, paint wastcs. other ig- ethylbenzene, chloro- nitable wastes benzene, methyl ethyl ketone WOODWORKING Wood cleaning and petroleum distillates. petroleum distillates, ignitable wastes, spent wax removal white spirits mineral spirits solvents Refinishing/stripping; paint removers, varnish acetone, toluene, petro- ignitable wastes. ignit- Brush cleaning and removers, enamel re- leum distillates, min- able paint wastes, sol- spray gun cleaning movers, shellac remov- eral spirits, methanol, vent still bottoms ers, pain! solvents. tur- methylene chloride, al- pentine cohols, ketones, oxy- genated solvents Staining stains mineral spirits. alco- ignitable wastes, spent hols, pigments solvents, solvent still bottoms Painting enamels, lacquers. toluene, pigments, tita- ignitable paint wastes, epoxy. alkyds, acrylics nium dioxide. epoxy- ignitable wastes, sol- ester resins, aromatic vent still bottoms hydrocarbons, glycol ether, halogenated hy- drocarbons. vinyl ace tate acrylic Finishing varnish. shellac. poly- denatured alcohols, ignitable wastes, spent urethane, lacquers resins, shellac, petro- solvents, solvent still leum distillates, tolu- bottoms ene diisocyanate N2 -~----- ---- ------ .~----- Table 2 EDUCATIONAL AND VOCATIONAL SHOPS WASTE DESCRIPTIONS1 DESIGNATION/ DOT HAZARD TRADE NAMES SHIPPING NAME CLASS WASTE TYPE UN'NA ID NUMBER ORM-A UNl846 PHOTOGRAPHIC WASTES Carbon Tetrachloride Carbon Tctrachloridc. Perchloro- methane. Necatorina, Benzino- form, CCL4 Heavy Metal Solutions Photographic processing waste containing heavy metals WaSle Carbon TClrach loridc Hazardous Waste Solution con- taining Cadmium. Chromium, Lead, and/or Cyanide SPENT SOUfENTS (see also ignitable paint wastes containing flammable solvents) Acetone Acetone Waste Acetone Waste Naphtha White Spirits White Spirits, Mineral Spirits. Naphtha Petroleum Distillate Petroleum Distillates Kerosene Kerosene Fuel oil #1 Methylene Chloride Dichloromcthanc. Methane Di- chloride, Methylene Bichloride, NCI-C50102, Solaesthin, Aero- thene, Narkotil. Solmethine Toluene Toluene, Methacide, Methylben- zene, Methylbenzol, Phenyl me- thane, Toluol. Antisal I A Benzene Benzene Ethanol Ethanol, Ethyl Alcohol Xylene Xylene, Xylol Methyl Ethyl Ketone Methyl Ethyl Ketone Tetrahydrofuran Tetrahydrofuran, THF Isopropanol Isopropanol, Isopropyl Alcohol Ethyl Benzene Ethyl Benzene I. I. I-Trichloroethane I I I-Trichlorocthanc. Aerothane TT, Chlorten, Inhibisol, Trichlo- roelhane, Chlorothene NU, NCI-C04626. Melhylchloroform, Chlorothene VG, Chlorothane NU, Chlorotene Trichloroethylene Perm-A-chlor, Trielin, Triline, Trial. Vestrol, Chlorylene, Dow- Tri, Vilran. TeE, Nialk. Philex WASTE INK WITH SOUfENTS OR HEAVY METALS Waste Ink Various Constituent Solvents: Carbon Tetrachloride, Chloro- form. Methylene Chloride. I I I-Trich loroethane, 1,2-Dichloroclhane, Benzene, Toluene. Ethyl Benzene, Tetra- chlorocthylene, Trichlorocthylene Various Constituents from Pig- ments: Chromium. Copper, Lead. Zinc. Cyanide Aluminum, Cad- mium. Nickel, Cobalt INK SLUDGE WITH CHROMIUM OR LEAD Ink sludge with Chro- Ink sludge containing heavy met- mium or Lead als Waste Naphtha, Solvent Waste Naphtha, Solvent Waste Petroleum Distillate Waste Kerosene Waste Dichloromcthane or Meth- ylene Chloride Waste Toluene (Toluol) Waste Benzene (Benzol) Waste Ethyl Alcohol Waste Xyle"e Waste Methyl Ethyl Ketone Waste Telrahydrofuran Waste Isopropanol Waste Ethyl Benzene Waste I I I-Trichloroethane Waste Trichlorocthylene Waste Ink Hazardous Waste, Liquid, NOS" Hazardous Waste, Solid, NOS 'These descriptions may change given variations in waste characteristics and conditions. 2Formulations with flash poinlless than 2000F and greater than or equal to lOooF 'Formulations with flash point less than loooF "Not Otherwise Specified. N3 ORM-E NA9189 Flammable Liquid UNI090 Combustible UN2553 Liquid2 Flammable Liquid' UN2553 Combustible UNI256 Liquid Flammable Liquid UN1256 Combustible UN1268 Liqu id Flammable Liquid UNI268 Combustible UNI223 Liquid ORM-A UNl593 Flammable Liquid UNI294 Flammable Liquid UN 11 14 Flammable Liquid UN 11 70 Flammable Liquid UNl307 Flammable Liquid UNII93 Flammable Liquid UN2056 Flammahle Liquid UNI219 Flammable Liquid UNl175 ORM-A UN2831 ORM-A UNl7lO Combustible Liquid Flammable Liquid UN2867 UNI210 ORM-E ORM-E NA9189 NA9189 Table 2 (Continued) EDUCATIONAL AND VOCATIONAL SHOPS WASTE DESCRIPTIONS DESIGNATION/ DOT HAZARD TRADE NAMES SHIPPING NAME CLASS WASTE TYPE UN/NA ID NUMBER STRONG ACID/ALKALINE WASTES Ammonium Hydroxide Ammonium Hydroxide NH40H, Waste Ammonium Hydroxide Corrosive Malerial NA2672 Spirit of Hartshorn, Aqua Ammo- (containing not less than 12% but nia not more than 44% ammonia) Waste Ammonium Hydroxide ORM-A NA2672 (containing less than 12% ammonia) Hydrobromic Acid Hydrobromic Acid, HBr Waste Hydrobromic Acid Corrosive Material UNI788 Hydrochloric Acid Hydrochloric Acid, HCI. Muriatic Waste Hydrochloric Acid Mixture Corrosive Material NAl789 Acid Hydrofluoric Acid Hydrofluoric Acid, HF, Fluorohy- Waste Hydrofluoric Acid Solution Corrosive Material UNI790 dric Acid Nitric Acid Nitric Acid, HN02. Aquafortis Waste Nitric Acid (over 40%) Ox id izer UN203l Waste Nitric Acid (40% or less) Corrosive Material NAI760 Phosphoric Acid Phosphoric Acid. H3P04 Ortho- Waste Phosphoric Acid Corrosive Material UNl805 phosphoric Acid Potassium Hydroxide Potassium Hydroxide. KOH, Po- Waste Potassium Hydroxide Solu- Corrosive Material UNI8l4 tassium Hydrate, Caustic Potash, lion Potassa Dry Solid, Flake, Bead. or Granu- Corrosive Material UNl813 lar Sodium Hydroxide Sodium Hydroxide, NaOH, Caus- Waste Sodium Hydroxide Solu- Corrosive Material UNl824 tic Soda, Soda Lye, Sodium Hy- lion drate Dry Solid, Flake. Bead, or Granu- Corrosive Material UNl823 lar Sulfuric Acid Sulfuric Acid, H2SO4 Oil of Waste Sulfuric Acid, Spent Corrosive Material UN1832 Vitriol Chromic Acid Chromic Acid Waste Chromic Acid Solution Corrosive Material UN 1755 Lacquer, Paint, or Var- Lacquer, Paint. or Varnish Re- Waste Compound, Lacquer, Paint. Corrosive Material NAI760 n/sh Removing Liquid moving Liquid or Varnish Removing, Liquid SPENT PLATING WASTES Spent Plating Wastes Spent etch baths, spent plating so- lutions and sludges, Slripping and cleaning baths Hazardous Waste, Liquid, NOS Hazardous Waste, Sol id, NOS ORM-E ORM-E IGNITABLE PAINT WASTES CONTAINING FLAMMABLE SOUfENTS (see also spent solvents) Ethylene Dichloride Ethylene Dichloride, Waste Ethylene Dichloride Flammable Liquid 1.2-Dichloroethane Chlorobenzcne Ch lornbcnzcnc. Mnnoch Inrnhcn- zene, Phenyl Chloride Methyl Ethyl Ketone Methyl Ethyl Ketonc, Melhyl Ac elOne. Meetco. Butanone. Ethyl Methyl Ketone, MEK. 2-Butanone Paint Dryer Paint Dryer Paint, Enamel, Lacquer, Stain, Shellac, or Va.... nish; Aluminum, Bronze, Gold, Wood Filler, Liq- uid or Lacquer Base, Liquid Paint, Enamel, Lacquer, Stain, Shellac, or Varnish; Aluminum, Bronze, Gold. Wood Fille~ liq- uid or Lacquer Base, Liquid Enamel Enamel Lacquer, Paint, or Va.... nish Removing, Reduc lng, or Thinning, Liquid Lacque~ Paint, or Varnish Re moving, Reducing, or Thinning. Liquid PAINT WASTE WITH HEAVY METALS Paint Waste Paint Waste with Heavy Metals Wasle Chloronclllcnc Waqc MClhyl Elhyl KClonc Waste Paint Dryer. Liquid Waste Paint. Enamel. Lacquer. Stain, Shellac, or Varnish; Alu- minum, Bronze. Gold. Wood Filler. Liquid or Lacquer Base. Liqu id Waste Compound. Enamel Waste Compound, Lacquer. Paint, or Varnish. Removing, Reducing, or Thinning. Liquid Hazardous Waste. Liquid, NOS Hazardous Waste, Solid, NOS IGNITABLE WASTES NOT OTHERWISE SPECIFIED (NOS) Ignitable Wastes NOS Ignitable Wastes NOS Waste Flammable Liquid, NOS Waste Combustible Liquid, NOS Waste Flammable Solid, NOS f'lammahlc l.iquid Flammahle Liquid Combustible Liquid Flammable Liquid Combustible Liquid Flammable Liquid Flammable Liquid Combustible Liquid Flammable Liquid ORM-E ORM-E Flammable Liquid Combuslible Liquid Flammable Solid NA9l89 NA9189 UN1I84 UNII14 UNI191 UN 1168 UNl168 UNI263 UNl263 NA 1263 NAI142 NA1I42 NA9l89 NA9l89 UN1993 NAl993 UN 1325 N4 Metal Manufacturing INDUSTRY OVERVIEW Your business is classified under Metal Manufacturing if you manufacture: ~ Metal furniture, shelves, lockers, cabinets and fixtures ~ Primary metal products ~ Fabricated metal products ~ Machinery, including electrical and electronic machinery. equipment and supplies ~ Storage or primary batteries ~ Motor vehicle parts and accessories ~ Measuring. analyzing. or controlling instruments (for example. photographic, medical or optical equipment) ~ Clocks and watches ~ Costume and precious metal jewelry ~ Needles, pins. and similar notions ~ Signs and advertising displays ~ Burial caskets ~ Silverware or stainless steel flatware. Metal Manufacturing also includes plants which are involved in metalworking activities such as: ~ Rolling, drawing, and extruding of non-ferrous metals ~ Heat treating ~ Coating, engraving, and allied services. Most metal manufacturing operations produce some hazardous waste. If you use any combustible or flammable solvents, strong acid or alkaline solutions, plating solutions, paints, cyanide solutions, or any solutions containing heavy metals. it is likely that your operation generates hazardous waste. If you produce 220 pounds (about half of a 55-gallon drum) or more of hazardous waste per month, you may be subject to new Resource Conservation and Recovery Act (RCRA) requirements, including the use of a Uniform Hazardous Waste Manifest to accompany hazardous wastes you ship off your plant site. Item lion the Manifest requires the Department of Transportation (DOT) description of the waste, including the proper shipping name, hazard class and UN/NA identification number. This information is provided for some of the wastes you may produce in Table I If you have any questions about your wastes or responsibilities for their disposal. contact your state hazardous waste management agency or EPA regional office. HAZARDOUS WASTES FROM METAL MANUFACTURING Businesses classified under Metal Manufacturing perform many different processes, including machining, grinding, buffing. polishing. tumbling, sand casting. forming. rolling, extruding, forging, ironing. lettering, enameling, cleaning, welding, finishing, die sinking. pickling, coining, degreasing, electrogalvanizing, electroplating, and painting. The wastes associated with these processes fall into roughly seven major categories: ~ SPent Solvents and Solvent Stili Bonoms in general result from solvents used in most cleaning and degreasing operations. The types of solvents used may include chlorinated solvents (for example, methylene chloride, dichlorobenzene, carbon tetrachloride, trichloroethylene) or non-halogenated solvents (acetone. xylene, toluene, benzene). Other solvents may be kerosene or mineral spirits ("Stoddard" Solvents). 01 ~ Strong acid Wastes are generated in considerable quantity wherever any type of metal is formed or processed. Many pickling solutions are highly acidic and as a result, acid may be carried to subsequent manufacturing operations if it is not neutralized. These may include drawing, rolling. pressing, electroplating, hot dip galvanizing or hot tinning, anodizing. phosphating, metal coloring and many more. ~ Strong Alkaline Wastes are generated from the use of pickled aluminum and sometimes zinc. ~ Plating Wastes are generated from electroplating operations. These wastes may be acidic or alkaline and contain appreciable concentrations of heavy metals. Acid plating solutions generally contain free acids and heavy metals such as copper, nickel, zinc and possibly tin or cadmium. Alkaline plating solutions include zinc baths and sometimes tin baths. The waste products from plating may include spent plating solutions or sludges. and stripping and cleaning bath solutions. ~ Heavy Metal Wastewater Sludges are generated from wastewater treatment. Depending on your operation, these sludges may contam arsenic. barium. chromIum, cadmium, lead. mercury, silver, or selenium. High concentrations of lead are found in the sludges from battery manufacturing plants. Other sludges may come from grinding. tank clean-outs, dust collectors, and lead pots. ~ Paint Wastes with Heavy Metals are generated by paint booths used in the sign and advertising display industry. Generally, the waste is an organic sludge that contains cadmium. chromium, lead, and/or mercury. ~ Cyanide Wastes are generated from cyanide plating solutions and simple cyanide solutions. Cyanide plating solutions are used in metal plating operations. Simple cyanide solutions are used mainly for hardening and metal cleaning. Cyanide baths are commonly used in metal finishing and heat treating operations. ~ Ignitable Wastes include any flammable or combustible liquid or combustible solid. not elsewhere classified. According to DOT definition. flammable materials have a flash point of less than IOOoF while combustible materials have flash points of between 100 and 2000F Ignitable wastes, however, are defined by EPA as hazardous only if they have flashpoints of less than 1400F ~ OIlIer Reactive Wastes are generated primarily by the photographic equipment and supplies industry. although other metal manufacturing industries may also generate reactive wastes. Specific wastes may include strong oxidizing agents such as chromic acid, perchlorates, and permanganates used in metal finishing. and other reactive compounds such as hypochlorites, peroxides, sulfides, nitrates, and sodium hydroxide. In addition to these wastes, all or most of the operations in the metal manufacturing industry will generate used oil. Oils may come from cutting, lubricating, and/or quenching. Currently, most used oil is exempt from EPA hazardous waste regulations. Some states, however. currently have rules which apply to used oil and EPA is now in the process of developing new regulations for used oil. Most metal manufacturers generate scrap metal. At present, any metal that is destined for reclamation is not regulated by EPA. Questions concerning used oils, scrap metal and other wastes should be referred to your state hazardous waste management agency or EPA regional office. Table I lists the wastes generated by many metal manufacturing industries, and provides DOT shipping descriptions. This list is not comprehensive. Your facility may produce only some of these wastes or generate other wastes that have inadvertently been excluded. Table I METAL MANUFACTURING WASTE DESCRIPTIONS1 DESIGNATIONS/ DOT HAZARD UN/NA WASTE TYPE TRADE NAMES SHIPPING NAME CLASS ID NUMBER SPENT SOUlENTS AND SOUlENT STILL BOTTOMS Thtrachlorocthylene Perchloroethylene, Perc, Tetralex, Waste Tetrachloroethylene or ORM-A UNI897 Perawin, Perclene, Terlen, Dida- Perchloroethylene kene, TetraCap, Antisal I, Fedad-UN, Neme Gemalgene, Perm-A-Clo~ TeE, Benzinol, Dow-Tri. Nialk. Vestrol, Triclin Trichloroethylene Tri-Clene, Trielene, Tri Waste Trichloroethylene ORM-A UNI7IO Methylene Chloride Aerothene MM, Narkotil Waste Dichloromethane or Meth- ORM-A UNI593 ylene Chloride l,l,l-Trichloroethane Aerothane IT, Chlorten, Inhibi- Waste 1,I.l-Trichloroethane ORM-A UN2831 sol, Chlorothen NU, Alpha-T Carbon Thtrachloride Perchloromethane. Tetraform, Waste Carbon Tetrachloride ORM-A UNI846 Carbona, Halon 104 Trichlorotr/nuoro- Fluorocarbon 113, Freon 113, Hazardous Waste, Liquid, NOS2 ORM-E NA9l89 ethane Ucon 113, Freon TF, Frigen 113 113TR-T, Arcton 63 Trichlorotrifiuoro- Eskimon 11. Ucon II, Isotron 11, Hazardous Wasle, Liqu id. NOS ORM-E NA9189 methane Freon 11, Freon MF, Fluoro- chloroform, Arcton 9 Thluene Toluol, Methercid, Methyl Ben- Waste Toluene (toluol) Flammable LiquidJ UNI294 zene, Methylbenzol, Phenyl- methane, Antisol lA Methyl Ethyl Ketone Methyl Ethyl Ketone, MEK, Waste Methyl Ethyl Ketone Flammable Liquid UNl193 Methyl Acetone, Meetco, Buta- none, Ethyl Methyl Ketone Benzene Benzene Waste Benzene (benzol) Flammable Liquid UNII14 Chloroform Chloroform Waste Chloroform ORM-A UNI888 Dichlorobenzene o-Dichlorobenzene Waste Dichlorobenzene, Ortho, ORM-A UNl591 Liquid Acetone Acetone Waste Acetone Flammable Liquid UNlO9O Xylene Xylene, Xylol Waste Xylene (xylol) Flammable Liquid UNI307 White Spirits Mineral Spirits, Naphtha, Stod- Waste Naphtha Flammable Liquid UN2553 dard Sol vent Kerosene Kerosene. Fuel Oil #1 Waste Kerosene Combustible Liquid' UNI223 Butyl Alcohol n-Butyl Alcohol, see-Butyl Alco- Waste Butyl Alcohol Flammable Liquid NAIl20 hol, tert-Butyl Alcobol STRONG ACID/ALKALINE WASTES Ammonium Hydroxide Ammonium Hydroxide, NH4OH, Waste Ammonium Hydroxide Corrosive Material NA2672 Spirit of Hartshorn, Aqua Ammo- (containing not less than 12% but nia not more than 44% ammonia) (containing less lhan 12% ORM-A NA2672 ammonia) Hydrobromic Acid Hydrobromic Acid, HBr Waste Hydrobromic Acid Corrosive Material UNl788 Hydrochloric Acid Hydrochloric Acid, HCl. Muriatic Waste Hydrochloric Acid Corrosive Material NAl789 Acid Hydrofluoric Acid Hydrofluoric Acid, HF, Fluoro- Waste Hydrofluoric Acid Corrosive Material UN 1790 hydric Acid Nitric Acid Nitric Acid, HN02. Waste Nitric Acid (over 40% Ox id izer UN203l Aquafortis nitric acid) (40% or less nitric acid) Corrosive Material NAI760 Phosphoric Acid Phosphoric Acid, HJPO" Waste Phosphoric Acid Corrosive Material UNl805 Orthophosphoric Acid Potassium Hydroxide Potassium Hydroxide, KOH, Po- Waste Potassium Hydroxide Solu- Corrosive Material UNI8l4 tassium Hydrate. Caustic Potash, tion Potassa Dry Solid. Flake, Bead, or Corrosive Material UNI813 Granular 02 ---~- ------------------------_.-.- --.----- Table 1 (continued) METAL MANUFACTURING WASTE DESCRIPTIONS' DESIGNATIONS/ DOT TRADE NAMES SHIPPING NAME r WASTE TYPE Sodium Hydroxide Sodium Hydroxidc. NaOH. Causlic Soda. Soda Lye. Sodium Hydrate Sulfuric Acid Sulfuric Acid. H,S04' Oil of Vitriol Perchloric Acid Perchloric Acid Acetic Acid Acetic Acid Nitrates Nitrate SPENT PLATING WASTES Spent Plating Wastes Spent Acid. Alkaline and Cya- nide Plating Solutions and Sludges HEAVY METAL WASTEWATER SLUDGES Heavy Metal Wastewater Sludges from wastewater treat- Sludges ment. grinding, tank clean OUlS, dUSl collectors. and lead pots CYANIDE WASTE Cyanide Waste Spent Cyanide, Hardening and cleaning solutions. Sludge from quench and wash tank IGNITABLE WASTES Ignitable Wastes NOS Ignitable Wastes NOS OTHER REACTIVE WASTES Acetyl Chloride Acetyl Chloride Chromic Acid Chromic Acid Hypochlorites Hypoch lorous Acid. Eau de Labarraque. Clorox, Dazzle Organic Peroxides Organic Peroxide Perchlorates Sodium or Potassium Perchlorate. lrenat, Periodin, Perchlorocap Permanganates Sodium or Potassium Permanga- nale. Permanganic Acid, Chame leon Mineral Sulfides Sodium or Potassium Sulfide, So- dium or Potassium Monosulfide, Sodium Sulfuret USED OILS Used Oil Dodge Combo MP8. Texaco Cleartex-D, Mobil Omicron. Shell Tel1us, Welbube A-3D7, Eppert 204, Sunvis 931, Solcne, Mobilmet Omieron Waste Sodium Hydroxide Solution Dry Solid. Flake. Bead. or Granular Waste Sulfuric Acid. Spent Waste Perchloric Acid (50%-72%) (50%) Waste Acetic Acid (Aqueous Solution) Waste Nitrate, NOS Hazardous Waste. Liquid or Solid, NOS Hazardous Waste. Liquid or Solid, NOS Waste Cyanide Solulion, NOS Waste Cyanide Mixlure, Dry Waste Flammable Liquid, NOS Waste Combustible Liquid. NOS Waste Flammable Solid, NOS Waste Acetyl Chloride Waste Chromic Acid Solution Hypochlorite solution (7% chlo- rine by weight) Hypochlorite solution (7% chlo- rine by weight) Waste Organic Peroxide, Liquid or Solution. NOS Waste Sodium Perchlorate Waste Potassium Perchloriate Waste Sodium Permanganate Waste Potassium Permanganate Waste Sodium Sulfide Waste Potassium Sulfide Wasle Petroleum Oil. NOS Waste Petroleum Oil. NOS HAZARD UN/NA CLASS ID NUMBER Corrosive Malcrial UNI824 Corrosive Material UNl823 Corrosive Material UN1832 Ox id izer UNl873 Oxidizer UNI8D2 Corrosive Material UN2790 Oxidizer NAl477 ORM-E NA9189 ORM-E NA9l89 Poison B Poison B UNI935 UNl588 Flammable Liquid Combustible Liquid Combustible Solid UNI993 NA1993 UNl325 Flammable Liquid UNl7l7 Corrosivc Material UNl755 Corrosive Material UNl79l ORM-B NAl791 Orga n ic Perox ide NA9183 Oxidizer Oxidizer UNI502 UNl489 Oxidizer Oxidizer UNI5D3 UNI490 Flammable Solid Flammable Solid UNl385 UNl382 Combustible Liquid Flammable Liquid NAl270 NAI27D 'These descriptions may change given variations in waste characteristics or conditions. "Not otherwise specified. 3 A flammable liquid has a flashpoint of less than 1000F. 4 A combustible liquid has a flash point of between 1000 and 2oooF' however. only those materials with flash points below 1400F are considered hazardous under EPA regulations. 03 ...--~." ...---'~- T'PD T~_~ '_' . . ! J."' .~", MEMORANDUM :::cp ("'~. 1986 L I ~.. I ~_. _. D L:. :;1 23 September 1986 - TO Craig Grabeel, Assistant to the City Manager~ James Rhoden, Fire Chief FROM: Carmen S Annunziato, Planning Director RE QUANTUM PARK Attached to this memo you will find a copy of the proposed final Hazardous Waste Contamination Response Plan which I am forwarding for your information and/or comments Z J'-' /bks 0; {}vAt~ ...../f,t' \t/? a- t ~y0</.f t, ~tJlt- j; 17'" r !J Cf)r}1- 1"~' l r (lty~~ / ~ [, l I 744 RECEIVED SEP 2.! 1986 CITY MANAGER'S OFFICE \ MEMORANDUM 16 September 1986 TO Perry Cessna, Utilities Director James Golden, Assistant City Planner FROM: Carmen S Annunziato, Planning Director RE: Quantum Park Attached to this memo you will find a copy of the proposed final Hazardous Waste Contamination Response Plan submitted by Deutsch Ireland Properties in conpection with the Quantum Park of Commerce Please review this plan and forward your comments for incorporation into the final plan where appropriate, as this document must be approved by the City Council i \/:' ( /{ ~ /] /'1~/(::J (C/?r'_....-'7l// 7~G-~~ CARMEN S ANNUNZIATO ~ /bks cc: City Manager DEUTSCH IRELAl\'TI PROPERTIES ~El:li.. Y:O "O~T L....UD[ROAL~_~!:!:ICE September 11, 1986 Mr Carmen Annunziato, City Planner City of Boynton Beach 120 N E 2nd Avenue PoO Box 310 Boynton Beach, Florida 33435 Approval of the Hazardous Waste Plan Contamination Respo e Dear Carmen In accordance with Condition 17 of the Development Order, Quantum Associates hereby submits to you their Hazardous Waste Plan for your final review and approval Please call me It ~nere are any questlons you nave durlng your review process or if additional copies are needed in order for you to complete your review Thank you for your consideratlon on this matter Very truly yours, QUANTUM ASSOCIATES .-/!:;ktl <g~ t.U 2e OLJ1UijLJ"-~ GEORGE W ZIMMERMAN {a.~'1':J VICE PRESIDENT OF DEVELOPMENT GWZ aem CC David S Pressly, Esq SUITE 1106-INTERNATlONAL BUILDING-2455 E. SUNRISE BOULEVARD-FORT LAUDERDALE, FLORIDA 33304 0 (305) 564-5114 THE BUILDING 01125 NORTHEAST 125 STREET NORTH MIAMI, FLORIDA 33161 . (305) 891-6806 AFFILIATES: 0/1 REALTY & MANAGEMENT CORP MITA CONSTRUCTION CORP J. LAW ENVIRONMENTAL SERVICES DIVISION OF LAW ENGINEERIN-:i rE5T;NG CL.MPANY 2749 DELK ROAD S E. MARIETTA, GEORGIA 30067 (404) 952-9005 February 18, 1986 Mr. Thornmas P. Misuraca Deutsch-Ireland Properties Suite 1106, International Bui~ding 2455 E. Sunrise Boulevard Fort Lauderdale, Florida 33304 Dear Mr. Misuraca Please find enclosed Revised Copy of Guidelines for the Preparation of Tenant Hazaraous Materla.LS .KespuuQC;: !lI~u~. ~ If you have any questions, please do not hesitate to call. Very truly yours, LAW ENVIRONMENTAL SERVICES dpov .. Neil D. Willi~ E. G!7eCh~al En?~ne~r (l. ~_ _/ ;!t/l- \. /-. At '- _'LC -K'.. Jfunes L. Studer, P. E \i5enior Geotechnical Engineer Registered Florida 26878 NIli :JLS/l sm Encl osur e 'I GUIDELINES FOR THE PREPARATION ~ r'~ wi ~ ~ ~r OF TENANT HAZ ARDOUS MATERIALS' IaA.J. ~ RESl'ONSE PLANS fI.. ,..,- 111 pI~ . -I~ ~ VS I' BOYNTON BEAL'B PARK OF COMMERCE /' Prepar ed by LNl ENVIRONHENTAL SERVICES Marietta, Georgia Prepared for DEUTSCH-IRELAND PROPERTIES Ft. Lauderdale, Florida V er si on 2 0 February 13, 1986 - ..~~~~---~-_._- ~ GUIDELINES FOR THE PREPARATION OF TrnANT HAZ ARDOUS MATERIALS RESPONSE PLANS BOYNTON BEACH PARK OF COMMERCE 1. INTRODUCTION The Boynton Beach Park of Commerce is a 539.9 acre develo~ ment between Ft. Lauderdale and West Palm Beach, Florida. The park is situated north and south of 22nd Avenue in Boynton Beach, Florida adjacent to Interstate 95 (see Figure 1). The park is bounded on the east by 1-95 and the Seaboard Coastl ine Rail road, on the south by Canal C-16, on the west by Canal E-4 and on the north by farml and and other undev eloped pr operty. It is antici- pated that the primary uses of the development will be 30.4 acres commercial, 133.1 acres office, 197.6 acres light industrial, and the remainder to include a Sea Pine Reserve, City Park, and state ri ghts- of-way. For the purposes of this aocument, the owners shall be considered the manager of the Park of Commerce. Tenants shall include all those personnel or companies which purchase or lease land or commercial space at the Park. Prior to occupancy, each tenant that uses, handles, stores or displays hazardous materials or generates hazardous waste as defined in 40 CFR Part 261 (7-1-85), shall meet the requirements of condition 16 of Ordinance No. 84-51 of the .Ordinance of the City of Boynton Beach, Florida, approving a comprehensive development of regional impact (DRI) for a proposed industrial office park comprising of approximately 539 acres located in the city of Boynton Beach, Florida pursuant to chapter 380, Florida Statues 1984, subject to special conditions, designating the city 1 '" manager of Boynton Beach as the local official responsible for assuring compliance with the development order.. The regulated substances described in 40 CFR Part 261 shall also include all waste materials which exceed the limits for ignitability, corrosivity, reactivity or EP toxicity as outlined in 40 CFR Part 261.20, 21, 22, 23 and 24. In additiun, the following materials and uses shall be prohibited: 1. Dioxin and Dioxin containing materials 2. Materials or substances containing PCB's 3 . Semi conductor manuf act ur i ng f acil i ti es 4. Wafer/chip manufacturing facilities 5. Underground Storage Tanks 6. Surface Impoundments 7. Landfilling or Burial of Waste Materials. 1 This document orovides guidance for the preparation of Tenant Hazardous Materials Response Plans as required by state U,? . Ordinance No. 84-51. The application for a hazardous waste facility permit must be completed by all persons who own or operate, or who intend to construct or close a hazardous treat- ment, storage or disposal facility as identified in Section 17- 3 0 , F 1 0 ri da a dm i n i s t rat i v e cod e ( FA C), u nl e sse x em p t e din a c cor- dance with Section 17-30.27, FAC. No regulated material shall be used, stored, handled or manufactured for any purpose within 60 days of the date that the Tenant Hazardous Materials Response Plan and the necessary permits have been filed with and approved by the appropriate regulatory agencies. "7 . --- This document does not relieve the tenants of the normal 2 II reporting, manifesting and regulatory procedures required by Federal, state or local agencies in the handling, storag~, inven- tory and reporting procedures for hazardous wastes. Application for a hazardous waste facility permit, per form 17-1.207(3), must - - ~ be completed in accordance wi th the requirements of section 17-30 1 of the FAC. This document provides an overview to assist tenants jY 1n identifying potential problem areas that might be encountered '~n early planning stages and provides the methodology for reporting of hazardous material leaks or spills, assessment pro- grams and demonstration of financial responsibility. This document does not a ttempt to address all the details outlined in the Federal Register for hazardous waste storage, treatment and disposal facili ties. This document briefly reviews the following items as required by Ordinance 84-51. Guidelines for the storage of chemicals and hazardous ma terial s. Guidelines and requirements for reporting of accidental - releases of hazardous materials. Emergency response team co-ordination with the local haz ardo us ma teri al contr 01 uni t. Specifications, guidelines and requirements for emer- .,.-- ~. -, "--- gency ground-water monitoring in the event of an acci- dental release of hazardous waste. Guidelines for the design of surface water management - and spill contai nrnent st r uct ur es and f acil i ti es. Guidelines for the demonstration of financial responsi- - - bility. 3 vt-~ 'I ~~ i-:;J:- . 2. GUIDELINES FOR THE STORAGE OF CHEMICALS AND HAZARDOUS MATER IAL S The guidelines for the storage of chemicals or hazardous materials identified in this section are in addition to the requirements specified in the Florida Administrative Code, the Code of Federal Regulations, and appropriate National Fire Associations Standards. It is the responsibil ity of the Tenant .~_~_ ...______'--'...~~-=~~~_~EW -.~.-...__. v- - --- -.. . to design and construct chemical storage facilities which meet or .- -- ... -. -~ ~ - exceed the requir~ments ~~e.c~fif:d. ~~~pp~icable agencies or - ~ - ~ groups. No regulated chemicals or hazardous substances shall be stored, used or manufactured at the Tenant's facility within 60 days of the date that authorization has been granted by the appropriate regulatory agencies. .....,.,-.... ,-~ ~=-:::o~--. The chemi calor haz ar do us mater i al ar ea s sh all be i sol ate d from pedestrian or vehicular traffic. Si gns shall be posted to identify all chemicals or hazardous materials stored at the facility. In addition, "Danger-Keep Out" and "Unauthorized Persons - Keep Out" signs shall be conspicuously posted. The chemical or hazardous material storage areas shall be totally contained using berms or curbs. The volume of the head space contained within the berms or curbs shall be equal to 150% of the maximum storage capacity of the tanks and drums plus 6 inches of free board. The floor system shall be sloped to drain to a dedicated sump for each storage area. The floor and sump shall be lined with low conductivity materials such as High Densit: Polyethylene sheet, in a similar manner to that shown in ~ure.~The storage area shall be covered and the storage area " __~ VJ 1t~ ~. . jt.iJ- , pJ" . an5 sump isolated from runoff. Potentially reactive chemicals shall be stored in separate storage areas. Chemi cal storage practices shall follow the prin- ciples of segregation, isolation and protection specified by the National Fire Protection Association. In no case shall strong oxidizing chemicals be stored with potentially combustible mat- erials or flammable liquids. In storage areas containing more than one type of chemical, each chemical or waste materi al shall be identified on a clearly visible area of the storage tank. The area shall be marked to identify the most severe health, flam- mability or reactivity hazard present. The storage tanks or containment facilities shall be specifically designed and cer tif i ed f or the chemi cal s or haz ar do us ma t e~ i al s w hi ch they f rom the recycl ed. Th e de si gn of th e con- contai n. Any hazardous material or chemical spilled or used tv clear the stem shall be collected and drummed tairunent system is the responsibility of the tenant. The sche- matic shown in Figure 2 represents one possible alternative. 3. GUIDELINES AND REQUIREMENTS FOR REPORTING OF ACCIDENTAL RELEASES OF HAZARDOUS MATERIALS. After each tenant has met the requirements of the state and Federal regulations and the city ordinance 84-51 regarding stor- age and handling of hazardous waste, the tenant shall contact the ~~--:----~, fire department to make arrangem~nts for a preplan emergency ~. .". .do'" ~ "0"-""" 01;:r- " response meeting (the phone number of the Boynton Beach fire department is 734-8111 Ext. 451). - Prior to the preplan meeting, the tenant shall have com- 5 . pleted material data safety sheets on all chemicals which may be stored on site as required by OSHA. Copies of the material data safety sheets shall be provided to t~re Marsh~~dditional copies shall remain in the plant for the employees to read (see the attached copy of a material data safety sheets by the U. S. '7 .., :.1" ') (cr. · Department of Labor OSHA) in Appendix A. The tenant shall contact the fire department and arrange for a site visit to: 1. Review the material safety data sheets 2. Quantify total chemicals and storage area facilities 3. Assess sprinkler systems and fire fighting equipnent 4. Evaluate site logistics and general operating procedures, 5. Meet with the assigned emergency coordinators Designate the Plant Emergency Coordinator, and I ~~ ~ Discuss emergency evacuation procedures< ~ ~ ? The purpose of this meeting is to provide the Fire 6. 7 . Department available information necessary to respond promptly in an erner gency. 4. EMERGENCY RESPONSE TEAM COORDINATION WITH THE LOCAL HAZ MDOUS MATERIAL CONTROL UN ITS In the event of a sudden release of hazardous materials the following procedures shall be foIl awed Call the Boynton Beach Fi re Department at 911 Give the Plant's name and location State whether the emergency is First Aid 6 Fire . site to assist the Fire Department. (If not at ~, :::* Haz ardous Waste ReI ea se Call one of the Plant Emergency Coordinators to be - plant Si~ &.,/.- t.. Call the Division of Emergency Management at (904)-488- " 1320 and report the accident using a Reporting Form ~? ~or Einergency Event~un~ in ADgendix i5j. ~u:;.. (~.;...ltr-A Call the National Response Center number at 1-800-424- 8802 and report the accident using a Reporting Form for Emergency Events found in Appendix A or equal. Assist in the removal of all non-essential personnel from the area. Coordinate remedial activities with the Boynton Beach Fire Department Hazardous Waste Response release on local surface-water and ground-water ~r. ~ ~"I -(1,;.."" Team. . Contact the ground-water monitoring team to install wells (if necessarj') and to assess the impact of the quali ty. 5. GUIDELINES FOR EMERGENCY GROUND-WATER MONITORING IN THE EVENT OF AN ACCIDENTAL RELEASES OF HAZARDOUS MATERIALS. The tenant shall comply with (';;11 federal, state and local regulatory requirements governing ground-water monitoring fol- lowing the sudden release of hazardous materials. In the event of an accidental release of hazardous materials in the storage area, the hazardous materials collected in the chemical spill sump will be removed and recycled or disposed. - 7 ~ ~ tP,?-"1' ~~. " Following removal of the hazardous material from the sump, the chemical spill sump and containment area shall ne cleaned to remove hazardous materials to acceptable levels for safe oper- ation. No additional ground-water monitoring will be required. In the event of an accidental release of hazardous materials to the surface water sump which drains the runway, parking areas and loading dock, the required level of remedial action will depend upon the design option. If a double liner and leak detec- tion layer are installed under the runway then the spill area and sump shall be pumped dry and cleaned to acceptable levels. The clean-up levels shall be approved by the appropriate federal, state and local regulatory agencies. No ground-water monitoring will be required if a double liner system is used and the spill is contained within the area draining to the surface water sump. If a double liner system is not installed, then within seven (7) days of the spill, a minimum of 4 ground-water monitoring wells, screened from the water table to east 10 feet below the water table, shall be install ed (see Figure 3) at or "-- near the perimeter of the containment area. Fig u r e 3 sh ow s a typical well construction detail. One monitoring well shall be installed up-gradient of the spill and three (3) wells dCMn- gradi ent of the spill. The well s shall be moni tor ed monthly for - a period of 12 months for the specific hazardous constituents which were spilled and which were used in the clean-up effort. If, after 12 months, the constituents are not detected in the ground-water sam pI es obtai ned f rom the moni tor i ng wells, sampl ing will be terminated. At that time, the monitoring wells may be ~ -- closed by filling the riser pipe with a cement bentonite grout 8 'I ":I ~. ~~ ~. " " . mixture to the top. In the event that a spill occurs in an area which does not drain to a surface water sump, or if an overflow condition causes hazardous materials to overflow the contairunent area, immediate action may be required to intercept potentially contaminated surface water and prevent it from entering the surface water retention basins. One surface water sample shall be obtained for every 200 lineal feet of contaminated ditch or runoff area. One additional monitoring well (total of 5) shall be installed immediately down gradient of the affected area. Clean-up of the affected area shall be to the levels prescrlbed and approved by the federal, state and local regulatory agencies. ..- 6. GUIDELINES FOR THE DESIGN OF SURFACE WATER MANAGEMENT AND SPILL CONTAINMENT STRUCTURES AND FACILITIES. The tenant shall comply with all rules and regulations from the federal, state and local agencies governing the design of surface water management and spill containment structures. All drawings and plans must be submitted and approved by the appro- priate agencies prior to construction. Surface water discharge containment and hazardous chemical containment shall be addressed in the design of the facilities. The surface water runoff from the runway, parking areas, and loading dock at the plant site shall be contained, collected and treated using an oil water separator system to remove any floating substances such as oil or gasoline. The collection system may be grav ity controll ed or colI ected and pumped. In the event a pump system is used, the water or fluid level in the sump 9 - ? ~ .,I.. (.~J:, p~. "yK ~. shall be maintained at a pumped down level so that the sumps . always have adequate capacity to completely contain and store liquids from sp.dls and clean-up efforts The rules and regulations for construction of surface water containment system and hazardous waste containment systems shall be researched and combined with the needs of each specific plant' 5 requirements. The components of the containment system shall resist chemical degradation due to exposure to the chemi- cals used at the tenant's facility. Figures 4 and 5 are two general examples of a plant'S ~ - ~ typical layout showing surface containment control and hazardous waste contr 01. Figure 4 shows a surface water control system which collects the runoff from the runway, parking area and loading dock in a small collection sump which is then pumped into a central collection sump and transfer system. Because of plant layout there may be more than one collection sump feeding a central collection sump. Surface water runoff is then fed into an oil/water separator system. The treated water is discharged to the surface water management system. Any oil collected is drummed and sent either to a hazardous landfill or recycled in the plant. Figure 5 shows a simpl er arrangement using an oil water separator for both the collection and treatment of surface water runoff. The surface water runoff is directed by gravity flow into the below grade oil/water separator. The treated water is discharged by gravity into the surface water management system. The oil is skimmed from the top and collected in drums fO~ disposal. f ~ lti._ ~'7J:t~ r ~_~.h.. ~ 1:~. . The system suggested in Figure 5 has a lower capital ~uip- ment cost but may require additional planning and site grading. Figure 6 shows a surface water control area with a secondary containment system and a collection sump which pumps t9 the central collection sump. The transfer pump is controlled by a level control probe immersed in the pit alongside the submersible pump. The 1 evel indicator activates a sw itch whi ch tur ns on the pump. As the 1 evel of the 1 ~quid fall s, the float switch con- tinues to fall with the liquid level until the lower set of switches is activated shutting off the pump. Secondary contain- ment may not be required in the surface water controlled area but is offered as an alternative. Figure 7 shows the surface runoff control area using the separator for both containment and treatment. This system is gravity fed and discharged. The system may require the use of a pump if proper grades cannot be achi eved. The primary device used to treat surface water runoff from the runway, parking areas and loading dock is the oil/water separator. Figures 8 and 9 illustrates two different types of oil/water separators. Figure 8 shows a McTighe standard oil/ water separator with a mechani cal oil removal sy stem. Figure 9 shows a McTighe separator with Petro-pak and a mechanical oil removal system. There are many variations of these units depending on the specific treatment objectives, vol- ume flow rate, regulations and site logistics. The oil/water separator should be designed for constant operation and low maintenance. As oily infl uent flows into the 11 . separator, oil and sludge are removed and clean effluent is discharged to the surface water management system. The oil/water separator is comprised of a stationary tank, full of water, having an inlet at one end directing the incoming oily infl uent over a specially desi gned heavy corrugated plate, set at a 33 degree angle. Initially the flow is reversed and the influent passes over the corrugated plate. The corrugations in- duces agitation causing the oils or lighter density substances to break away. As the oil rises, it is joined by the other droplets of oil and due to their buoyancy rise rapidly to the surface. The rate at which the soils and other floating industrial waste raise to the surface depends on the oil droplet size. The larger the droplet, the faster the rate of rise and separation. Sludge or heavy solids within the stream settle to the bottom of the separator, cOllecting at the center sludge baffle plate. The second phase of separation begins as the influent is directed between an inclined arrangement of corrugated parallel plates, stacked upwardly, sloping at a 45 degree angle, and spaced 4 inches apart to prevent fouling by debris or gummy solias. It is here where buoyancy forces cause smaller oil droplets to rise and coalesce into sheets of oil on the underside of each of the corrugated plates, creep up to the surface, and finally break loose at the top in the form of large globules. Clean water flows in a downward path to the outlet where clarified water is permitted to escape from the lClWer regions as the separated oil is withdrawn from the surface. The oil is COllected and drummed for recycling or disposal. The sludge is collected and disposed at a licensed solid waste disposal 12 . facili ty. It is the responsibility of the tenant to design or provide documentation for approval of the surface water control and hazardous waste containment systems. The containment areas and oil/water separators shall only be provided in the parking areas, truck runways, loading ramps and docks and chemical storage areas, where regulated chemicals or hazardous materials likely to be transported. 7. GUIDELINES FOR THE DEMONSTRATION OF FINANCIAL RESPONSIBILITY Each tenant that handles, stores, uses or generates regu- {. J.".. ~ lated chemicals or hazardous materials shall demonstrate .. financial responsibility as outlined in 40 CFR part 264.140-150. ~...- No regulated chemicals or hazardous materials shall be handled, stored, used or generated within 60 days of approval of the financial demonstration by the appropriate regulatory agencies. It is the responsibility of each tenant to prepare the ~ " ~. financial demonstration and secure the approval of the appro- priate regulatory agencies. In addition to the requirements of ~ 40 CFR, each tenant that handles, stores, uses or generates regulated chemicals or hazardous materials shall contribute the Emergency Action (EA) response fund. The fund - ? administered by the administrative officer of the Trea- . ....... sure Coast Regional Planning Council. In the event of a release - of a regulated substance to the environment requiring payment form the EP response fund, the tenant responsible for the release will, in addition to any or all other costs for remedial action, reimburse tbe EA response fun~ for the exact dollar amount ~ .~.~:::K1::j~~~ . expended f rom the fund. In accordance with 40 CFR Section 264.142 the tenant shall prepare a cost estimate for closure and post closure care of the facility. The estimate must be prepared in current dollars for the point in time during the operation of the facility when closure or remediation would be most expensive, as stated in the closure plan (see 40 CFR Part 264.ll2(a)). The tenant shall adjust the closure and post-closure cost estimates each year within 30 days of the anniversary of the approval of the financial demonstration. The adjustment in the cost estimates shall reflect inflation and changes in the opera- tion of the facility which make closure or post closure more less costly. The tenant shall establish financial assurance for closure and post-closure care of the facili ty using one or more of the following options 1. Trust Fund 2. Surety Bond Guaranteeing Payment into the Closure and Post-Closure Trust Funds 3. Surety Bond Guaranteeing Performance of Closure and Post-Cl os ur e. 4. Closure and Post-Closure Letter of Credit. 5. Closure and Post-Closure Insurance. 6. Financial Test and Corporate Guarantee for Cl osure and Post-Cl os ur e. The closure and post-closure plans and cos~ estimates shall be prepared and certified by a registered professional engineer J - - 14 -~7 ~f' . and shall be approved by the EPA Regional Administrator after regulatory agencies. The basic requirements for the financial assurance options are stated in 40 CFR Parts 264.143 and 145. In addition, each tenant that handles. stores. us e s 0 r - generates regulated substances shall "demonstrate financial - responsibility for bodily injury and property damage to tnird - parrles caused by sudden accidental occurrences arising from" the ~ operation of the facility (40 CFR part 264.147). The tenant- shall maintain liability coverage for sudden accidental occur=- - -- --~-~ rences of at least $1,000,000 per occurrence with an annual aggreSiltQ--Of ~2,ef)e,66~, -~~:l:~ie~~ -~-=~~;';~~nse costs~he . ------..... liability demonstration requirements are stated in 40 CFR Part - ----~-.~~_LZ~.~,,__""'- _.....__--"'~ 264.147. '-.... ':"'~"-.':..-.~.......~....~.... . ;-HU U1 tA~ ~~ :J uJ:f.~~ 15 , APPENDIX A -------~--- ___-------0-------- ---c J>' 0 0 o:z :Xl :;c Z 0 o Q. 01 '" c: U'l fT'\ -I Z .." ~ \fl. If\ b 2 z C. J>' -e. 0 .rJ>'~gc! ~gr;a ~J>'~~ \~ \~ )z 6~M .0 ..-9- )' .--~----- r- - - .. \ r ::: _ _ :::: - il ~ \ \ ~ _ ,~- \l \ I \ >j\ - \ \ \ "- III",' , , , \ \ l. 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"5 "'io ~. o::.:'lIwl I ~I! ,& ;:"" 'l'l! f o'l;:I ie ;t~ ~'=' i..' ..t et:t= , I... ~j ,.." :a t"~ ~~ ~t a~ '-.... ~3 -,;~l~ "'~ ,l ~: ~I" l:~. ;.. ~'l .. i" ~i ..1"f1 .. 1":':. .... ~.. t d ::~.. tt ,j~~~1I z ;'11 112~.. .1" :.. 0..1,,1= .......... .... .......... -------- - ------------ n, J \~ <., . I / I I' ~ ) I ~~ ~): It' /- ,,--- .~n ~I\~', 't br.J U - C' fl h '."1" ~ 1}- .Ifbo~ , I _.\ :/1 ~ , j I ~ r I" t r ,. -.~-:=~ I \ ~ '} ~~ 1 ....:'J'lf'<1 1 trl'-i,-:"" .~<"~ ,...,-1'1 '~ ~,,+..~ ~ ';'",..1,., n ., n n I I I ,,.~: ) ~ ~ 11 II ~ ., ~ ,') .-", ., ~, 7 !, '''I.. \ '. (lil'> C'O).. \ 1 \" ~ ..... ? " n" il n i '" 11 ~~~ ri"' 1 ',.'?:t.,::1 ;J 111..., ~ ;:;_ ~~ MASTER SITE DEVELOPMENT PLAN I'-:--'-:"r-' "-'- (II>-, -... ,..... I[G[N(~ MSP.~A i'q '7 1 T ~- r.......~-.,,') ~ ..1. ...... ~ ~:~-:,.;I-::. .,:;: 1 )ft" . 0 '--J L _. _ UUh IJJ I ~JJ 1..~,..hl.1 ... J .-.. . Hf'W'.tctl. o-"'.In......". '-.II..fr',,' 11) _. ............, f,,...lItplK"r.. -J l nF'ITSCIIIREI.ANU ~:'~~.~.' .......:... ..M.....~~ .~f n.,.... ...... I.~,.. _ ..,. '0. , "........... .,r Wrtl...ds ~ _ .. ,,~ ~ f E:3 ~::~:'.. r....... ~~: --.- ....... - JfJ'~l------ - - --'I' ,-- .A \ - \ \ CORRESPO"IDE~CE ~-----~ treQlure co~t regional planniQg council January 8, 1988 Mr Carmen Annunziato, City Planner City of Boynton Beach 120 N E 2nd Avenue Post Office Box 310 Boynton Beach, FL 33435 Subject Quantum Park Dear Carmen Council staff has reviewed Version 5 0 of Guidelines for the Preparation of Tenant Hazardous Materials Contamination Response Plans for Quantum Park With inclusion of revised page 5 (see attached), it satisfied both conditions 16 and 17 of the Development Order for this project If you have any questions, please call Sincerely, (Xk~ ~Z L Chri sti ne Beditz C!;- DRI Coordinator LCB 19 Attachment cc Steven W Deutsch Heidi Schloss Marion Hedgepeth r ..,-... .-".-_.-;......~.':'" 1-. --., ::' ,JAN ;: - ~ ) \ f-'LJ' \i --- ~ ----"~-- -,--~- 3228 s.w. martin downs blvd suite 205 p.o. box 1529 palm city, Rorida 33490 phone (305) 286-3313 karen t. marcus chairman jim minix vice chairman thomas g. kenny, III secretary/treasurer daniel m. cory executive director [g1@~@(U]re@ ~[Ji)~O[Ji)@@[fO[Ji)~ ~lfi)(Q] [P)~@llfi)[j))O[j))~~ ~[fi)~o ~,.., .,.,.... ...,.... ....,..., ~.... ~...., ~...~ Hazardous Materials Management Environmental Engineering Planning VIA POSTMASTERS November 23, 1987 -.. -''''~ '.. f} , I f" ) : 11 ~JI! J/'~rf 07 1968 Mr. Lawrence Kirch Treasure Coast Regional Planning Council 3228 Martin Downs Boulevard, Suite 205 Palm City, Florida 34990 '.fll_... .!:<4- .~ """I.......,.... , ,. 'L ~ ~_.J JJ.~1 (.;,l,UIt..JGiL "'~l,illllci,;",~ Re: Quantum Park Hazardous Materials Management Plan (1025.02) Dear Larry: In accordance with our conversation last week, I am enclosing a revised page 5 of the above document. This revision includes all of the language we agreed upon regarding containment: the previous submittal contained a clerical error. I apologize for this oversight and trust the attached will clarify the situation. Thank you for calling this to my attention. Sincerely, RESOURCE ENGINEERING AND PLANNING, INC. ~. Mary M. Howard, AICP President MMH:cac Enclosure cc: Mr. Steven W. Deutsch, with enclosure AEPnnc. . 3920 ReA Boulevard . Palm Beach Gardens, Florida 33410 . II 305.622.9030 Persons - Keep Out" signs shall be conspicuously posted. The chemical or hazardous material storage areas shall be contained by continuous impervious berms or concrete curbs. The height of the curbing shall be determined by calculating the volume of the head space contained within the berms or curbs and shall be equal to 150% of the maximum storage capacity of the tanks and drums plus 6 inches of free board. The floor system shall be sloped to drain to a designated sump for each storage area. The floor and sump shall be lined with low conductivity materials such as High Density Polyethylene Sheet, or a suitable chendcally resistent expoxy paint, in a similar manner to that shown in Figure 2. The storage area shall be covered and the storage area and sump isolated from runoff. Potentially reactive chemicals shall be stored in separate storage areas. Chemical storage practices shall follow the principles of segregation, isolation, and protection specified by the National Fire Protection Association. In no case shall strong oxidizing chemicals be stored with potentially combustible materials or flammable liquids. In storage areas containing more than one type of chemical, each chemical or waste material shall be identified on a clearly visible area of the storage tank. The area shall be marked to identify the most severe health, flammability, or reactivity hazard present. The storage tanks or containment facilities shall be specifically designed and certified for the chemicals or hazardous materials which they contain. Any hazardous material or chemical spilled or used to clear the chemical containment system shall be collected and drummed from the sump and recycled or disposed at a licensed hazardous waste facility. The design of the containment system is the responsibility of the owner. The schematic shown on Figure 2 represents one possible alternative. The Surface Water 5 STATE OF FLORIDA DEPARTMENT OF ENVIRONMENTAL REGULATION SOUTHEAST FLORIDA DISTRICT /~ l~~~ t:r r: .\!:i \~~"h.~ ..i. .'. i~1 ~J"1f:/J V , \ ,i' / "S~ BOB MARTINEZ GOVERNOR P O. BOX 3858 3301 GUN CLUB ROAD WEST PALM BEACH, FLORIDA 334023858 DALE TWACHTMANN SECRET ARy J. SCOTT BENYON DISTRICT MANAGER January 28, 1987 R T:''-''''TT' tl:~ \.....;-~..../t..... ,. . ., J;' 1- , Mr Steven W. Deutsch Deutsch Ireland Properties 2455 East Sunrise Blvd., Suite 1106 Ft. Lauderdale, Florida 33304 JANi 1 PLAn;di \'.... U..r"; i Dear Mr. Deutsch: RE: Boynton Beach Park of Commerce Guidelines For The Preparation Of Tenant Hazardous Materials Response Plans After reviewing the above referenced plan, I have the following comments. Overall, the plan appears to be good with all areas of concern generally covered. A few minor points may need some clar- ification. A distinction should be made between hazasrdous mater- ials and hazardous waste. Although both can be equally damaging to the environment if improperly handled, the Department of Environ- mental Regulation permits and regulates the storage and transport of hazardous waste but not hazardous materials. References to 40 CFR Parts 260-265 would only apply to hazardous waste since only waste is covered by the regu~~~&ns. Financial responsibility (pages 13-15) as used in 40 CFR Part 264.140-150 is such an example. It deals with hazardous waste but does not require coverage for hazardous materials. Although "Surface Water Management System" is not defined on Figures 4, 5 and 7, discharge from oil/water separators should not be directly to the project lake system since many pollutants are dissolved and not removed by such a separator. Section 4(12) of Development Order 84-51 (D.O.) does waive the requuirement for the retention of the. first inch of runoff for depressed truck wells. However, it also specifically requires that "Parking areas and roadways to the truck wells shall be designed to divert runoff to storage and exfiltration systems on-site prior to discharge into the surface water management system". This requirement does not seem to have been achieved by the designs on Figures 4 and 5. Protecting Florida and Your Quality of Life Mr. steven W. Deutsch January 28, 1987 Page 2 "Process Area And Surface Water Control Containment Area" is not defined on Figures 6 and 7. If it is an area where hazardous materials are used, handled, stored or displayed, then direct discharge to the surface water management system from the oil/water separator as illustrated, is prohibited by D.O. Section 4(16). Please clarify these points for me. Thank you for this opportunity to comment on your plan. If I can be of any assistance, please do not hesitate to call me at (305) 689-5800. Sincerely, .~ Herbert H. Zebuth ~ Environmental Coordinator cc: Scott Benyon Carmen Annunziato~ Daniel M. Cary Robert McVety John Outland Robert Kukleski :=-=~~~::-2::j treClure ( st. lucie CO OJ! 1 mcrt!n regJona] r;~1""'" L, ~ ~ ,....l~!'.~~...a....... /' __,-",--,~~~--~~-<o"~~-~---'"" _~.-J J,.,.I j "-'.Ll jJ jJj l~ ';J 'OUnC1J January 22, 1987 RT . 'r"'" - - ~ ,-..., Mr Steven Deutsch Deutsch Ireland Properties SUit2 11(;6 - International Building 2455 E Sunrise Boulevara Ft ~auderdale, FL 33304 I JAN ~ ~Q~ PLA:" Subject Approval of the Hazardous Waste Continuation Plan Dear Mr DeutSCh However, I have rev i ewed the plan Please excuse the delay in my response and otfer these comments ~. "f: ;.. 1 I thill", you meant citJ rather than 2 On :Jage 2, second paragrapn, state, page 4, second paragraph, needs some discussion as to how isolation wi 11 be achieved, page 4, last paragraph, it is unclear how a curb could contain a spill in an adequate manner, page 5, second paragraph, seems to assume that disposal would be done in a proper manner, page 8, first complete paragraph, should both liners didn't fail before waiver of a page IG, second comolete paragraph, there contamination other than oi 1, page 13, last paragraph, the fund cannot be administered oy Treasure C oa s t , an d t1e sentence that ends at the top of page 15 is not complete 3 4 5 have some test to ensure man it or i n 9 well, should be some mention of f) 7 8 If you have any questions, please let me know Sincerely, 1 Terry Virta Planning Di TV ks v$ AICP ector cc Carnen Annunziato Boynton Park of Commerce file .~ ~~;~~/~~ , 620 s. dixie highway p.o. drawer 396 stuart, florida, 33495-0396 phone (305) 286-3313 a. a. hendrv, III chairman karen t. marcus vice chairman margaret c. bowman secretarvitreasurer daniel m. corv executive director BOARD OF COUNTY COMMISSIONERS KAREN T MARCUI District No. 1 LAke Perk KEN IPILLlAI District No.2. Welt Pelm BelICh JERRY L. OWENI Diltrict No.3. South Pelm 8eIICh DOROTHY WILKEN Diltrict No.4. Delrey BelICh KENNETH M. ADAMI Diltrict No.5. Belle G'" COUNTY ADMINISTRATOR John C. SanlllMy PALM BEACH COUNTY EMERGENCY OPERA TING CENTER November 26, 1986 Mr Steve Deutsch 2455 E Sunrise Blvd. Suite 1106 Ft Lauderdale, Fl. 33304 Dear Mr. Deutsch 8. T KENNEDY, JR Director Pelm INch County Di_lon of Emer...ncy U.n..........t 3723 Belvedere RGed We.. Pelm Beech. Floride 33406 PHONE:683-0880 Civil Defense (Races) Radio Station WC4AAC NOAA We.ther Radio Station KEC-50 (Alt.) n~" .- ~-O~ "Er jont:: FLt; I Our review of your Boynton Beach Park of Commerce docu- ment was from the perspective of a hazardous material contam- ination prevention and response plan Our recommendation that you not be permitted underground storage tanks was intended to mean for the storage of acute toxic chemicals identified in 40 CFR as adopted by the State of Florida as Chapter 17-30, FAC. It was not intended to prohibit the storage of ordinary petroleum products as long as the installation of such tanks was in compliance with Chapter 17-61, FAC or was not otherwise prohibited by the City of Boynton Beach. BTK fd Sincerely, '"" Information Copy Mr. Carmen Annuniato ~ Planning Director, City of Boynton Beach -?;..- Y CITY of -BOYNTON BEACH -;.. 200 N. Seacrest Blvd Post Office Box 310 Boynton Beach, FL 33435 (305) 734-8111 5~~~E.~=:~~ "< v~ _ 0> . a f~~;ii~07ro;;;:;:..;;;~F;' ~-~ -~-ip?\ l!.." .,.. . ..., ~..L ..... -- _.....~ =-~ :'t .. .'J..'-w: . --~~~~~ .. "'~:'l~-. Q~ d"",. ---- - ~.__ --~o):g. ~ '- ~ 1'* -.~ -- ...- !Sl ~~~~~_. -..r - -=--_-:"..-- ~~.:..:~. OFFICE OF THE PLANNING DIRECTOR t 14 November 1986 Mr George Zimmerman Deutsch-Ireland Properties 2455 East Sunrise Blvd. Ft Lauderdale, FL 33304 Dear George As per your request, I am attaching marked up copies plus associated materials with respect to the draft Hazardous Water Containment Response Plan. Yours very truly, CITY OF BOYNTON BEACH ~J~ . Carmen S. Annunziato, A~ Planning Director .~~ /bks Enclosures c:;. ..... CITY of BOYNTON BEACH ';' --- 200 N. Seacrest Blvd Post Office Box 310 Boynton Beach, FL 33435 (305) 734-8111 r' --- ---- --- -- :~~--!""'tEJ:::::='::I~~r::~ ..:-. __ It> .....~ iEo<;n, ./' ~....,-=~~~~ ji.l~!'~~. \; ~~ ..~ ~.- ~ ~. ~ l'~. _"-- ~ ~~---~~ ~ . ......., ~~--~ OFFICE OF THE PLANNING DIRECTOR 21 October 1986 Mr. George Zimmerman Deutsch-Ireland Properties 2455 East Sunrise Boulevard Ft. Lauderdale, FL 33304 Dear Mr. Zimmerman Attached you will find a copy of a letter from Daniel M Cary, Executive Director of the Treasure Coast Regional Planning Council which is self-explanatory In order to accommodate Mr. Carey's concerns, it will be necessary for Quantum to amend the Sand Pine Scrub preserve management plan and resubmit it in final form for the City's approval. Thank you for your cooperation in this matter. Yours very truly, CITY OF BOYNTON BEACH C~J~ Carmen S. Annunziato, AICP Planning Director /bks Enclosure cc: Daniel M Cary Central File trecvure co~t regional planni09 council Mr Carmen Annunziato, City Planner City of Boynton Beach 120 E Boynton Beach Boulevard Boynton Beach, FL 33435 Subject Quantum Park at Boynton Beach Dear Mr Annunziato Durinq review of the Ecological Report for the Quantum Park Development, Council staff identified concerns over whether 40 acres of Sand Pine Scrub habitat would cumulatively occur on the property if 1) experiments proposed to create additional scrub habitat areas did not succeed, and 2) additional scrub habitat areas (1-2 acres) were not preserved It was recommended that language addressing these concerns be added to the report as a condition of Council's approval Such language is contained in our letter of September 4, 1986 to the City of Boynton Beach Since that describing designated attached) provi des the preservation time we have recei ved a letter and a map from the developer addit i ona 1 areas of scrub habitat that wi 11 remai n withi n 1 andscape and up 1 and buffer areas after deve 1 opment (see The designation of these additional scrub habitat areas additional necessary acreage and an acceptable alternative for should the scrub creation project fail It is recommended that the attached descri ot i on and map along with the language provided in our previous transmittal, or that of similar intent, become part of the Sand Pine Scrub preserve and management plan the developer must follow Since site preparation and work in the preserve area has already commenced, plan ammendments should be made as soon as time and procedure permits questions please call I' t DMC MB/ks cc Kevi n Hall ahan Thomas P Misuraca George W Zimmerman Donald Richardson Jon C Moyle, Esquire 620 s. dixie highway p.o. drawer 396 stuart, florida, 33495-0396 phone (305) 286-3313 0.0. hendry, III chairman koren t. marcus vice chairman margaret c. bowman secretary/treasurer daniel m. cory executive director '" QUANTUM PARK \? , -:::. ,~, .<, -:::: -~ n",",--, ~~ . . '; ,....., .:.~ \ rI , ~~~~ni' ~i'~1~ ..... : ~ ~;- ~ ~ ""~ --i :_+ September 22, 1986 ;":-kt "~"':i c:JUr ~;claw PL-.~'~il ~fI1HCLL Mr Michael Busha, Regional Planner Treasure Coast Regional Planning Council 620 South Dixie Highway Stuart, Florida 33495 Re Sand pine Scrub Alternate Areas Dear Mike In accordance with your concerns, we have again evaluated the Quantum Site to establish the alternate sand pine scrub areas illustrated on the attached Exhibit A These alternate areas are to provide an extra level of assurance that the sand pine scrub maintained on the site will definitely amount to 40 acres Since there is some question in your mind as to the viability of scrub being created by the so called "sand scrub fingers", we have identified these additional scrub areas that will be maintained in other areas of the site until such time as the scrub fingers become viable At such time that we submit to Treasure Coast an ongoing management report that identifies, in concrete terms, the viability of the sand pine scrub fingers, we will maintain these additional areas in their natural or rehabilitated state as shown on Exhibit A Upon completion and acceptance of such report by the City of Boynton Beach, these areas would be released for final planting Following is a listing of the areas in the order in which they would be released AREA #1 - is a 20' strip of land contained within parcel #55 which will be utilized as part of the green space requirement of that parcel It amounts to one half acre in area AREA #2 is the roadway right-of-way areas of Quantum Boulevard north of Northwe$t 22nd Avenue These areas amount to 1 1 acres Although a greater area exists, minimal disturbance during construction leads us to believe only the 1 1 acres will be left viable upon completion of the roadway AREA #3 is the roadway right-of-way for High Ridge Road north of Northwest 22nd Avenue Again, the same situation occurs here as the right-of-way on Quantum Boulevard Resulting scrub area is 58 acres 2455 EAST SUNRISE BOULEVARD . SUITE 1106 . FORT LAUDERDALE, FLORIDA 33304 BROWARD (305) 564-5114 . PALM BEACH (305) 734-3555 Mr Michael Busha, Continued September 22, 1986 Page 2 AREA #4 is the right-of-way area on the south loop of High Ridge Road adj acent to parcel # 5 5 These areas will be maintained in scrub in the amount of 42 acres . AREA #5 is an area beyond the perimeter fence substation that will be constructed on parcel 51B 1 03 acres of sand pine scrub of the FP &L It amounts to AREA #6 is a land area that will surround the lake being developed on this water management parcel It amounts to 1 17 acres AREA #7 is the area adjacent to a lake in the southwest corner of the project Sand pine scrub amounts to 32 acres AREA #8 is an area adjacent to the lake and wetland and across the street from the sand pine preserve Scrub is 69 acres in area AREA #9 is an area adjacent to the lake on the north side of Northwest 22nd Avenue that has a sand pine area of 56 acres AREA #10 is the lake area in the center of development parcels, on the north edge of parcel #55 It has a sand pine area of 76 acres In total, the sand pine area illustrated on Exhibit A is 7 1 acres If this plan meets with your approval as a final resolution of the Ecological Report and the Sand Pine Preserve's Management Plan, please provide us with your approval accordingly Thank you for your consideration on this matter Very truly yours, ,/ GEORGE W ZIMMERMAN Vice President of Development GWZ aem Enclosure CC Mr Edward B Deutsch Mr Thomas P Misuraca Mr Carmen Annunziato David S Pressly, Esq Mr Donald Richardson 68.". QLANTUM ~ Pt\RK BOARD OF COU ARE T MARCUS District t"o. 1 Lake Perk ~N SPILLlAS District No.2. st Pelm Beech JER Y L. OWENS District~O. 3. S th Palm Beach DOR HY WILKEN Di rict No.4, Delray Beach KENNETH M. ADAMS District No.6. Belle Glade COUNTY ADMINISTRATOR John C. San.bury PALM BEACH COUNTY EMERGENCY OPERA TING CENTER September 23, 1986 Mr Carmen Annunziato Planning Director City of Boynton Beach P O. Box 310 Boynton Beach, Florida 33435 D8ar Mr Annunziato B T KENNEDY, JR Director Palm Beach County Divi.ion of Emergency Management 3723 Belvedere Road West Palm Beach. Florida 33406 PHONE:683-0880 Civil Defense (Races) Radio Station WC4AAC NOAA Weather Radio Station KEC-50 (Alt.) f: ._-~,-'~-~'- ~~,...-::) ..;JJ_ ,- Enclosed is a copy of our review of the Hazardous Materials Contamination Prevention and Response Plan for the Boynton Beach Park of Commerce In our response to Deutsch-Ireland Properties, we indicated that our recommended changes are subject to the concurrence of the City of Boynton Beach If we may be of any further assistance, please let me know BTK fd Enclosure Sincerely, ~<. Bennett T Kennedy, Jr Director, Palm Beach County Division of Emergency Management ~- --- BOARD OF COUNTY COMMISSIONERS KAREN T MARCUS District No. 1 Laka Park KEN SPILLlAS District No.2, West Palm Beach JERRY L. OWENS District No.3, South Palm Beach DOROTHY WILKEN District No.4, Delrey Beech KENNETH MADAMS District No.5, Belle Glade COUNTY ADMINISTRATOR John C. Sansbury PALM BEACH COUNTY EMERGENCY OPERA TING CENTER September 23, 1986 ~r George W Zimmerman Vlce President of Development Deutch Ireland Properties Suite 1106 International Building 2455 E Sunrise Boulevard Ft Lauderdale, Florida 33304 Dear Mr Zimmerman B T KENNEDY, JR Director Palm Beach County Division of Emergency Manegement 3723 Belvedere Road West Palm Beach, Florida 33406 PHONE:683-0880 Civil Defense (Races) Radio Station WC4AAC NOAA Weather Radio Station KEC-50 (Alt.) The attached Hazardous Materlals Contamination Prevention and Response Plan for the Boynton Beach Park of Commerce was directed to us by your office for review Our review of this plan is made as a courtesy to and in support of the City of Boynton Beach, Florida and the Treasure Coast Regional Planning Council The attached recommended additions, deletions, and changes to the plan are subject to the concurrence of the City of Boynton Beach in consultation with the Treasure Coast Regional Planning Council To provide an understanding of our review, we show recom- mended amendments to the plan in the form of underlines for additions and strike-outs for deletions In addition, we make the following comments 1 The plan does not meet the requirements of Condition 17 of the Development Order, Ordlnance No 84-51 of the City of Boynton Beach in that it only provides general guidelines for the development of hazardous materials contaminatlon response plans and further delegates the responsibility for preparing such plans to future tenants (more) Mr George W Zimmerman Deutch Ireland Properties Page 2 September 23, 1986 2. An internal alarm and communication system should be provided to alert others in the facility to an acci- dental spill or release of hazardous materials 3 The plan should require the proper training of all personnel prior to their use, handling or storage of hazardous materials. Relative to the position in which they are employed, individuals should be required at all times to be capable of demonstrating their knowl- edge and competence of using, handling, and/or storage of hazardous materials in compliance with 40 CFR 264 16 and this plan 4 The plan should require a representative of each facility to familiarize representative of both the Boynton Beach Police Department and the Boynton Beach Fire Department with the layout of each facility, properties of hazardous waste handled at each facility and associated hazards, places where facility personnel would normally be working, entrances to and roads inside the facility, and possible evacuation routes 5 The plan should identify local hospitals and such hospitals should be familiarized with the properties of hazardous materials used at any facility and the types of injuries or illnesses which could result from fires, explosions or releases at the facility 6 The plan should describe in detail, the actions facility personnel must take to comply with 40 CFR Parts 264 51 and 264.56 in response to fires, explosions, or any unplanned sudden or non-sudden release of hazardous materials or hazardous waste constituents to air, soil or surface water 7. There should be no underground storage tanks. All above ground stationary storage tanks must be installed in compliance with Chapter 17-61, Florida Administrative Code 8 Figure 2 of the plan permits the transferral of hazardous waste liquid from the sump pump to be containerized for disposal in an area not protected by the double liner. This should not be allowed (more) Mr. George W. Zimmerman Deutch Ireland Properties Page 3 September 23, 1986 9 Even though the Development Order, Ordinance No 84-51 does not require the developer to install a master ground water monitoring system to monitor the quality of the ground water underlying the development as a whole; and does give the developer the option of requiring each tenant to install individual facility monitoring wells, the plan does not meet the require- ments of condition 16 of the ordinance for an early warning monitoring system The plan requires the tenant to install monitoring wells only after a known and reported spill of hazardous waste products. The plan is void of any system to detect contaminants entering ground water underlying a facility from unknown and/or unreported spills 10 Material data safety sheets referenced to Appendix "A" is not shown. Sincerely, BTK fd Attachment Information Copies: Mr. Carmen Annunziato, Planning Director, City of Boynton Beach Ms. L Christine Beditz, DRI Coordinator, Treasure CJast Regional Planning Countil DEUTSCH IRELAND PROPERTIES REPLY TO f"ORT LAUDEROALE O""ICE September 15, 1986 Mr Bennett T Kennedy, Jr , Director Palm Beach County Division of Emergency Management 3723 Belvedere Road W Palm Beach, Florida 33406 Dear Mr Kennedy The Development Order for the Boynton Beach Park of Commerce, now known as Quantum Park, specifically requires approval of the Hazardous Waste Contamination Response Plan by the Palm Beach County Division of Emergency Management If you do not wish to be involved in the approval of such plans, please direct a letter to Mr Daniel Cary, Director of the Treasure Coast Regional Planning Council so stating This, I believe, would be the most efficient means of removing the request for such approval from Development Orders as they are issued I appreciate your help on this matter We will also try to contact Mr Cary to eliminate the requirement for your approval, if you so desire Thank you Very truly yours, , TUM ASSOCIATES GWZ aem CC Mr Carmen Annunziato, City Planner City of Boynton Beach SUITE 1106-INTERNATIONAL BUILDING-2455 E. SUNRISE BOULEVARD-FORT LAUDERDALE, FLORIDA 33304 . (305) 564-5114 THE BUILDING 1125 NORTHEAST 125 STREET NORTH MIAMI, FLORIDA 33161 (305) 891-6806 AFFILIATES. 0/1 REALTY & MANAGEMENT CORP MITA CONSTRUCTION CORP J. LAW ENVIRONMENTAL SERVICES DhllSION OF LAW ENGINEERING rF~TING ClJMPANY 2749 DELK ROAD S E MARIETTA, GEORGIA 30067 (404) 952 9005 February 18, 1986 Mr. Thommas P. Misuraca Deutsch-Ireland Properties Sui te 1106, Inter na ti onal B uil ding 2455 E Sunri se Boul evard Fort Lauderdale, Florida 33304 Dear Mr. Misuraca Please find enclosed Revised Copy of Guidelines for the Preparation of Tenant Hazardous Materials Response Plans. If you have any questions, please do not hesitate to call. Very truly yours, LPW ENVIRONMENTAL SERVICES dpo t:/ · Neil D Willi~. E. GJ1. eCh:a:Jie~ ( L<__ i '.f/'" ? _'l."~. ~,fumes L. Studer, P.E. "Senior Geotechnical Engineer Registered Florida 26878 NIli JLS/I sm Encl osur e GUIDELINES FOR THE PREPARATION OF TENANT HAZ ARDOOS MATERIALS RESPONSE PLANS BOYNTON BEAl.'8 PARK OF COMMERCE Prepared by LNi ENVIRONHENTAL SERVICES Marietta, Georgia Prepared for DEUTSCH-IRELAND PROPERTIES Ft. Lauder dal e, Flori da V er si on 2 0 February 13, 1986 GUIDELINES FOR THE PREPARATION OF TENANT HAZARDOUS MATERIALS RESPONSE PLANS BOYNTON BEACH PARK OF COMMERCE 1. INTRODUCTION The Boynton Beach Park of Commerce is a 539 9 acre develop- ment between Ft. Lauderdale and West Palm Beach, Florida. The park is situated north and south of 22nd Avenue in Boynton Beach, Florida adjacent to Interstate 95 (see Figure I). The park is bounded on the east by 1-95 and the Seaboard Coastline Railroad, on the south by Canal C-16, on the west by Canal E-4 and on the north by farmland and other undeveloped property It is antici- pated that the primary uses of the development will be 30 4 acres commercial, 133 1 acres office, 197.6 acres light industrial, and the remainder to include a Sea Pine Reserve, City Park, and state rights-of-way. For the purposes of this document, the owners shall be considered the manager of the Park of Commerce Tenants shall include all those personnel or companies which purchase or lease land or commercial space at the Park Prior to occupancy, each tenant that uses, handles, stores or displays hazardous materials or generates hazardous waste as defined in 40 CFR Part 261 ~+-~-85*, shall meet the requirements of condition 16 of Ordinance No 84-51 of the "er~i~anee e~ ~he City of Boynton Beach, Florida, approving a comprehensive development of regional impact (DRI) for a proposed industrial office park comprising of approximately 539 acres located in the city of Boynton Beach, Florida pursuant to chapter 380, Florida S~a~tle9 Statutes 1984, subject to special conditions, designating 1 the city manager of Boynton Beach as the local official responsi- ble for assuring compliance with the development order " The regulated substances described in 40 CFR Part 26l shall also include all waste materials which exceed the limits for ignitability, corrosivity, reactivity or EP toxicity as outlined in 40 CFR Part 261.20, 21, 22, 23 and 24 In addition, the following materials and uses shall be prohibited 1. Dioxin and Dioxin containing materials 2. Materials or substances containing PCB's 3. Semi conductor manufacturing facilities 4 Wafer/chip manufacturing facilities 5. Underground Storage Tanks 6 Surface Impoundments 7. Landfilling or Burial of Waste Materials. This document provides guidance for the preparation of Tenant Hazardous Materials Response Plans as required by 5~a~e city Ordinance No. 84-51 The application for a hazardous waste facility permit must be completed by all persons who own or operate, or who intend to construct or close a hazardous treat- ment, storage or disposal facility as identified in Section 17- 30, Florida administrative code (FAC), unless exempted in accor- dance with Section 17-30 27, FAC No regulated material shall be used, stored, handled or manufactured for any purpose within 60 days of the date that the Tenant Hazardous Materials Response Plan and the necessary permits have been filed with and approved by the appropriate regulatory agencies This document does not relieve the tenants of the normal 2 reporting, manifesting and regulatory procedures required by Federal, State e~ and local agencies in the handling, storage, inventory and reporting procedures for hazardous wastes. Appli- cation for a hazardous waste facility permit, per form 17-1.207(3), must be completed in accordance with the requirements of section 17-30 of the FAC This document provides an overview to assist tenants in identifying potential problem areas that might be en- countered in early planning stages and provides the methodology for reporting of hazardous material leaks or spills, assessment programs and demonstration of financial responsibility This document does not attempt to address all the details outlined in the Federal Register for hazardous waste storage, treatment and disposal facilities This document briefly reviews the following items as required by Ordinance 84-51. Guidelines for the storage of chemicals and hazardous materials. Guidelines and requirements for reporting of accidental releases of hazardous materials. Emergency response team co-ordination with the local hazardous material control unit Specifications, guidelines and requirements for emer- gency ground-water monitoring in the event of an acci- dental release of hazardous waste. Guidelines for the design of surface water management and spill containment structures and facilities. Guidelines for the demonstration of financial responsi- bility 3 --'-- -------- 2. GUIDELINES FOR THE STORAGE OF CHEMICALS AND HAZARDOUS MATERIALS The guidelines for the storage of chemicals or hazardous materials identified in this section are in addition to the requirements specified in the Florida Administrative Code, the Code of Federal Regulations, and appropriate National Fire Protection Associations Standards It is the responsibility of the Tenant to design and construct chemical storage facilities which meet or exceed the requirements specified by applicable agencies or groups. No regulated chemicals or hazardous substances shall be stored, used or manufactured at the Tenant's facility within 60 days of the date that authorization has been granted by the appropriate regulatory agencies The chemical or hazardous material areas shall be isolated from pedestrian e~ and vehicular traffic. Signs shall be posted to identify all chemicals or hazardous materials stored at the facility In addition, "Danger-Keep Out" and "Unauthorized Persons - Keep Out" signs shall be conspicuously posted The chemical or hazardous material storage areas sfia~~ Be ~e~a!!y eeft~a~ftee HS~ft~ Be~ffls e~ eH~6s. ~fte ve~Hffle ef ~fte heae s~aee eeft~a~ftee w~~fi~ft ~fte Be~ffls e~ eH~es sfta~~ Be e~Ha~ ~e ~5e% e~ ~he fflaxifflHffl s~e~a~e ea~aei~y ef ~he ~aftks aRe erHfflS ~~HS 6 ~Rehes e~ f~ee 6ea~e ~he ~!ee~ syseeffl sha~~ Be s!e~ee ~e e~aift ~e a eee~ea~ee SHffl~ fe~ eaeh s~e~a~e a~ea ~fte f~ee~ afte SHffl~ sfta!~ ee !~ftee W~~ft ~ew eefteHe~~vi~y ma~e~~a~s SHeft as H~~h Befts~~y Pelye~hy~efte shee~7 ift a s~ffl~la~ fflaftfte~ ~e ~ha~ SfteWfl ~ft F~~H~e ~~ ~he s~e~a~e a~ea sha~l ee eeve~ee afte efte s~e~a~e area 4 ;. and the area in which spilled materials are collected and con- tainerized from the sump pump shall be totally contained using curbs and provided with impervious bases, free of cracks and gaps, to fully contain leaks, spills, accumulated precipitation, and toxic runoff from potential fire fighting operations until the collected material can be neutralized and/or removed from the facility site The loading and off-loading areas shall have curbs on all sides except the side connecting to the driveway area The loading and off-loading area shall be depressed and shall provide a gradient away from the driveway area to an impervious sump located within the storage area Entrance to the loading and off- loading area shall be elevated in a manner that prevents natural drainage from entering the storage area and be capable of prevent- ing washout of any hazardous waste by a 100 year flood. The floor system shall be sloped to drain to a dedicated sump for each storage area The floor and sump shall be lined with low conductivity materials such as High Density Polyethylene sheet, in a manner similar to that shown in Figure 2 The storage area shall be covered and the storage area and sump isolated from runoff Potentially reactive chemicals shall be stored in separate storage areas. Chemical storage practices shall follow the princi- ples of segregation, isolation and protection specified by the National Fire Protection Association In no case shall oxidizing chemicals be stored with potentially combustible materials or flammable liquids. Radioactive materials shall be stored with a shielding equivalent to that used in shipping In storage areas 5 containing more than one type of chemical, each chemical or waste material shall be identified on a clearly visible area of the storage tank. The area shall be marked to identify the most severe health, flammability or reactivity hazard present using the hazardous identification system described in the National Fire Protection Association Standard No. 704. The storage tanks or containment facilities shall be specifically designed and certified for the chemicals or hazardous materials which they contain. Storage tanks used for hazardous chemicals shall be located above ground and shall have sufficient shell strength to assure against collapse or rupture. Pressure control for closed tanks shall be provided Tanks shall have controls to prevent overfilling. Any hazardous material or chemical spilled or used to clear the chemical containment system shall be collected and drummed from the sump and disposed or recycled. The design of the containment system is the responsibility of the Tenant subject to the approval of the authority having jurisdiction 3 GUIDELINES AND REQUIREMENTS FOR REPORTING OF ACCIDENTAL RELEASES OF HAZARDOUS MATERIALS After each Tenant has met the requirements of the State and Federal regulations and ~fte ei~y Ordinance No. 84-51 of the City of Boynton Beach regarding storage and handling of hazardous waste, the Tenant shall contact the Boynton Beach Fire Department to make arrangements for a preplan emergency response meeting (the phone number of the Boynton Beach Fire Department is 734-8111 ext. 451) Prior to the preplan meeting, the Tenant shall have completed 6 ~~ material data safety sheets on all chemicals which may be stored on site as required by OSHA. Copies of the -material data safety sheets shall be provided to the Fire Marshall Additional copies shall remain in the plant for the employees to read (see the at- tached copy of a material data safety sheets by the U S Depart- ment of Labor OSHA)in Appendix A The tenant shall contact the fire department and arrange for a site visit to I Review the material safety data sheets 2. Quantify total chemicals and storage area facilities 3 Assess sprinkler systems and fire fighting equipment 4 Evaluate site logistics and general operating procedures, 5 Meet with the assigned emergency coordinators 6. Designate the Plant Emergency Coordinator, and 7. Discuss emergency evacuation procedures_ The purpose of this meeting is to provide the Fire Department available information necessary to respond promptly in an emergency 4 EMERGENCY RESPONSE TEAM COORDINATION WITH THE LOCAL HAZARDOUS MATERIAL CONTROL UNITS In the event of a sudden release of hazardous materials the following procedures shall be followed Call the Boynton Beach Fire Department at 911 Give the Plant's name and location State whether the emergency is First Aid 7 Fire Hazardous material or hazardous waste spill or release Call one of the Plant Emergency Coordinators to be on site to assist the Fire and Police Department~ (If not at the plant site) Using a reporting form for emergency events found in Appendix A or equal, call the Palm Beach County Division of Emergency Management at 683-0880 for notification of proper State agencies. Call the National Response Center number at 1-800-424-8802 and report the accident using a reporting form for emer- gency event found in Appendix A or equal.for reportable quantities Assist in the removal of all non-essential personnel from the area Coordinate remedial activities with the Boynton Beach Fire Department~fta2a~ae~s was~e res~e~se ~eaft\. Contact the ground-water monitoring team to instal wells (if necessary) and to assess the impact of the release on local surface-water and ground-water quality 5 GUIDELINES FOR EMERGENCY GROUND-WATER MONITORING IN THE EVENT OF AN ACCIDENTAL RELEASE OF HAZARDOUS MATERIALS The Tenant shall comply with all Federal, State and local regulatory requirements governing ground-water monitoring follow- ing the s~aaeR release of hazardous materials. 8 In the event of an accidental release of hazardous materials in the storage area, the hazardous materials collected in the chemical sump will be removed and recycled or disposed There shall be no on-site disposal of any type of waste product The '. disposal of all hazardous waste or regulated substances to include residue of hazardous materials in empty containers shall be in compliance with the applicable provisions of the Resource Conserva- tion and Recovery Act (42 USC 6901), Chapter l7-30 Florida Adminis- tive Code, and all implementing Federal, State and local ru~es and regulations. 9 Following removal of the hazardous material from the sump, the chemical spill sump and containment area shall be cleaned to remove hazardous materials to acceptable levels for safe oper- ation No additional ground-water monitoring will be required. No waste that may be incompatible with the released material shall be treated, stored or disposed of until cleanup procedures are completed and all emergency equipment is cleaned and fit for its intended use before operations are resumed. In the event of an accidental release of hazardous materials to the surface water sump which drains the runway, parking areas and loading dock, the required level of remedial action will depend upon the design option. If a double liner and leak detec- tion layer are installed under the runway then the spill area and sump shall be pumped dry and cleaned to acceptable levels The clean-up levels shall be approved by the appropriate federal, state and local regulatory agencies No ground-water monitoring will be required if a double liner system is used and the spill is contained within the area draining to the surface water sump If a double liner system is not installed, then within seven (7) days of the spill, a minimum of 4 ground-water monitoring wells, screened from the water table to a depth at least 10 feet below the water table, shall be installed (see Figure 3) at or near the perimeter of the containment area. Figure 3 shows a typical well construction detail. One monitoring well shall be installed up-gradient of the spill and three (3) wells down- gradient of the spill The wells shall be monitored monthly for a period of 12 months for the specific hazardous constituents lO which were spilled and which were-used in the clean-up effort. If, after 12 months, the constituents are not detected in the ground-water samples obtained from the monitoring wells, sampling will be terminated At that time, the monitoring wells may be closed by filling the riser pipe with a cement bentonite grout mixture to the top In the event that a spill occurs in an area which does not drain to a surface water sump, or if an overflow condition causes hazardous materials to overflow the containment area, immediate action may shall be required to intercept potentially contaminated surface water and prevent it from entering the surface water retention basins. One surface water sample shall be obtained for every 200 lineal feet of contaminated ditch or runoff area. One additional monitoring well (total of 5) shall be installed immediately down-gradient of the affected area Clean-up of the affected area shall be to the levels prescribed and approved by the federal, state and local regulatory agencies 6 GUIDELINES FOR THE DESIGN OF SURFACE WATER MANAGEMENT AND SPILL CONTAINMENT STRUCTURES AND FACILITIES The tenant shall comply with all ~~~es aHa ~e~~~a~~eHS frem ~fte feae~a~7 s~a~e aHa ~eea~ a~enefes Federal regulations and those of the Florida Department of Environmental Regulations, the South Florida Water Management District and the City of Boynton Beach governing the design of surface water management and spill containment structures. All drawings and plans must be submitted and approved by the appropriate agencies prior to construction. 11 Surface water discharge containment and hazardous chemical containment shall be addressed in the design of the facilities The surface water runoff from the runway, parking areas, and loading dock at the plant site shall be contained, collected and treated using an oil water separator system to remove any float- ing substances such as oil or gasoline. The collection system may be gravity controlled or collected and pumped In the event a pump system is used, the water or fluid level in the sump 12 shall be maintained at a pumped down level so that the sumps always have adequate capacity to completely contain and store liquids from spJ.lls and clean-up efforts. The rules and regulations for construction of surface water containment system and hazardous waste containment systems shall be researched and combined with the needs of each specific plant's requirements. The components of the containment system shall resist chemical degradation due to exposure to the chemi- cals used at the tenant's facility. Figures 4 and 5 are two general examples of a plant's typical layout showing surface containment control and hazardous waste control. Figure 4 shows a surface water control system which collects the runoff from the runway, parking area and loading dock in a small collection sump which is then pumped into a central collection sump and transfer system. Because of plant layout there may be more than one collection sump feeding a central collection sump. Surface water runoff is then fed into an oil/water separator system. The treated water is discharged to the surface water management system. Any oil collected is drummed and sent either to a hazardous landfill or recycled in the plant. Figure 5 shows a simpler arrangement using an oil water separat or fur both the collection and treatment of surface water run 0 f f . Th e sur f ace w ate r r un 0 f f is d ire ct e d by g r a v i ty flow into the below grade oil/water separator. The treated water is discharged by gravity into the surface water management system. The oil is skimmed from the top and collected in drums for di sposal. 1-& 13 "' The system suggested in Figure 5 has a lower capital e:}uip- ment cost but may require additional planning and site grading. Figure 6 shows a surface water control area with a secondary containment system and a collection sump which pumps t9 the central collection sump. The transfer pump is controlled by a level control probe inunersed in the pit alongside the submersible " pump. The level indicator activates a switch which turns on the pump. As the level of the liquid falls, the float switch con- tinues to fall with the liquid level until the lower set of switches is activated shutting off the pump. Secondary contain- ment may not be required in the surface water controlled area but is offered as an alternative. Figure 7 shows the surface runoff control area using the separator for both containment and treatment. This system is gravity fed and discharged The sy stem may req ui re the use of a plunp if proper grades cannot be achi eved. The primary device used to treat surface water runoff from the runway, parking areas and loading dock is the oil/water separator. Figures 8 and 9 illustrates two different types of oil/water separators. Figure 8 shows a McTighe standard oil/ water separator with a mechanical oil removal system. Figure 9 shows a McTighe separator with Petro-pak and a mechanical oil removal system. There are many variations of these units depending on the specific treatment objectives, vol- ume flow rate, regulations and site logistics. The oil/water separator should be designed for constant operation and low maintenance. As oily influent flows into the B: 14 separator, oil and sludge are removed and clean effluent is discharged to the surface water management system. The oil/water separator is comprised of a stationary tank, full of water, having an inlet at one end directing the incoming oily infl uent over a specially desi gned heavy corrugated plate, set at a 33 degree angle Initially the flow is reversed and the influent passes over the corrugated plate. The corrugations in- duces agitation causing the oils or lighter density substances to break away. As the oil rises, it is joined by the other droplets of oil and due to their buoyancy rise rapidly to the surface. The rate at which the soils and other floating industrial waste raise to the surface depends on the oil droplet size. The larger the droplet, the faster the rate of rise and separation. Sludge or heavy solids within the stream settle to the bottom of the separator, collecting at the center sludge baffle plate. The second phase of separation begins as the influent is directed between an inclined arrangement of corrugated parallel plates, stacked upwardly, sloping at a 45 degree angle, and spaced 4 inches apart to prevent fouling by debris or gummy solias. It is here where buoyancy forces cause smaller oil droplets to rise and coalesce into sheets of oil on the underside of each of the corrugated plates, creep up to the surface, and finally break loose at the top in the form of large globules. Clean water flows in a downward path to the outlet where clarified water is permitted to escape frOOl the lower regions as the separated oil is withdrawn f rom the surf ace. The oil is collected and drummed for recycling or disposal. The sludge is collected and disposed at a licensed solid waste disposal 1:-2- 15 -- facH i ty. It is the responsibility of the tenant to design or provide documentation for approval of the surface water control and haz ardous waste contai nment sy stems. The containment areas and oil/water separators shall only be provided in the parking areas, truck runways, loading ramps and docks and chemical storage areas, where regulated chemicals or hazardous materials likely to be transported. 7. GUIDELINES FOR THE DEMONSTRATION OF FINANCIAL RESPONSIBILITY Each tenant that handles, stores, uses or generates regu- lated chemicals or hazardous materials shall demonstrate financial responsibility as outlined in 40 CFR part 264.140-150. No regulated chemicals or hazardous materials shall be handled, stored, used or generated within 60 days of approval of the financial demonstration by the appropriate regulatory agencies. It is the responsibility of each tenant to prepare the financial demonstration and secure the approval of the appro- priate regulatory agencies In addition to the requirements of 40 CFR, each tenant that handles, stores, uses or generates regulated chemicals or hazardous materials shall contribute $20,000 to the Emergency Action (EA) response fund. The fund shall be administered by the administrative officer of the Trea- sure Coast Regional Planning Council. In the event of a release of a regulated substance to the environment requiring payment form the EP response fund, the tenant responsibl e f or the r el ease will, in addition to any or all other costs for remedial action, reimburse the EA response fund for the exact dollar amount !-3- 16 expended f rom the fund. In accordance with 40 CFR Section 264.142 the tenant shall prepare a cost estimate for closure and post closu~e care of the facility. The estimate must be prepared in current dollars for the point in time during the operation of the facility when closure or remediation would be most expensive, as stated in the closure plan (see 40 CFR Part 264.112(a)). The tenant shall adjust the closure and post-closure cost estimates each year within 30 days of the anniversary of the approval of the financial demonstration. The adjustment in the cost estimates shall reflect inflation and changes in the opera- tion of the facility which make closure or post closure more less costly. The tenant shall establish financial assurance for closure and post-closure care of the facili ty using one or more of the following options 1 Tr ust Fund 2. Surety Bond Guaranteeing Payment into the Closure and Post-Closure Trust Funds. 3. Surety Bond Guaranteeing Performance of Closure and Post-Closure. 4. Closure and Post-Closure Letter of Credit. S. Closure and Post-Closure Insurance. 6. Financial Test and Corporate Guarantee for Closure and Post-Closur e. The closure and post-closure plans and cost estimates shall be prepared and certified by a registered professional engineer 1-4-17 ... and shall be approved by the EPA Regional Administrator after regulatory agencies. The basic requirements for the financial assurance options are stated in 40 CFR Parts 264.143 and 145. In addition, each tenant that handles, stores, uses or generates regulated substances shall "demonstrate financial responsibility for bodily injury and property damage to third parties caused by sudden accidental occurrences arising from" the ope rat ion 0 f the f a c i lit Y (.. 0 C F R pa r t 2 6 4 . 1 47 ). The ten ant shall maintain liability coverage for sudden accidental occur- rences of at least $1,000,000 per occurrence with an annual aggregate of $2,000,000, excluding legal defense costs. 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September 18, 1986 i j.., - --------- TO / ~en Annunziato, Planning Director FROM: Craig Grabeel, Assistant to the City Manager SUBJECT: Boynton Beach Park of Commerce - DRI Hazardous Waste Contamination Response Plan Please find attached correspondence from the Palm Beach County Division of Emergency Management regarding subject DRI/Plan Inasmuch as this plan apparently relates to the DRI ordi- nance requirements and Technical Review Board and/or Environmental Review Committee review, it will be forwarded to your office as a matter under your cognizance You may prefer, however, to contact Mr Zimmerman to ensure its delivery to the appropriate OffiC~ " J ~!!a~ Craig Grabeel Assistant to the City Manager CG sr Attachment cc Peter L Cheney Chief Jim Rhoden Perry Cessna BOARD OF COUNTY COMMISSIONERS KAREN T MARCUS District No.1 Leke Park KEN SPILLlAS District No.2, West Pelm Beech JERRY L. OWENS District No.3. South Pelm Beech DOROTHY WILKEN District No.4, Delrey Beech KENNETH MADAMS District No.5, Belle Glede COUNTY ADMINISTRATOR John C, San.bury PALM BEACH COUNTY EMERGENCY OPERATING CENTER September 12, 1986 Mr George W Zimmerman Deutsch Ireland Properties International Building 2455 E. Sunrise Boulevard Ft Lauderdale, Florida 33304 Dear Mr. Zimmerman B T KENNEDY JR Director Palm Beech County Division of Emergency Management 3723 Belvedere Road West Palm Beach, Florida 33406 PHONE:683-0880 Civil Defense (Races) Radio Station WC4AAC NOAA Weather Radio Station KEC-50 (Alt.) The enclosed Hazardous Waste contamination Response Plan prepared for Boynton Beach Park of Commerce was misdirected to our office for review and is returned. Since the plan must comply with the provisions of an ordinance of the City of Boynton Beach and applicable codes of the State of Florida, it should be directed to the City Manager of Boynton Beach for review and approval by his staff. BTK fd Enclosure Sincerely, r. County agement Information Copy: City Manager Peter cheneyJ City of Boynton Beach RECEIVED I SEP Y 1986 CITY MANAGER'S OFFICE